• Korean Journal of Materials Research
• /
• v.20 no.5
• /
• pp.246-251
• /
• 2010

The composite photocatalysts of a Fe-modified carbon nanotube (CNT)-$TiO_2$ were synthesized by a two-step sol-gel method at high temperature. Its chemical composition and surface properties were investigated by BET surface area, scanning electron microscope (SEM), Transmission Electron Microscope (TEM), X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) spectroscopy. The results showed that the BET surface area was improved by modification of Fe, which was related to the adsorption capacity for each composite. Interesting thin layer aggregates of nanosized $TiO_2$ were observed from TEM images, probably stabilized by the presence of CNT, and the surface and structural characterization of the samples was carried out. The XRD results showed that the Fe/CNT-$TiO_2$ composites contained a mix of anatase and rutile forms of $TiO_2$ particles when the precursor is $TiOSO_4{\cdot}xH_2O$ (TOS). An excellent photocatalytic activity of Fe/CNT-$TiO_2$ was obtained for the degradation of methylene blue (MB) under visible light irradiation. It was considered that Fe cation could be doped into the matrix of $TiO_2$, which could hinder the recombination rate of the excited electrons/holes. The photocatalytic activity of the composites was also found to depend on the presence of CNT. The synergistic effects among the Fe, CNT and $TiO_2$ components were responsible for improving the visible light photocatalytic activity.

• Composites Research
• /
• v.17 no.3
• /
• pp.1-7
• /
• 2004

In the vacuum assisted RTM (VARTM) process that has become the center of attention for manufacturing massive composite structures, a good evacuation of air in the fiber preform is recognized as the prime factor. The microvoids, or the dry spots, are formed as a result of improper gate/vent locations and the mold geometry. The non-uniform resin velocity at the flow front leads to the formation of microvoids in the fibers, whereas the air in the microvoids can migrate along with the resin flow during mold filling. The residual air in the internal voids of a composite structure may cause a degradation of the mechanical properties as well as the structural failure. In this study, a unified macro- and micro analysis methods were developed to investigate the formation and transport of air in resin during VARTM process. A numerical simulation program was developed to analyze the three-dimensional flow pattern as well as the macro- and microscopic distribution of air in a composite part fabricated by VARTM process.

• Composites Research
• /
• v.30 no.6
• /
• pp.371-378
• /
• 2017

In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.36 no.12
• /
• pp.1535-1542
• /
• 2012

A Heat Recovery Steam Generator(HRSG) is the main component of a Combined Cycle Power Plant(CCPP). It is a very large structure that is made from relatively thin metal sheets. Therefore, the structural integrity of an HRSG is very important to ensure safe operation during plant lifetime. In particular, thermal deformation and thermal fatigue have been revealed as the main causes of the mechanical degradation of an HRSG. In order to prevent unexpected damage, safety evaluation based on a large-scale analysis is necessary. Therefore, this study aims to improve the safety of HRSG by using Finite Element Analysis(FEA) results derived from large-scale analysis. Furthermore, the modified design is verified by comparing it with the original one. This result will be used as basic data for improving the safety of a vertical-type HRSG.

• Journal of Korean Society of Steel Construction
• /
• v.10 no.2 s.35
• /
• pp.201-209
• /
• 1998

The presence of elevated temperature can alter significantly the structural response of fibre-reinforced laminated composites. A thermal environment causes degradation in both strength and constitutive properties, particularly in the case of fibre-reinforced polymeric composites. Furthermore, associated thermal expansion, either alone or in combination with mechanically induced deformation, can result in buckling, large deflections, and excessively high stress levels. Consequently, it is often imperative to consider environmental effects in the analysis and design of laminated systems. Exact analytical solutions of higher-order shear deformation theory is developed to study the thermal buckling of cross-ply and antisymmetric angle-ply rectangular plates. The buckling behavior of moderately thick cross-ply and antisymmetric angle-ply laminates that are simply supported and subject to a uniform temperature rise is analyzed. Numerical results are presented for fiber-reinforced laminates and show the effects of ply orientation, number of layers, plate thickness, and aspects ratio on the critical buckling temperature and compared with those obtained using the classical and first-order shear deformation theory.

• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.14 no.3
• /
• pp.1-14
• /
• 2011

In order to determine temporal changes of the urban landscape, interdependence and interaction among geo-spatial objects can be analyzed using GIS analytic methods. In this study, to investigate changes in the landscape structure of the Namyangju area, the size and shape of landscape patches, and the distance between the patches were analyzed with the Spatial Autocorrelation Method. In addition, both global and local spatial autocorrelation analyses were conducted. The results of global Moran's I revealed that both patch size and shape index transformed to a more dispersed pattern over time. Next, the local Moran's I of patch size in all time series determined that almost all patches were of a high-low pattern. Meanwhile, the local Moran's I of the shape index was found to have changed from a high-high pattern to a high-low pattern in time series. Finally, as time passes, the number of hot spot patches about size and shape index had been decreased according to the results of hot spot analysis. These changes appeared around the development projects in the study area. From the results of this study, degradation of landscape patches in Namyangju were ascertained and their specific areas were delineated. Such results can be used as useful data in selecting areas for conservation and for preparing plans and strategies in environmental restoration.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• v.14 no.7
• /
• pp.2938-2956
• /
• 2020

Objective image quality assessment (IQA) models have been developed by effective features to imitate the characteristics of human visual system (HVS). Actually, HVS is extremely sensitive to color degradation and complex texture changes. In this paper, we firstly reveal that many existing full reference image quality assessment (FR-IQA) methods can hardly measure the image quality with contrast and masking texture changes. To solve this problem, considering texture masking effect, we proposed a novel FR-IQA method, called Texture and Color Quality Index (TCQI). The proposed method considers both in the masking effect texture and color visual perceptual threshold, which adopts three kinds of features to reflect masking texture, color difference and structural information. Furthermore, random forest (RF) is used to address the drawbacks of existing pooling technologies. Compared with other traditional learning-based tools (support vector regression and neural network), RF can achieve the better prediction performance. Experiments conducted on five large-scale databases demonstrate that our approach is highly consistent with subjective perception, outperforms twelve the state-of-the-art IQA models in terms of prediction accuracy and keeps a moderate computational complexity. The cross database validation also validates our approach achieves the ability to maintain high robustness.

• Journal of Periodontal and Implant Science
• /
• v.27 no.1
• /
• pp.19-43
• /
• 1997

The barrier membranes for GTR procedure could be affected bY bacterial contamination after exposure to oral environment. This study was done to evaluate whether the tetracycline impregnated barrier membranes could inhibit bacterial attachment and penetration into membranes. The resorbable membrane(polylactic and polyglycolide copolymer, $Resolute^{(R)}$, W.L Gore and Associates, Inc..USA) and the non-resorbable membrane(e-PTFE; Gore-TexTM, W.L. Gore & Associates, Inc.,USA) were cut into 4mm discs and trated with 5% tridodecylmethylammonium chloride solution in ethanol and dried in air. The membranes were immersed in tetracycline(TC) solution (100mg/ml, pH 8.0) and dried. To the maxillary canine-premolar region in six periodontally healthy volunteers, removable acrylic devices were inserted, on which 8 cylindrical chambers were glued with TC impregnated and non-impregnated discs, the membrane discs were examined for bacterial attachment and penetration, and structural changes under SEM and LM. From the 1st day to the 7th day, membranes showed bacterial plaque formation composed of cocci and rods. Thereafter, filamentous bacteria appeared and the plaque thickness increased. The TC impregnated e-PTFE membranes showed less bacterial attachment and delayed in bacterial plaque maturation than non-treated membranes. As for bacterial penetration, the TC impregnated e-PTFE membranes showed superficial invasion and infrequent presence of bacteria in unexposed inner surface at the 4th week. while the non-treated e-PTFE membranes showed deep bacterial invasion at the 2nd week and frequent presence of internal bacteria at the 4th week. The resorbable membranes started to be resorbed at the 2nd week and were perforated at the 4th week, regardless of TC treatment. In conclusion, bacterial plaque formation and penetration was efficiently delayed in TC impregnated e-PTFE membranes, whereas resorbable membranes were similar in bacterial invasion due to membrane degradation and perforation, regardless of TC treatment.

• Journal of KIISE:Software and Applications
• /
• v.30 no.1_2
• /
• pp.140-152
• /
• 2003

An XML document has a structure which may be irregular. It is difficult for end-users to comprehend the irregular document structure exactly. For these XML documents, an end-user has a difficulty in using structured query. Therefore, an end-user formulates no structured query or a query which has a little structure information. In this context, we propose new retrieval models which use the structured information for ranking and compensate the difference between user query structure and document structure. To ease with querying, we assume the independence among querying paths which represent structural constraints. Since this assumption makes degradation of the expression power of a query language, we also propose a model which overcome this problem. As there had been no test collections for XML documents, we made a small test collection from TIPSTER of the RTEC and experimented on this collection without a structured query, From this experiment, we showed that our models improve average precision about 67% over conventional Vector-Space model.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.27 no.3
• /
• pp.115-121
• /
• 2017

The degradation of the concrete due to deterioration factors, such as corrosion of steel bars, cracks and structural strength of reinforced concrete structures, is a social problem. Especially, concrete structures constructed in seawater, underground water, waste water treatment facilities and sewerage are subject to chemical attack by acid and sulphate. Therefore, this study was conducted to compare sulfated glass and fine aggregate of slag using waste glass fine powder and meta kaolin. The results showed that the slag fine aggregate showed better sulfate resistance than the river sand, and the fine powder of waste glass showed the best performance at 3 % displacement.