• Title/Summary/Keyword: styrylpyridinium

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Photoisomerization of Styrylpyridunium Derivatives for Optical Memory

  • Kang, Young-Soo;Seo, Kyong-Won;Lee, Dong-Jae;Hong, Yong-Pyo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.81-84
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    • 2001
  • The trans and cis forms of N-alkyl-4-styrylpyridinium derivatives (CnSP: n= 4, 8, 12, 16) were successfully synthesized and purified. The derivatives of styrylpyridinium cause photoisomerization when they are illuminated with UV light. The pressure-area isotherms of CnSP and their derivatives were studied to reveal the effect of alkyl chain length. The photoisomerization of CnSP monolayers at the air/water interfaces was indirectly studied by measuring surface tension changes with photoirradiation on the water surface. The characteristics of CnSP were furthermore studied with UV-vis, surface pressure-area isotherms, surface potential-area isotherms, Brewster Angle Microscopy (BAM) at the air/water interface, and optical diffraction efficiency on the ultrathin films.

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Tri-enzyme modified electrochemical biosensor for paracetamol detection (파라세타몰 검출을 위한 전기화학적 다중효소 바이오센서)

  • Park, Deog-Su;Shim, Yoon-Bo;Chang, Seung-Cheol
    • Journal of Sensor Science and Technology
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    • v.17 no.1
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    • pp.29-34
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    • 2008
  • A new disposable amperometric tri-enzyme biosensor for the detection of paracetamol has been developed. The paracetamol sensors developed uses horseradish peroxidase modified screen-printed carbon electrodes (HRP-SPCEs) coupled with immobilized enzymes, tyrosinase and aryl acylamidase, prepared using a poly (vinyl alcohol) bearing styrylpyridinium groups (PVA-SbQ) matrix. Optimization of the experimental parameters has been performed and the paracetamol biosensor showed detection limit for paracetamol is as low as $100{\mu}M$ and the sensitivity of the sensor is $1.46nA{\mu}M^{-1}cm^{-2}$.