• 한국재료학회지
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• 제13권1호
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• pp.59-63
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• 2003

The microstructural characteristics of $Al_2$$O_3$/Cu composites hot-pressed at different temperatures for atmosphere switching from $H_2$to Ar have been studied. When the composite atmosphere was switched at $1000^{\circ}C$ it led to more homogeneous microstructure than when the atmosphere was switched at $1450^{\circ}C$. The strong sensitivity of Cu to atmosphere, especially the oxygen content in the atmosphere, was found to be responsible for the observed change, based upon the interfacial phenomena related to the formation of $CuAlO_2$. The practical implication of these results is that an optimum processing condition for the design of homogeneous microstructure and stable properties can be established.

• 한국분말재료학회지
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• 제11권5호
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• pp.421-426
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• 2004

The microstructure and mechanical property of hot-pressed $Al_2O_3/Cu$ composites with a different temperature for atmosphere changing from H$_{2}$ to Ar have been studied. When atmosphere-changed from H$_{2}$ to Ar gas at 145$0^{\circ}C$, the hot-pressed composite was characterized by inhomogeneous microstructure and low fracture strength. On the contrary, when atmosphere-changed at low temperature of 110$0^{\circ}C$ the composite showed more homogeneous microstructure, higher fracture strength and smaller deviation in strength. Based on the thermodynamic consideration and microstructural analysis, it was interpreted that the Cu wetting behavior relating to the formation of CuAlO$_{2}$ is probably responsible for strong dependence of microstructure on atmosphere changing temperature. The reason for a strong sensitivity of fracture strength and especially of its deviation to atmosphere changing temperature was explained by the microstructural inhomogeneity and by the role of CuAlO$_{2}$ phase on the interfacial bonding strength.

• 한국세라믹학회지
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• 제56권4호
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• pp.374-386
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• 2019

A process for nitrogen doping of TiO₂ ceramics was developed, whereby polycrystalline titania particles were prepared at 450-1000℃ with variation of the firing schedule under N₂ atmosphere. The effect of nitrogen doping on the polycrystallites was investigated by X-ray diffraction (XRD) and Raman analysis. The microstructure of the TiO₂ ceramics changed with variation of the firing temperature and the firing atmosphere (N₂ or O₂). The microstructural changes in the nitrogen-doped TiO₂ ceramics were closely related to changes in the Raman spectra. Within the evaluated temperature range, the nitrogen-doped titania ceramics comprised anatase and/or rutile phases, similar to those of titania ceramics fired in air. Infiltration of nitrogen gas into the titania ceramics was analyzed by Raman spectroscopy and XRD analysis, showing a considerable change in the profiles of the N₂-doped TiO₂ ceramics compared with those of the TiO₂ ceramics fired under O₂ atmosphere. The nitrogen doping in the anatase phase may produce active sites for photocatalysis in the visible and ultraviolet regions.

• 한국포장학회지
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• 제28권3호
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• pp.217-221
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• 2022

저온에서 신선육을 보관 저장하는 용기의 기체조성을 고CO₂/저O₂ 농도로 자동적으로 제어하는 용기 시스템을 제작하고, 0℃에서 21일간 돼지고기 삼겹살을 담아 저장하면서 품질보전의 측면에서 진공 포장과 함기 대조구 조건과 비교하였다. CO₂ 주입 시간 프로그램에 의하여 CO₂ 농도는 47~60%, O₂ 농도는 7~10%로 유지될 수 있었고, 이는 호기적 세균 증식과 pH 증가의 억제의 효과와 함께 관능적 품질유지에 기여하였다. 진공포장은 함기 대조구에 비하여 낮은 미생물 성장과 pH 증가를 보여주었으나 높은 drip 손실의 단점을 보였다. 전체적 품질보존의 측면에서 고안된 고CO₂ 치환 용기는 육류의 품질유지에 효과적이며, 육류의 종류와 특성에 맞게 기체 농도 조건을 변경하여 활용범위를 확장할 수 있을 것이다.

• 융복합기술연구소 논문집
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• 제13권1호
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• pp.13-17
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• 2023

Direct air capture (DAC) refers to the process of permanently removing CO₂ from the atmosphere by capturing CO₂ that has been emitted into the atmosphere from the past to the present directly from the atmosphere. DAC is a process that captures CO₂ that exists at 400 ppm in the atmosphere, so it has the problem of requiring a significant amount of air and high energy compared to CO₂ capture from a point source such as exhaust gas from a coal-fired power plant. In this study, we aim to introduce the performance, characteristics, and processes of absorbents that can be applied to DAC, focusing on the DAC process using absorbents developed to date, and present challenges that must be overcome in future DAC technology development.

• 대한원격탐사학회지
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• 제37권6_2호
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• pp.1859-1867
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• 2021

본 연구는 부산지역의 봄철과 여름철 대기 중 미세먼지(particulate matter, PM) 농도 및 빗물 수질을 정량화하고 다변량 통계분석을 이용하여 계절(봄, 여름) 특성에 따른 대기 중 PM 농도가 빗물 수질에 미치는 영향을 평가하였다. 연구기간(2020년 3월-8월)동안 기상청 AWS (automatic weather system)에서 측정된 대기 중 PM 농도와 총 68번의 강우 특성 자료를 이용하였으며, 총 68번의 강우 이벤트 중 13회 강우를 대상으로 부산 부경대학교 캠퍼스에 집수장치를 설치하여 총 216개의 빗물 샘플을 수집하였다. 빗물의 pH와 전기전도도(electrical conductivity, EC)는 실시간 측정되었으며, 빗물 내 양이온(Na⁺, Mg²⁺, K⁺, Ca²⁺, and NH₄⁺) 및 음이온(Cl^-, NO₃^-, and SO₄^2-) 농도를 분석하였다. 또한, 자체 제작한 미세먼지 센서를 이용하여 강우 전후로 대기 중 PM₁₀ 농도를 측정하였으며, 측정된 데이터를 바탕으로 주성분 분석(principal component analysis, PCA)과 피어슨 상관분석(Person correlation analysis)을 실시하여 대기 중 PM₁₀ 농도와 빗물 수질 간 상관관계를 규명하였다. 연구결과, 부산지역의 일평균 대기 중 PM 농도 및 강우 특성은 계절적 차이가 존재하였으며, 대기 중 PM₁₀ 농도와 빗물 수질간 상관성 또한 상이하게 나타났다. 봄철의 경우, 일평균 대기 중 PM₁₀ (34.11 ㎍/m³) 및 PM_2.5 (19.23 ㎍/m³)의 평균 농도는 상대적으로 높게 나타났고 일평균 누적 강우량 및 강우 강도는 상대적으로 낮게 나타났다. 또한, 대기 중 PM₁₀ 농도는 빗물 수질과 유의미한 상관관계를 보였으며 대기 중 PM₁₀ 농도는 pH (r = -0.84)는 감소시키고 EC (r = 0.95) 및 수용성 음이온(r = 0.99) 농도는 증가시키는 요인으로 작용하였다. 여름철의 경우에는 일 평균 PM₁₀ (27.79 ㎍/m³) 및 PM_2.5 (17.41 ㎍/m³)의 평균 농도가 상대적으로 낮은 농도 분포를 보였으며, 최대 일 평균 강우 강도는 81.6 mm/h로 오랜 시간 많은 양의 비를 기록하였다. 상대적으로 낮은 대기 중 PM 농도와 높은 강우 강도로 인해 대기 중 PM₁₀ 농도가 빗물 수질에 미치는 영향을 확인할 수 없었다.

• 대기
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• 제29권4호
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• pp.429-438
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• 2019

Organic carbon (OC) and elemental carbon (EC) in PM_2.5 were measured with Sunset Laboratory Model-5 Semi-Continuous OC/EC Field Analyzer by NIOSH/TOT method at Anmyeondo Global Atmosphere Watch (GAW) Regional Station (37°32'N, 127°19'E) in July and August, 2017. The mean values of OC and EC were 3.7 ㎍ m^-3 and 0.7 ㎍ m^-3, respectively. During the study period, the concentrations of reactive gases and aerosol compositions were evidently lower than those of other seasons. It is mostly due to meteorological setting of the northeast Asia, where the influence of continental outflow is at its minimum during this season under southwesterly wind. While the diurnal variation of OC and EC were not clear, the concentrations of O₃, CO, NOx, EC, and OC were evidently enhanced under easterly wind at night from 20:00 to 8:00. However, the high concentration of EC was observed concurrently with CO and NOx under northerly wind during 20:00~24:00. It indicates the influence of thermal power plant and industrial facilities, which was recognized as a major emission source during KORUS-AQ campaign. The diurnal variations of pollutants clearly showed the influence of land-sea breeze, in which OC showed good correlation between EC and O₃ in seabreeze. It is estimated to be the recirculation of pollutants in land-sea breeze cycle. This study suggests that in general, Anmyeondo station serves well as a background monitoring station. However, the variation in meteorological condition is so dynamic that it is primary factor to determine the concentrations of secondary species as well as primary pollutants at Anmyeondo station.

• 동아시아식생활학회지
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• 제3권2호
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• pp.99-106
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• 1993

The aim of this study is to elevate the efficiency of salting with low salt concentration in order to improve the quality of salted Chinese cabbage. The efficiency of salting was tested with various sub-atmosphere(760mmHg to 0mmHg), temperature(20$^{\circ}C$ and 30$^{\circ}C$), and concentration of salt(3%, 5% and 10%). The salting efficiency was estimated by amounts of juice, calcium elution, sodium penetration and the state of tissue. The amunts of juice eleuted from Chinese cabbage was increased significantly with the decrease of atmosphere and the time to reach the highest amounts was reduced. This tendency was promoted, with increase of salinigy(from 3% to 10%)and the increase of temperature(more juice at 30$^{\circ}C$ than 20$^{\circ}C$). The amounts of eluted calcium from Chinese cabbage tissue during salting under sub-atmosphere was directly proportional to amounts of juice and was inversely proportional to penetrated sodium. The salting time was reduced with elevation of sub-atmosphere. It was desirable to take between 5.5 and 9 hours to salt under the condition of 3% of salting, 20$^{\circ}C$, and 560-0mmHg. It took between 4.4 and 5 hours under 5% of salt and between 4 and 4.5 hours under 10% of salt. However, it was undesirable because the drying phenomenon and the transparency of tissue appeared under 30$^{\circ}C$ and 160-0mmHg.

• 대기
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• 제32권4호
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• pp.307-322
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• 2022

A drone has recently got attention as an instrument for weather observation in lower atmosphere because it can produce the high spatiotemporal resolution weather data even though the weather phenomenon is inaccessible. Sea fog is a weather phenomenon occurred in lower atmosphere, and has observational limitations because it occurs on the sea. Therefore, goal of this study is to analyze the vertical structures about inflow, development and dispersion of sea fog using the high-resolution weather data with the meteorological sensor-equipped drone. This study observed sea fogs in the west coast of the Korean peninsula from March to October 2021 and investigated one sea fog inflowed into the coast on June 8th 2021. θ_e - q_v diagrams (θ_e: equivalent potential temperature, q_v: water vapor ratio) and vertical wind structures were analyzed. At inflow of sea fog, moist adiabatically stable layer was formed in 0-300 m and prevailing wind was switched from south-southwesterly to west-southwesterly under 120 m. Both changes are favorable for sea fog on the location. θ_e and q_v plummeted in a layer 0-183 m. The inflowed sea fog developed from 183 m to 327 m by mixing with ambient atmosphere on top of sea fog. Also, strong mechanical turbulence near ground drove a vertical mixing under stable layer. At dispersion of sea fog, as θ_e on ground gradually increased, air condition was changed to neutral. Evaporation occurred on both bottom and top in sea fog. These results induced dissipation of sea fog.

• 한국포장학회지
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• 제26권1호
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• pp.19-23
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• 2020

Al-laminated packaging film incorporating ascorbic acid or tocopherol at inner food contact layer was tested in the potential to improve antioxidative preservation of powdered infant formula under CO₂-enriched atmosphere. Product of 200 g was packaged with the packaging film containing 0.3% antioxidant in sealant layer of low density polyethylene and stored at 30℃ for 286 days with periodic measurement of package atmosphere and product's quality attributes. The CO₂-flushed package resulted in shrinkage of tight contact between the product and the film not allowing gas sampling of package atmosphere after 140 days. Package of tocopherol-incorporated film allowed some ingress of oxygen after 112 days presumably due to its weakening of heat-seal area. The increased oxygen concentration in the tocopherol-added film package led to the concomitant increase of peroxide value, an index of lipid oxidation. On the other hand, packaging of ascorbic acid-added film pouch could suppress lipid oxidation marginally in consistent manner compared to control package without any antioxidant.