• Applied Microscopy
• /
• 제46권4호
• /
• pp.217-226
• /
• 2016

Monolayer hexagonal boron nitride (h-BN) is a phenomenal two-dimensional material; most of its physical properties rival those of graphene because of their structural similarities. This intriguing material has thus spurred scientists and researchers to develop novel synthetic methods to attain scalability for enabling its practical utilization. When probing the growth behaviors and structural characteristics of h-BN, the use of appropriate characterization techniques is important. In this review, we detail the use of scanning and transmission electron microscopies to investigate the atomic configurations of monolayer and bilayer h-BN grown via chemical vapor deposition. These advanced microscopy techniques have been demonstrated to provide intimate insights to the atomic structures of h-BN, which can be interpreted directly or indirectly using known growth mechanisms and existing theoretical calculations. This review provides a collective understanding of the structural characteristics and defects of synthetic h-BN films and facilitates a better perspective toward the development of new and improved synthesis techniques.

• 한국전기전자재료학회논문지
• /
• 제14권11호
• /
• pp.879-884
• /
• 2001

In this paper, the structural and dielectric properties of (Sr$_{l-x}$Ca$_{x}$)TiO$_3$ (0$\leq$x$\leq$0.2) -based grain boundary layer ceramics were investigated by XRD, SEM and HP4194A. The ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 1420~152$0^{\circ}C$ and 4 hours, respectively. The average grain size and the lattice constant were decreased with increasing content of Ca. The average grain size was increased with increase of sintering temperature. The relative density of all specimens was 96~98%. The 2nd Phase formed by the thermal diffusion of CuO from the surface leads to very excellent dielectric properties, that is, $\varepsilon$$_{r}$>50000, tan $\delta$<0.05, $\Delta$C<$\pm$10%. The appropriate Ca content was under 15 ㏖%.s under 15 ㏖%.%.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2000년도 하계학술대회 논문집
• /
• pp.387-390
• /
• 2000

The $Al_2$O$_3$specimens were prepared by the conventional mixed oxide method with addition La$_2$O$_3$, Bi$_2$O$_3$. The specimens were sintered at 15$25^{\circ}C$, 5hr., in air. The structural properties of the specimens were investigated by XRD and SEM. The $Al_2$O$_3$ceramics with dopants had hexagonal structure and didn't show secondary phases. In the case of specimens with 0.25wt% La$_2$O$_3$and 0.25wt% Bi$_2$O$_3$bulk densities and lattice parameter of c/a were 3.818g/cm$^3$, 3.783g/cm$^3$and ca=2.725, c/a=2.723, respectively. The bulk densities of $Al_2$O$_3$ceramics were decreased with dopants.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
• /
• pp.466-467
• /
• 2005

Al doped zinc oxide films (ZnO:Al) were deposited on glass substrate by RF magnetron sputtering from a ZnO target mixed with 2 wt% $Al_2O_3$. The as-deposited ZnO:Al films were rapid-thermal annealed. Electrical properties and structural evolution of the films, as annealed by rapid thermal process (RTP), were studied and compared with the films annealed by conventional annealing process. RTP, the (002) peak intensity increases and the electrical resistivity decreases by 20%, after RT annealing. The effects of RT annealing on the structural evolution and electrical properties of RF sputtered films were further discussed and compared also with the films deposited by DC magnetron sputtering.

• 한국전기전자재료학회논문지
• /
• 제24권3호
• /
• pp.177-181
• /
• 2011

We have studied structural, optical, and electrical properties of the Al-doped ZnO (AZO) thin films being usable in transparent conducting oxides. The AZO thin films were deposited on the corning 1737 glass plate by the RF magnetron sputtering system. To find optimal properties of AZO for transparent conducting oxides, the RF power in sputtering process was varied as 40 W, 60 W, and 80 W, respectively. As RF power increased, the crystallinity of AZO thin film was decreased, the optical bandgap of AZO thin film increased. The transmittance of the film was over 80% in the visible light range regardless of the changes in RF power. The measurement of Hall effect characterizes the whole thin film as n-type, and the electrical property was improved with increasing RF power. The structural, optical, and electrical properties of the AZO thin films were affected by Al dopant content in AZO thin film.

• 한국재료학회지
• /
• 제20권3호
• /
• pp.148-154
• /
• 2010

It is necessary to develop new methods to prevent catastrophic failure of structural material in order to avoid accidents and conserve natural and energy resources. Design of intelligent materials with a self-diagnosing function to prevent fatal fracture of structural materials was achieved by smart composites consisting of carbon fiber tows or carbon powders with a small value of ultimate elongation and glass fiber tows with a large value of ultimate elongation. The changes in electrical resistance of CF-GFRP/GFRP (carbon fiber and glass fiber-reinforced plastics/glass fiber-reinforced plastics) composites increased abruptly with increasing strain, and a tremendous change was seen at the transition point where carbon fiber tows were broken. Therefore, the composites were not to monitor damage from the early stage. On the other hand, the change in electrical resistance of CP-GFRP/GFRP (carbon powder dispersed in glass fiber-reinforced plastics/glass fiber-reinforced plastics) composites increased almost linearly in proportion to strain. CP-GFRP/GFRP composites are superior to CF-GFRP/GFRP composites in terms of their capability to monitor damage by measuring change in electrical resistance from the early stage of damage. However, the former was inferior to the latter as an application because of the difficulties of mass production and high cost. A method based on monitoring damage by measuring changes in the electrical resistance of structural materials is promising for improved reliability of the material.

• Coupled systems mechanics
• /
• 제6권1호
• /
• pp.29-40
• /
• 2017

This work employed density functional theory to investigate the structural and ferroelectric properties of the Ruddlesden-Popper (RP) phase of lead titanate, $Pb_2TiO_4$, as well as its phase transitions with epitaxial strain. A wealth of novel structural instabilities, which are absent in the host $PbTiO_3$ material, were identified in the RP phase through phonon soft-mode analysis. Our calculations showed that the ground state of $Pb_2TiO_4$ is antiferroelectric, distinct from the dominant ferroelectric phase in the corresponding host material. In addition, applied epitaxial strain was found to play a key role in the interactions among the instabilities. The induction of a sequence of antiferroelectric and antiferrodistortive (AFD) phase transitions by epitaxial strain was demonstrated, in which the ferroic instability and AFD distortion were cooperative rather than competitive, as is the case in the host $PbTiO_3$. The RP phase in conjunction with strain engineering thus represents a new approach to creating ferroic orders and modifying the interplay among structural instabilities in the same constituent materials, enabling us to tailor the functionality of perovskite oxides for novel device applications.

• Advances in concrete construction
• /
• 제1권1호
• /
• pp.1-27
• /
• 2013

Discrete steel fibres can increase significantly the bending and the shear resistance of concrete structural elements when Steel Fibre Reinforced Concrete (SFRC) is designed in such a way that fibre reinforcing mechanisms are optimized. To assess the fibre reinforcement effectiveness in shallow structural elements failing in bending and in shear, experimental and numerical research were performed. Uniaxial compression and bending tests were executed to derive the constitutive laws of the developed SFRC. Using a cross-section layered model and the material constitutive laws, the deformational behaviour of structural elements failing in bending was predicted from the moment-curvature relationship of the representative cross sections. To evaluate the influence of the percentage of fibres on the shear resistance of shallow structures, three point bending tests with shallow beams were performed. The applicability of the formulation proposed by RILEM TC 162-TDF for the prediction of the shear resistance of SFRC elements was evaluated. Inverse analysis was adopted to determine indirectly the values of the fracture mode I parameters of the developed SFRC. With these values, and using a softening diagram for modelling the crack shear softening behaviour, the response of the SFRC beams failing in shear was predicted.

• 한국기계기술학회지
• /
• 제20권6호
• /
• pp.947-956
• /
• 2018

This research has been conducted to design upright parts of hand-made vehicles with the purpose of reducing material and machining cost while ensuring structural safety. Aluminum knuckles were modelled with three parts in order to enhance design flexibility as well as to reduce CNC machining cost. A vehicle model was constructed in CAD program and simulated in ADAMS View in order to estimate joint forces developing during 20 degree step steering condition at 60km/h. The joint forces obtained in the vehicle dynamics simulation were used for the structural analysis in ANSYS and dimensions of knuckle parts were adjusted until the lowest safety factor reached 2.0. The weight of knuckle decreased by 50% compared to the previous version that was designed without the structural analysis. The overall manufacturing cost decreased by 33% due to the reduction in the material as well as the CNC machining effort.

• Structural Engineering and Mechanics
• /
• 제77권5호
• /
• pp.673-689
• /
• 2021

This paper addresses the efficiency of thermal insulation layers applied to protect structural elements strengthened by fiber-reinforced polymers (FRP) in the case of fire event. The paper presents numerical modeling and nonlinear analysis of reinforced concrete (RC) columns externally strengthened by FRP and protected by thermal insulation layers when subjected to elevated temperature specified by standard fire tests, in order to predict their residual capacity and fire endurance. The adopted numerical approach uses commercial software includes heat transfer, variation of thermal and mechanical properties of concrete, steel reinforcement, FRP and insulation material with elevated temperature. The numerical results show good agreement with published results of full-scale fire tests. A parametric study was conducted to investigate the influence of several variables on the structural response and residual capacity of insulated FRP-confined columns loaded by service loads when exposed to fire. The residual capacity of FRP-confined RC column was affected by concrete grade and insulation material and was shown to improve substantially by increasing the concrete cover and insulation layer thickness. By increasing the VG insulation layer thickness 15, 32, 44, 57 mm, the loss in column capacity after 5 hours of fire was 30%, 13%, 7% and 5%, respectively. The obtained results demonstrate the validity of the presented approach for estimation of fire endurance and residual strength, as an alternative for fire testing, and for design of fire protection layers for FRP-confined RC columns.