• 물과 미래
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• 제28권5호
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• pp.117-127
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• 1995

해상도를 고려하는 GIUH 모형에 대한 적용과 분석을 평창강 유역의 소유역인 이목정유역에 대하여 수행하였다. 모형의 적용과 Fractal 분석을 위해 1:25,000, 1:50,000 그리고 1:100,000 축척의 지도를 이용하였다. 따라서 축척간의 비율이 일정한 값을 갖는다. 링크의 길이는 해상도 1mm의 구장기를 이용하였고 Fractal 차원은 Richardson 방법을 사용하였다. 지도의 축척에 따라 매개변수들의 현저한 변화를 발견하였으며 이러한 경향은 매개변수의 물리적 의미를 상실하게 한다. 그런데 Fractal 변환과 의 Melton지형법칙은 이러한 규모문제를 효과적으로 조정해주는 역할을 할 수 있다. 그리고 이 방법은 하도망과 유역간의 연관성을 모형에 반영할 수 있는 장점이 있다. 이 연구에서 제안한 GIUH의 적용성을 검증하기 위해 지수형 GIUH 모형과 비교하였다. 그 결과 제안된 2모수 gamma GIUH 모형이 좋은 재현성을 보였다. 따라서 Fractal 이론을 도입한 2모수 gamma GIUH 모형은 축척을 고려하는 IUH를 유도하는데 있어서 적절하다고 할 수 있다.

• 공업화학
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• 제26권2호
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• pp.184-192
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• 2015

석유 코크스, 바이오매스, 혼합연료들의 이산화탄소 가스화 반응성을 측정하고 비교하기 위해서 TGA (Thermogravimetric analyzer)를 이용하여 $1,100{\sim}1,400^{\circ}C$의 char-$CO_2$ 가스화 반응을 조사하였다. 기-고체반응속도 모델들에 적용하여 $1,100{\sim}1,400^{\circ}C$의 온도 영역에서의 반응 속도 상수를 구하였다. 또한 반응 속도 상수와 온도와의 관계를 Arrhenius 식에 적용하여 각 모델에서의 활성화에너지(Ea) 및 빈도 인자($K_0$)를 구하고 이를 실험값과 비교하여 석유 코크스, 바이오매스, 혼합 연료들의 이산화탄소 가스화 반응을 잘 모사하는 반응 속도식을 제시하였다. 반응온도가 증가할수록 이산화탄소 가스화에 소요되는 반응시간은 감축되었다. 또한 바이오매스와의 혼합이 증가할수록 활성화 에너지의 감소를 보여 바이오매스의 혼합이 석유 코크스의 이산화탄소 가스화 반응에 시너지 효과를 가져옴을 확인하였다.

• 한국환경과학회지
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• 제19권2호
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• pp.217-227
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• 2010

This paper was studied $CO_2$ respiration rate with physicochemical properties of soils at wetland, paddy field and forest in Nongju-ri, Haeryong-myeon, Suncheon city, Jeollanam-do. Soil temperature and $CO_2$ respiration rate were measured at the field, and soil pH, moisture and soil organic carbon were analyzed in laboratory. Field monitoring was conducted at 6 points (W3, W7, W13, W17, W23, W27) for wetland, 3 points (P1, P2, P3) for paddy field and 3 points (F1, F2, F3) for forest in 10 January 2009. $CO_2$ concentrations in chamber were measured 352~382 ppm for wetland, 364~382 ppm for paddy field and 379~390 ppm for forest, and the average values were 370 ppm, 370 ppm and 385 ppm, respectively. $CO_2$ respiration rates of soils were measured $-73{\sim}44\;mg/m^2/hr$ for wetland, $-74{\sim}24\;mg/m^2/hr$ for paddy field and $-55{\sim}106\;mg/m^2/hr$ for forest, and the average values were $-8\;mg/m^2/hr$, $-25\;mg/m^2/hr$ and $38\;mg/m^2/hr$. $CO_2$ was uptake from air to soil in wetland and paddy field, but it was emission from soil to air in forest. $CO_2$ respiration rate function in uptake condition increased exponential and linear as soil temperature and soil organic carbon. But, it in emission condition decreased linear as soil temperature and soil organic carbon. $CO_2$ respiration rate function in wetland decreased linear as soil moisture, but its in paddy and forest increased linear as soil moisture. $CO_2$ respiration rate function in all sites increased linear as soil pH, and increasing rate at forest was highest.

• Bulletin of the Korean Chemical Society
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• 제26권7호
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• pp.1065-1070
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• 2005

$[Mn_{12}O_{12}(O_2CPh-4-SMe)_{16}(H_2O)_4]{\cdot}7CH_2Cl_2$ (1), a new single-molecule magnet complex has been successfully synthesized by substitution of acetate ligand of Mn12ac with 4-(methylthio)benzoic acid. Complex 1 crystallizes into triclinic P$\overline{1}$ with a = 18.321(3) $\AA$, b = 19.011(3) $\AA$, c = 27.230(4) $\AA$, $\alpha$ = 86.973(3)$^{\circ}$, $\beta$ = 76.919(3)$^{\circ}$, $\gamma$ = 87.613(3)$^{\circ}$, and Z = 2. In complex 1, one Mn(III) ion has an abnormal Jahn-Teller elongation axis oriented at an oxide ion. Complex 1 has two out-of-phase ac susceptibility peaks in the 2-4 K and 4-7 K regions. Effective anisotropy energy barrier and pre-exponential factor are $U_{eff}$ = 45.95 K, 1/$\tau$0 = 8.6 ${\times}\;10^9s^{-1}\;for\;{\chi}_M$'' peaks in the lower temperature region and $U_{eff}$ = 59.45 K, 1/$\tau_0$ = 2.2 ${\times}\;10^8\;s^{-1}$ for $\chi_M$'' peaks in the higher temperature region. The parameters of S = 10, g = 1.87, D = -0.40 $cm^{-1}$, and E = 0.00034 $cm^{-1}$ were obtained from the M/N${\mu}_B$ vs. H/T plot of complex 1.

• 유기물자원화
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• 제30권4호
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• pp.67-83
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• 2022

바이오차는 바이오매스를 산소가 제한된 환경에서 고온(300~700℃)으로 열분해하여 얻어지는 탄소 함량이 높은 생성물이다. 최근 바이오차는 농업 부산물을 최소화하고 순환 경제의 효율성을 높이는 효과적인 도구로 농업 및 환경 분야에서 다양한 용도로 널리 사용되고 있다. 바이오차를 만드는 재료로 왕겨, 가축분, 보릿짚 등 여러종류의 유기성 부산물이 사용되고 있으며, 약 10% 바이오차 적용(wt/wt)은 작물의 수확량, 토양 탄소 격리량을 높여준다는 연구 결과가 있다. 우리나라 농경지의 경우 논에서 밭으로 토지 이용이 전환되거나 간척으로 인한 갯벌이 논으로 개간되고, 산림에서 밭이나 시설재배지로 개간되는 경우가 발생한다. 그러므로 농경지 전환으로 인한 농경지별 바이오차 적용 효과가 상이할 것으로 판단된다. 그러나 국내에서 농경지 유형별 바이오차 종류와 투입 수준에 따른 토양 탄소저장 연구는 여전히 미흡한 상황이다. 이에 본 연구는 농경지 토양별 바이오차 종류와 투입 수준에 따른 토양 탄소저장과 무기화되어 배출되는 이산화탄소(CO₂) 배출량을 정량적으로 평가하였다. 본 연구에 사용한 재료는 보릿짚, 가축분을 수거, 건조 등 전처리 과정을 거친 후 충남 예산에 있는 바이오차 제조공장 탄화로를 이용하여 TLUD (Top Lit Up Draft) 상향 통풍형 열분해 방식으로 약 500℃에서 제조하였다. Kinetic 모델 적용 결과 토양에 투입된 탄소 무기화는 바이오차를 투입하지 않으면 토양 종류별 8.2~16.5% 비율로 탄소원이 무기화 되어 이산화탄소로 배출되었다. 노지 밭 토양에서 15.5~16.5%로 가장 높았고, 간척지 토양에서 8.2~8.7%로 가장 낮았다. 이는 토양 내 탄소 함량이 높은 토양에서 유기물의 분해가 상대적으로 높아 배출되는 이산화탄소(CO₂)는 탄소 함량에 비례하여 증가하는 것으로 판단된다. 바이오차를 투입한 토양에서 탄소 함량이 증가함에도 상대적으로 무기화되는 비율은 낮아졌다. 국제 바이오차협 회에서는 H:C 비율이 0.7 이하면 100년 이상 토양 내 탄소 격리효과가 있는 것으로 인정되고 있다. 본 연구를 통해 바이오차의 원료물질이 상이한 보릿짚, 가축분 바이오차 간 탄소 무기화에 미치는 영향이 상이할 것으로 판단했지만, 각각의 바이오차 H:C 비율이 0.30~0.39로 0.7 이하임으로 토양에 혼합하였을 때 탄소 무기화의 비율이 낮고 탄소 격리의 효과가 나타났다.

• 대한산업공학회지
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• 제28권1호
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• pp.63-75
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• 2002

To improve the efficiency of the electric power generation, monthly maximum electric power consumptions for a next one year should be forecasted in advance and used as the fundamental input to the yearly electric power-generating master plan, which has a greatly influence upon relevant sub-plans successively. In this paper, we analyze the past 22-year hourly maximum electric load data available from KEPCO(Korea Electric Power Corporation) and select necessary data from the raw data for our model in order to reflect more recent trends and seasonal components, which hopefully result in a better forecasting model in terms of forecasted errors. After analyzing the selected data, we recommend to KEPCO the Winters' multiplicative model with decomposition and exponential smoothing technique among many candidate forecasting models and provide forecasts for the electric power consumptions and their 95% confidence intervals up to December of 1999. It turns out that the relative errors of our forecasts over the twelve actual load data are ranged between 0.1% and 6.6% and that the average relative error is only 3.3%. These results indicate that our model, which was accepted as the first statistical forecasting model for monthly maximum power consumption, is very suitable to KEPCO.

• Advances in nano research
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• 제6권3호
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• pp.219-242
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• 2018

In this study, static bending of an edge cracked cantilever nanobeam composed of functionally graded material (FGM) subjected to transversal point load at the free end of the beam is investigated based on modified couple stress theory. Material properties of the beam change in the height direction according to exponential distributions. The cracked nanobeam is modelled using a proper modification of the classical cracked-beam theory consisting of two sub-nanobeams connected through a massless elastic rotational spring. The inclusion of an additional material parameter enables the new beam model to capture the size effect. The new non-classical beam model reduces to the classical beam model when the length scale parameter is set to zero. The considered problem is investigated within the Euler-Bernoulli beam theory by using finite element method. In order to establish the accuracy of the present formulation and results, the deflections are obtained, and compared with the published results available in the literature. Good agreement is observed. In the numerical study, the static deflections of the edge cracked FGM nanobeams are calculated and discussed for different crack positions, different lengths of the beam, different length scale parameter, different crack depths, and different material distributions. Also, the difference between the classical beam theory and modified couple stress theory is investigated for static bending of edge cracked FGM nanobeams. It is believed that the tabulated results will be a reference with which other researchers can compare their results.

• Journal of Information Processing Systems
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• 제5권2호
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• pp.69-76
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• 2009

Self healing systems are considered as cognation-enabled sub form of fault tolerance system. But our experiments that we report in this paper show that self healing systems can be used for performance optimization, configuration management, access control management and bunch of other functions. The exponential complexity that results from interaction between autonomic systems and users (software and human users) has hindered the deployment and user of intelligent systems for a while now. We show that if that exceptional complexity is converted into self-growing knowledge (policies in our case), can make up for initial development cost of building an intelligent system. In this paper, we report the application of AHSEN (Autonomic Healing-based Self management Engine) to in OKKAM Project infrastructure backbone cluster that mimics the web service based architecture of u-Zone gateway infrastructure. The 'blind' load division on per-request bases is not optimal for distributed and performance hungry infrastructure such as OKKAM. The approach adopted assesses the active threads on the virtual machine and does resource estimates for active processes. The availability of a certain server is represented through worker modules at load server. Our simulation results on the OKKAM infrastructure show that the self healing significantly improves the performance and clearly demarcates the logical ambiguities in contemporary designs of self healing infrastructures proposed for large scale computing infrastructures.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2010년도 춘계 학술발표회
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• pp.448-456
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• 2010

The mechanical behavior of granular soils is affected by particle bonding including natural cementation. This study addresses a simple model of small strain stiffness and salt concentration based on wave measurements of salt-cemented particulate media. Published models of artificially cemented soils with different curing methods and several types of cementation agents are reviewed. Glass beads with the median diameter of D50 = 0.5mm are prepared in rectangular cells using the water-pluviated method in salt water with different concentrations. Piezo disk elements and bender elements embedded in the cell are used for the measurements of compressional and shear waves. The relationships between elastic wave velocities and salt concentration show an exponential function. The measured small strain stiffness matches well the predicted small strain stiffness based on micromechanics for simple cubic monosized sphere particles. This study demonstrates that the salt concentration in salt-cemented specimen may be evaluated by using elastic wave velocities.

• International Journal of Reliability and Applications
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• 제13권1호
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• pp.19-35
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• 2012

This paper presents an optimum design of step-stress partially accelerated life test (PALT) plan which allows the test condition to be changed from use to accelerated condition on the occurrence of fixed number of failures. Various life distribution models such as exponential, Weibull, log-logistic, Burr type-Xii, etc have been used in the literature to analyze the PALT data. The need of different life distribution models is necessitated as in the presence of a limited source of data as typically occurs with modern devices having high reliability, the use of correct life distribution model helps in preventing the choice of unnecessary and expensive planned replacements. Truncated distributions arise when sample selection is not possible in some sub-region of sample space. In this paper it is assumed that the lifetimes of the items follow Truncated Logistic distribution truncated at point zero since time to failure of an item cannot be negative. Optimum step-stress PALT plan that finds the optimal proportion of units failed at normal use condition is determined by using the D-optimality criterion. The method developed has been explained using a numerical example. Sensitivity analysis and comparative study have also been carried out.