• Journal of the Korean Society of Industry Convergence
• /
• v.26 no.4_1
• /
• pp.517-527
• /
• 2023

Many techniques have been proposed and investigated for microlens array manufacturing in three-dimensional (3D) structures. We present fabricating a microlens array using selective laser etching and a CO₂ laser. The femtosecond laser was employed to produce multiple micro-cracks that comprise the predesigned 3D structure. Subsequently, the wet etching process with a KOH solution was used to produce the primary microlens array structures. To polish the nonoptical surface to the optical surface, we performed reflow postprocessing using a CO₂ laser. We confirmed that the micro lens array can be manufactured in three primary shapes (cone, pyramid and hemisphere). Compared to our previous study, the processing time required for laser processing was reduced from approximately 1 hour to less than 30 seconds using the proposed processing method. Therefore, micro lens arrays can be manufactured using our processing method and can be applied to mass productionon large surface areas.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.29 no.1
• /
• pp.9-14
• /
• 2023

The application of starch-based films is limited by the poor water vapor barrier and mechanical properties. In this study, plasticized octenyl-succinated corn starch (OTPS) was mixed into Poly (butylene adipate-co-terephthalate) (PBAT) with various concentration (0/0.25/0.5/0.75 wt%) of epoxidized soybean oil (ESO) to enhance the mechanical properties and the hydrophobicity of blends. Tensile Strength and elongation at break of PBAT/OTPS film was slightly strengthened as the added ratio of ESO raised to 0.5 wt%, yet lessened again in 0.75 wt% sample. The yield strength and elastic modulus were highest in 0.25wt% of ESO added. In thermal properties, the melting temperature (T_m) and crystallization temperature (T_c) were highest at ESO 0.25 and the maximum degradation temperature (T_max) of components of the films were developed as ESO added. Also, it has been proved that the addition of hydrophobic substances reduces the hydrophilicity of the film by contact angle. This suggests the use of epoxidized oil for preparing films based on high TPS content allows obtaining enhanced interfacial adhesion. This study confirmed that ESO acts as a compatibilizer between OTPS and PBAT to improve the mechanical properties and hydrophobicity of the sample. The sample containing 0.5wt% of ESO was the most suitable for packaging application.

• Journal of the Korean Wood Science and Technology
• /
• v.50 no.4
• /
• pp.219-236
• /
• 2022

Wood-based nanocomposite electrode materials were synthesized for application in supercapacitors by mixing nanostructured hematite (Fe₂O₃) with highly porous activated carbon (AC) produced from the wood-waste of Pinus roxburghii. The AC was characterized using various instrumental techniques and the results showed admirable electrochemical properties, such as high surface area and reasonable porosity. Firstly, AC was tested as an electrode material for supercapacitors and it showed a specific capacitance of 59.02 Fg^-1 at a current density of 1 Ag^-1, cycle life of 84.2% after 1,000 cycles (at a current density of 3 Ag^-1), and energy density of 5.1 Wh/kg at a power density of 135 Wkg^-1. However, when the AC was composited with different ratios of Fe₂O₃ (1:1, 2:1, and 1:2), there was an overall improvement in its electrochemical performance. Among the 3 ratios, 2:1 (AC:Fe₂O₃) had the best specific capacitance of 102.42 Fg^-1 at 1 Ag^-1, cycle life of 94.4% capacitance after 1,000 cycles (at a current density of 3 Ag^-1), and energy density of 8.34 Wh/kg at a power density of 395.15 Wkg^-1 in 6 M KOH electrolyte in a 3-electrode experimental setup with a high working voltage of 1.55 V. Furthermore, when Fe₂O₃ was doubled, 1:2 (AC:Fe₂O₃), the electrochemical capacitive performance of the electrode twisted and deteriorated due to either the accumulation of Fe₂O₃ particles within the composite or higher bulk resistance value of pure Fe₂O₃.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.18 no.3
• /
• pp.355-362
• /
• 2020

The corrosion behavior of the Inconel X-750 alloy was investigated for its potential application under a Cl₂-O₂ mixed gas flow in an Ar atmosphere. The corrosion rate was found to be negligible at temperatures up to 400℃ under a flow rate of 30 mL·min^-1 Cl₂ + 170 mL·min^-1 Ar, whereas an exponential increase was observed in the corrosion rate at temperatures greater than 500℃. The suppression of the corrosion reaction due to the presence of O₂ was verified experimentally at flow rates of 30 mL·min^-1 Cl₂ (4.96 g·m^-2·h^-1), 20 mL·min^-1 Cl₂ + 10 mL·min^-1 O₂ (2.02 g·m^-2 ·h^-1), and 10 mL·min^-1 Cl₂ + 20 mL·min^-1 O₂ (1.34 g·m^-2·h^-1) under a constant Ar flow rate of 170 mL·min^-1 at 600℃ for 8 h. The surface morphology analysis results revealed that porous surfaces with tunnel-type holes were produced under the Cl₂-O₂ mixed-gas condition. Furthermore, the effects of the Cl₂ flow rate on the corrosion rate were investigated, indicating that its impact was negligible within the range of 5-30 mL·min^-1 Cl₂ at 600℃.

• Journal of Sensor Science and Technology
• /
• v.28 no.6
• /
• pp.402-406
• /
• 2019

Recently, semiconducting organic materials have been spotlighted as next-generation electronic materials based on their tunable electrical and optical properties, low-cost process, and flexibility. However, typical organic semiconductor materials are vulnerable to moisture and oxygen. Therefore, an encapsulation layer is essential for application of electronic devices. In this study, SiN_x thin films deposited at process temperatures below 150 ℃ by plasma-enhanced chemical vapor deposition (PECVD) were characterized for application as an encapsulation layer on organic devices. A single structured SiN_x thin film was optimized as an organic light-emitting diode (OLED) encapsulation layer at process temperature of 80 ℃. The optimized SiN_x film exhibited excellent water vapor transmission rate (WVTR) of less than 5 × 10^-5 g/㎡·day and transmittance of over 87.3% on the visible region with thickness of 1 ㎛. Application of the SiN_x thin film on the top-emitting OLED showed that the PECVD process did not degrade the electrical properties of the device, and the OLED with SiN_x exhibited improved operating lifetime

• Bulletin of the Korean Chemical Society
• /
• v.32 no.7
• /
• pp.2385-2390
• /
• 2011

Preparation of ammonium dihydrogenphosphate supported on alumina ($NH_4H_2PO_4/Al_2O_3$) and its primary application as a solid acid supported heterogeneous catalyst to the synthesis of 1,2,4,5-tetrasubstituted imidazoles by a one-pot, four-component condensation of benzil, aromatic aldehydes, primary amines, and ammonium acetate under thermal solvent-free conditions were described. The results showed that the novel catalyst has high activity and the desired products were obtained in high yields. Furthermore, the products could be separated simply from the catalyst, and the catalyst could be recycled and reused with only slight reduction in its catalytic activity. Characterization of the catalyst was performed by FT-IR spectroscopy, the $N_2$ adsorption/desorption analysis (BET), thermal analysis (TG/DTG), and X-ray diffraction (XRD) techniques.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.62 no.3
• /
• pp.39-49
• /
• 2020

Rice paddy cultivation is one of the major sources in methane (CH₄) emission of which accurate assessment would be a prerequisite for agricultural greenhouse gas management. Biomass treatment in paddy fields is an important factor that affects CH₄ emissions and thus needs to be taken into account. The objectives of this study were to apply drone images to investigate organic matter practices and to incorporate into the estimation of CH₄ emissions from paddy fields. Three study areas were selected by one from each of the three different regions of Yeongnam, Honam and Jungbu, which are the most active region in paddy cultivation. The eBee drone was used to take images of the study sites twice a year; Jul mid-season for identifying rice cultivation area; Jan for investigating rice straw management and winter crop cultivation. Based on biomass management practices, different emissions factors were assigned on an individual paddy field and CH₄ emmisions were estimated by multiplying respective areas. The ratios of rice straw application and winter crop cultivation were 1.4% and 37.2% in Hapcheon, 1.3% and 19.8% in Gimje, and 0.0% and 0.5% in Dangjin, respectively. The CH₄ emissions estimates for respective sites were 0.40 ton CH₄/year/ha, 0.34 ton CH₄/year/ha, and 0.29 ton CH₄/year/ha. On average, estimated CH₄ emissions of this study were 28.5% less than the current Tier 2 CH₄ emission estimation method.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.26 no.2
• /
• pp.53-60
• /
• 2020

A concept of household container to create and keep the modified atmosphere (MA) beneficial for fresh produce mix was devised and tested under typical chilled storage conditions of 3℃. The container system containing mixed products is initialized by applying weak hypobaric condition (0.9 atm) and subsequently injecting CO₂ gas at an appropriate low level (0.03 atm). The passive atmosphere modification by produce respiration is then induced to reach a target until gas diffusion tube of proper dimension starts to open. The design was made to attain quasi-steady state mass balance of O₂, CO₂ and N₂ to maintain the desired MA through the storage. Interrupted opening for taking out or placing some products was to reinitialize the loop of control logic. The developed concept was tested by the container which held commodities of spinach, pak choi, oyster mushroom, peeled onion, strawberry and cut carrot. The target optimum MA of 11% O₂ and 10% CO₂ (0.11 and 0.10 atm, respectively) was set to avoid injurious range of O₂ and CO₂ concentrations for any commodities. The developed container system could work to reach and maintain beneficial MA of 0.10-0.12 atm O₂ and 0.07-0.10 atm CO₂ close to the target during the storage contributing to quality retention of products measured in weight loss, chlorophyll content of spinach, ascorbic acid content of pak choi, color of onion, texture of oyster mushroom, bacterial count of strawberry and carotenoids of carrot. The container system shows potential to improve current preservation practice of fresh produce mix on consumers' level.

• Journal of Animal Science and Technology
• /
• v.64 no.4
• /
• pp.603-620
• /
• 2022

Human activities have caused an increase in greenhouse gas emissions, resulting in climate change that affects many factors of human life including its effect on water and food quality in certain areas with implications for human health. CH₄ and N₂O are known as potent non-CO₂ GHGs. The livestock industry contributes to direct emissions of CH₄ (38.24%) and N₂O (6.70%) through enteric fermentation and manure treatment, as well as indirect N₂O emissions via NH₃ volatilization. NH₃ is also a secondary precursor of particulate matter. Several approaches have been proposed to address this issue, including dietary management, manure treatment, and the possibility of inhibitor usage. Inhibitors, including urease and nitrification inhibitors, are widely used in agricultural fields. The use of urease and nitrification inhibitors is known to be effective in reducing nitrogen loss from agricultural soil in the form of NH₃ and N₂O and can further reduce CH₄ as a side effect. However, the effectiveness of inhibitors in livestock manure systems has not yet been explored. This review discusses the potential of inhibitor usage, specifically of N-(n-butyl) thiophosphoric triamide, dicyandiamide, and 3,4-dimethylpyrazole phosphate, to reduce emissions from livestock manure. This review focuses on the application of inhibitors to manure, as well as the association of these inhibitors with health, toxicity, and economic benefits.

• Korean Journal of Organic Agriculture
• /
• v.23 no.4
• /
• pp.923-938
• /
• 2015

This study was conducted to serve as the basis for establishing a standard cultivation, which enhances the alternative utilization of pig manure, a major cause of environmental pollution, by finding a means for reducing greenhouse gas emissions for eco-friendly cultivation. In a laboratory, $CH_4$ and $CO_2$ emission patterns were investigated corresponding to incremental pig manure treatments in paddy soil. The emissions peaked 12 to 27 days after manure application in the 100~400% applications. It was found that increasing applications of pig manure resulted an increase in $CH_4$ and $CO_2$ emissions. Additionally, application of more than 150% emitted a larger amount of these gasses than applying chemical fertilizer. However, the test application of 100% pig manure emitted a smaller amount of $CH_4$ and hence Global Warming Potential (GWP) than those emitted by chemical fertilizer. If appropriate amount of fertilization is applied in compliance with the standard application rate, the pig manure may be effective in reducing greenhouse gas emissions and the soil environment made more favorable than with the use of chemical fertilizer.