• Title/Summary/Keyword: styrene-butadiene-styrene

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Development of nonwoven fabric and new adhesive system to manufacture hybrid corrugated board (농산물용 복합 골판지 제조를 위한 부직포 및 신규 접착시스템에 대한 연구)

  • Lee, Ji-Young;Yoon, Hee-Youl;Oh, Seok-Ju;Sung, Yong-Joo;Kim, Byeong-Ho;Lim, Gi-Baek;Choi, Jae-Sung;Kim, Sun-Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.49-55
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    • 2012
  • Even though corrugated boards are the most common packaging materials for agricultural products, conventional corrugated boards are not able to maintain the freshness of agricultural products. In order to overcome the limitations of conventional corrugated boards, a new hybrid corrugated board-composed of linerboard, a corrugating medium, and non-woven fabric-was designed to possess antibacterial, high porous and shock-absorbing properties. In this study, we compared the physical properties of non-woven fabric to those of the base papers of conventional corrugated boards and developed a new adhesive system as a first step toward manufacturing the hybrid corrugated board. We found that the non-woven fabric, which had relatively high elongation, was applicable in the corrugated board process, and that the manufacturing conditions must be controlled in order to prevent the break of the non-woven fabric. The mixture of starch and styrene-butadiene (SB) latex showed high adhesive strength, but the addition level of SB latex should not exceed 30% in starch solution.

Hybrid (CNC+Laser) process for polymer welding (하이브리드 방식 (CNC+Laser)을 이용한 폴리머용접공정)

  • Yoo, Jong-Gi;Lee, Choon-Woo;Kim, Soon-Dong;Choi, Hae-Woon;Shin, Hyun-Myung
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.4-4
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    • 2009
  • Polycarbonate (PC) and Acrylonitrile Butadiene Styrene (ABS) was welded through a combination of a diode laser and CNC. Laser beam passed the transparent PC and was absorbed in an opaque ABS. Polymers were melted and welded by absorbed and conducted heat. Experiments were carried out by varying working distance from 44mm to 50mm for the focus spot diameter control, laser input power from 10W to 25W, and scanning speed from 100 to 400mm/min. The weld bead size and the specimen cross-section were analyzed, and tensile results were presented through the joint force measurement. With focus distance at 48mm, laser power with 20W, and welding speed at 300mm/min, experimental results showed the best welding quality which bead size was 3.75mm and the shear strength was $22.8N/mm^2$. Considering tensile strength of ABS is $43N/mm^2$, shear strength was sufficient to hold two materials. A single process was possible in CNC machining processes, surface processing, hole machining and welding. As a result, the process cycle time was reduced to 25%. Compared to a typical process, specimens were fabricated in a single process, with high precision. By combining two operations processes developed process gained 50% more efficiency.

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Improvement of Low-quality Local Aggregates Using Coating Materials (코팅재료를 이용한 비쇄석골재의 성능향상)

  • Park Dae-Wook;Kim Min-Gu
    • International Journal of Highway Engineering
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    • v.8 no.3 s.29
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    • pp.39-48
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    • 2006
  • A laboratory investigation was conducted wherein smooth, rounded, siliceous river gravel aggregates were coated with fine-grained polyethylene, carpet co-product, or cement + styrene butadiene rubber latex and used to prepare hot mix asphalt concrete specimens. Only the coarse (+ No.4) aggregates were coated. The concept was that the coatings would enhance surface roughness of the aggregates and, thus, produce asphalt mixtures with superior engineering properties. Hot mix asphalt specimens were prepared and evaluated using several standard and non-standard test procedures. Based on experiences during the coating processes and analyses of these limited test results, the following was concluded: All three aggregate coating materials increased Hveem and Marshall stability, tensile strength, and resilient modulus(stiffness). These findings are indicative of improved resistance to rutting and cracking in hot mix asphalt pavements prepared using coated gravel aggregates in comparison to similar uncoated gravel aggregates.

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Retentive Force of Adjustable Dental Impression Trays with Different Synthetic Resin Materials (합성수지 재료에 따른 가변형 치과 인상용 트레이의 유지력에 관한 연구)

  • Lee, In-Seob;Lee, jin-Han;Kim, Yu-Lee;Dong, Jin-Keun
    • Journal of Dental Rehabilitation and Applied Science
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    • v.22 no.1
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    • pp.11-21
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    • 2006
  • The adjustable dental impression trays were made for being adjusted their width automatically along the width of patient's dental arch. The purpose of this study was to investigate the retentive force of adjustable dental impression trays made of different synthetic resin materials. Three pairs of adjustable trays were made of ABS(acrylonitrile butadiene styrene) synthetic resin, polyurethane synthetic resin and polycarbonate synthetic resin with a hole and without a rim on the border area of them. The experiment was done with the horse-shoe shaped metal plate to pull out the set impression body from the tray jig which was made for holding the tray on the lower part of Universal Testing Machine(UTM, Zwick Z020, Zwick Co., Germany). After the alginate impression in the tray was allowed to set four minutes, a tensile force was applied at right angles to the tray which had been previously seated on the jig. The force was applied to measure a maximum force by use of UTM at a constant strain rate 100mm per minute. The results obtained in this study were as follows : 1. The upper trays were showed higher retentive force than lower trays in three tray materials. 2. There was no significant difference in the retentive force of the tray materials(p>0.05).

Effect of 1,3-Diphenyl-guanidine (DPG) Mixing Step on the Properties of SSBR-silica Compounds

  • Lim, Seok-Hwan;Lee, Sangdae;Lee, Noori;Ahn, Byeong Kyu;Park, Nam;Kim, Wonho
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.81-92
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    • 2016
  • 1,3-Diphenylguanidine (DPG) is commonly used as a secondary accelerator which not only acts as booster of cure but also activating silanization reaction. The aim of this study is to increase the interaction between silica and rubber by using DPG. In this study, mixing was proceeded in two steps. The T-1 compound is mixed DPG with silica and silane coupling agent in the kneader at high temperature which is named as $1^{st}$ mixing step. T-3 compound is mixed DPG with curatives in the two-roll mill at low temperature which is named as $2^{nd}$ mixing step. The T-2 compound is mixed a half of DPG in $1^{st}$ mixing step and the remainder is mixed in $2^{nd}$ mixing step. Total DPG content was equal for all compounds. When DPG is mixed with silica, silane coupling agent during the $1^{st}$ mixing step, a decrease in cure rate and an increase in scorch time can be seen. This indicates that DPG is adsorbed on the surface of silica. during rubber processing. However, bound rubber content is increased and dynamic properties are improved. These results are due to the highly accelerated silanization reaction. However, there are no significant difference in 100%, 300% modulus.

Work Environments and Exposure to Hazardous Substances in Korean Tire Manufacturing

  • Lee, Na-Roo;Lee, Byung-Kyu;Jeong, Si-Jeong;Yi, Gwang-Yong;Shin, Jung-Ah
    • Safety and Health at Work
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    • v.3 no.2
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    • pp.130-139
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    • 2012
  • Objectives: The purpose of this study is to evaluate the tire manufacturing work environments extensively and to identify workers' exposure to hazardous substances in various work processes. Methods: Personal air sampling was conducted to measure polycyclic aromatic hydrocarbons, carbon disulfide, 1,3-butadiene, styrene, methyl isobutyl ketone, methylcyclohexane, formaldehyde, sulfur dioxide, and rubber fume in tire manufacturing plants using the National Institute for Occupational Safety Health Manual of Analytical Methods. Noise, carbon monoxide, and heat stress exposure were evaluated using direct reading instruments. Past concentrations of rubber fume were assessed using regression analysis of total particulate data from 2003 to 2007, after identifying the correlation between the concentration of total particulate and rubber fume. Results: Workers were exposed to rubber fume that exceeded 0.6 mg/$m^3$, the maximum exposure limit of the UK, in curing and production management processes. Forty-seven percent of workers were exposed to noise levels exceeding 85 dBA. Workers in the production management process were exposed to $28.1^{\circ}C$ (wet bulb globe temperature value, WBGT value) even when the outdoor atmosphere was $2.7^{\circ}C$ (WBGT value). Exposures to other substances were below the limit of detection or under a tenth of the threshold limit values given by the American Conference of Governmental Industrial Hygienists. Conclusion: To better classify exposure groups and to improve work environments, examining closely at rubber fume components and temperature as risk indicators in tire manufacturing is recommended.

Effect of Surfactant on the Physical Properties and Crosslink Density of Silica Filled ESBR Compounds and Carbon Black Filled Compounds

  • Hwang, Kiwon;Kim, Woong;Ahn, Byungkyu;Mun, Hyunsung;Yu, Eunho;Kim, Donghyuk;Ryu, Gyeongchan;Kim, Wonho
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.39-47
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    • 2018
  • Styrene-butadiene rubber (SBR) is widely used in tire treads due to its excellent abrasion resistance, braking performance, and reasonable cost. Depending on the polymerization method, SBR is classified into solution-polymerized SBR (SSBR) and emulsion-polymerized SBR (ESBR). ESBR is less expensive and environmentally friendlier than SSBR because it uses water as a solvent. A higher molecular weight is also easier to obtain in ESBR, which has advantages in mechanical properties and tire performance. In ESBR polymerization, a surfactant is added to create an emulsion system with a hydrophobic monomer in the water phase. However, some amount of surfactant remains in the ESBR during coagulation, making the polymer chains in micelles clump together. As a result, it is well-known that residual surfactant adversely affects the physical properties of silica-filled ESBR compounds. However, researches about the effect of residual surfactant on the physical properties of ESBR are lacking. Therefore, in this study we compared the effects of remaining surfactant in ESBR on the mechanical properties of silica-filled and carbon black-filled compounds. The crosslinking density and filler-rubber interaction are also analyzed by using the Flory-Rehner theory and Kraus equation. In addition, the effects of surfactant on the mechanical properties and crosslinking density are compared with the effects of TDAE oil (a conventional processing aid).

Influence of Molecular Size of Liquid BR on Properties of Silica-Filled SBR Compounds (액상 BR의 분자 크기가 실리카로 보강된 SBR 배합물의 특성에 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.36 no.3
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    • pp.162-168
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    • 2001
  • Low molecular weight polybutadiene (liquid BR) improves the filler dispersion in a silica-filled styrene-butadiene rubber (SBR) compound. In the present work, influence of molecular weight or the liquid BR on properties of a silica-filled SBR compound was studied. Minimum and maximum torques in the rheocurve for the compound containing the liquid BR with higher molecular weight (HLBR) are lower than those for the compound containing the liquid BR with lower one (LLBR) while the delta torques are nearly the same. Mooney scorch time of the compound containing HLBR is faster than that of the compound containing LLBR. Modulus or the compound containing HLBR is lower than that of the compound containing LLBR while tensile strength of the former is higher than that of the latter. The elongation at break of the former is also longer than that of the latter. Stability for the thermal aging at $90^{\circ}C$ for 3 days is less favorable for the former than for the latter.

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Effect of Addition of Ground Granulated Blast-furnace Slag on Strength Properties of Autoclaved Polymer-Modified Concrete (오토클레이브 양생 폴리머 시멘트 콘크리트의 강도성상에 미치는 고로슬래그 미분말 혼입의 영향)

  • 주명기
    • Journal of the Korea Concrete Institute
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    • v.14 no.4
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    • pp.608-614
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    • 2002
  • The effects of slag content and polymer-binder ratio on the strength properties of autoclaved SBR-modified concretes using ground granulated blast-furnace slag(slag) and a styrene-butadiene rubber (SBR) latex are examined. As a result, the compressive and tensile strengths of the autoclaved SBR-modified concretes using slag increase with increasing slag content, and reach a maximum at a slag content 40%, and increase with increasing polymer-binder ratio. In particular, the autoclaved SBR-modified concretes with a slag content of 40% provide about three times higher tensile strength than unmodified concretes. Such high strength development is attributed to the high tensile strength of SBR polymer and the improved bond between cement hydrates and aggregates because of the addition of SBR latex.

An Experimental Study on the Mechanical Properties of Fiber Reinforced Fly Ash.Lime.Gypsum Composites (섬유보강 플라이애쉬.석고.복합체의 역학적특성에 관한 실험적 연구)

  • 박승범
    • Magazine of the Korea Concrete Institute
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    • v.5 no.4
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    • pp.145-155
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    • 1993
  • The results of an experimental study on the manufacture and the mechanical properties of fiber reinforced fly ash$\cdot$lime$\cdot$gypsum composites are presented in this paper. 'The composites using fly ash, lime, and gypsum were prepared with various fibers (PAN-derived and Pitch-derived carbon fiber, alkali-resistance glass fiber) and a small amount of polymer emulsion-styrene butadiene rubber latex (SBR). As the test results show, the manufacturing process technology of fly ash$\cdot$lime$\cdot$gypsum composites was developed and its optimum mix proportions were successfully proposed. And the flexural strength and toughness of fiber reinforced fly ash$\cdot$lime $\cdot$gypsum composites were increased remarkably by fiber contents, but the compressive strength of the composites were influenced by the kinds fiber more than by the fiber contents. Also, the addition of a polymer emulsion to the composites decreased the bulk specific gravity, but the compressive and flexural strength, and the toughness of the composites were not influenced by it, but were considerably improved by increasing fiber contents.