• Applied Biological Chemistry
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• v.26 no.1
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• pp.53-57
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• 1983

Butachlor incubated for certain periods of time under the simulated, rather aerobic, rice-paddy conditions of two different soils exhibited two major degradation products. 2,6-diethyl-N-(butoxymethyl) acetanilide and a new product C in all cases, and a relativly small amount of another new product D named tentatively as 8-ethyl-2-hydroxy-N-(butoxymethyl)-3,4-dihydroquinoline in some cases. The supposedly microbial degradation seemed to proceed with incubation periods to some extent. An anaerobic incubation in the previous investigation showed 2,6-diethyl-N-(butoxymethyl) acetanilide as the major product, whereas the new product C with m/z 291 turned out to be the major one in the present condition. Structural elucidation of the products was done based on the fragmentation patterns of the given mass spectra and a possible pathway for their formation was postulated.

• Environmental Engineering Research
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• v.24 no.4
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• pp.670-679
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• 2019

Lignin complexity molecule makes its biodegradation difficult during lignocellulosic wastes composting. So, the improvement of its biodegradation has usually been considered as an objective. This study aimed to determine the impact of Trametes trogii inoculation on organic matter and particularly on lignin and cellulose during green wastes co-composting with olive mill waste water sludge and coffee grounds. Three types of heaps (H1, H2 and H3) were investigated during 180 d. H3 and H2 were inoculated at the beginning of the process (t₀) and 120 d later (t₁₂₀), respectively while H1 was the control. Results showed the absence of pH stabilization in H3 during the first month. Also, in this period we observed a faster degradation of some easily available organic matter in H3 than in the other heaps. After 120 d, a better cellulose decomposition (25.28%) was noticed in H3 than in H1 and H2 (16%). Inoculation during the second fermentation phase induced supplementary lignin degradation in H2 with a percentage of 35% against 23 and 26% for H1 and H3, respectively. For all the runs, a Fourier Transform Infrared analysis showed aliphatic groups' decrease, OH groups' increase and lignin structural modification.

• Journal of the Korean Society for Railway
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• v.15 no.2
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• pp.109-115
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• 2012

In order to evaluate the effect of structural degradation of a GFRP composite bogie frame due to ballast-flying phenomena, the impact test and residual compression test after impact was conducted for glass fiber/epoxy 4-harness satin woven laminate composites applied to skin part of a bogie frame. The impact test was performed using a instrumented impact testing system with energy levels of 5J, 10J, and 20J, and the impactor was designed to have various ballast shapes such as sphere, cube, and cone to consider the ballasted track environments. The residual compression strength was tested to evaluate the degradation of mechanical properties of impact-damaged laminate composites. The results showed that the damage area and the degradation of residual compressive strength after impact for laminate composites was increased with increase of impact energy for all ballast shapes, and was particularly most influenced by ballast shape of cone.

• Korean Journal of Materials Research
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• v.24 no.1
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• pp.6-12
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• 2014

In the present work, $WO_3$ and $WO_3-TiO_2$ were prepared by the chemical deposition method. Structural variations, surface state and elemental compositions were investigated for preparation of $WO_3-TiO_2$ sonocatalyst. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and transmission electron microscopy (TEM) were employed for characterization of these new photocatalysts. A rhodamine B (Rh.B) solution under ultrasonic irradiation was used to determine the catalytic activity. Excellent catalytic degradation of an Rh.B solution was observed using the $WO_3-TiO_2$ composites under ultrasonic irradiation. Sonocatalytic degradation is a novel technology of treating wastewater. During the ultrasonic treatment of aqueous solutions sonoluminescence, cavitaties and "hot spot" occurred, leading to the dissociation of water molecules. In case of a $WO_3$ coupled system, a semiconductor coupled with two components has a beneficial role in improving charge separation and enhancing $TiO_2$ response to ultrasonic radiations. In case of the addition of $WO_3$ as new matter, the excited electrons from the $WO_3$ particles are quickly transferred to $TiO_2$ particle, as the conduction band of $WO_3$ is 0.74 eV which is -0.5 eV more than that of $TiO_2$. This transfer of charge should enhance the oxidation of the adsorbed organic substrate. The result shows that the photocatalytic performance of $TiO_2$ nanoparticles was improved by loading $WO_3$.

• Asian-Australasian Journal of Animal Sciences
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• v.32 no.11
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• pp.1686-1694
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• 2019

Objective: Lignin plays a relevant role in the inhibition of cell wall (CW) structural carbohydrate degradation. Thus, obtaining accurate estimates of the lignin content in tropical plants is important in order to properly characterize the mechanism of lignin action on CW degradation. Comparing conflicting results between the different methods available for commercial use will bring insight on the subject. This way, providing data to better understand the relationship between lignin concentration and implications with tropical forage degradation. Methods: Five grass species, Brachiaria brizantha cv $Marand{\acute{u}}$, Brachiaria brizantha cv $Xara{\acute{e}}s$(MG-5), Panicum maximum cv Mombaça, Pennisetum purpureum cv Cameroon, and Pennisetum purpureum cv Napier, were harvested at five maturity stages. Acid detergent lignin (ADL), Klason lignin (KL), acetyl bromide lignin (ABL), and permanganate lignin (PerL) were measured on all species. Lignin concentration was correlated with in vitro degradability. Results: Highly significant effects for maturity, lignin method and their interaction on lignin content were observed. The ADL, KL and ABL methods had similar negative correlations with degradability. The PerL method failed to reliably estimate the degradability of tropical grasses, possibly due to interference of other substances potentially soluble in the $KMnO_4$ solution. Conclusion: ADL and KL methods use strong acid ($H_2SO_4$) and require determination of ash and N content in the lignin residues, therefore, increasing time and cost of analysis. The ABL method has no need for such corrections and is a fast and a convenient method for determination of total lignin content in plants, thus, it may be a good option for routine laboratory analysis.

• Structural Engineering and Mechanics
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• v.60 no.6
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• pp.1063-1077
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• 2016

Components manufactured from composite materials are frequently subjected to superimposed mechanical and thermal loadings during their operating service. Both types of loadings may cause fracture and failure of composite structures. When composite cross-ply laminates of type [$0_m/90_n]_s$ are subjected to uni-axial tensile loading, different types of damage are set-up and developed such as matrix cracking: transverse and longitudinal cracks, delamination between disoriented layers and broken fibers. The development of these modes of damage can be detrimental for the stiffness of the laminates. From the experimental point of view, transverse cracking is known as the first mode of damage. In this regard, the objective of the present paper is to investigate the effect of transverse cracking in cross-ply laminate under thermo-mechanical degradation. A Finite Element (FE) simulation of damage evolution in composite crossply laminates of type [$0_m/90_n]_s$ subjected to uni-axial tensile loading is carried out. The effect of transverse cracking on the cross-ply laminate strength under thermo-mechanical degradation is investigated numerically. The results obtained by prediction of the numerical model developed in this investigation demonstrate the influence of the transverse cracking on the bearing capacity and resistance to damage as well as its effects on the variation of the mechanical properties such as Young's modulus, Poisson's ratio and coefficient of thermal expansion. The results obtained are in good agreement with those predicted by the Shear-lag analytical model as well as with the obtained experimental results available in the literature.

• Structural Engineering and Mechanics
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• v.81 no.1
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• pp.11-28
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• 2022

This paper considers the combination of cyclic and axial loads to investigate the hysteretic performance of H-section 6061-T6 aluminum alloy members. The hysteretic performance of aluminum alloy members is the basis for the seismic performance of aluminum alloy structures. Despite the prevalence of aluminum alloy reticulated shells structures worldwide, research into the seismic performance of aluminum alloy structures remains inadequate. To address this deficiency, we design and conduct cyclic axial load testing of three H-section members based on a reliable testing system. The influence of slenderness ratios and bending direction on the failure form, bearing capacity, and stiffness degradation of each member are analyzed. The experiment results show that overall buckling dominates the failure mechanism of all test members before local buckling occurs. As the load increases after overall buckling, the plasticity of the member develops, finally leading to local buckling and fracture failure. The results illustrate that the plasticity development of the local buckling position is the main reason for the stiffness degradation and failure of the member. Additionally, with the increase of the slenderness ratio, the energy-dissipation capacity and stiffness of the member decrease significantly. Simultaneously, a finite element model based on the Chaboche hybrid strengthening model is established according to the experiment, and the rationality of the constitutive model and validity of the finite element simulation method are verified. The parameter analysis of twenty-four members with different sections, slenderness ratios, bending directions, and boundary conditions are also carried out. Results show that the section size and boundary condition of the member have a significant influence on stiffness degradation and energy dissipation capacity. Based on the above, the appropriate material constitutive relationship and analysis method of H-section aluminum alloy members under cyclic loading are determined, providing a reference for the seismic design of aluminum alloy structures.

• Applied Chemistry for Engineering
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• v.34 no.1
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• pp.30-35
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• 2023

The glass bead surface was coated using a TiO₂ sol, after which dry-treated (TB) and calcined (TBc) samples were prepared. Photocatalytic degradation of methylene blue and toluene, as well as characterization of the TiO₂ thin films, were carried out. The TiO₂ thin film of the TB sample had the same shape as the sponge foam, according to FE-SEM, XPS, and FTIR analyses, and contained both amorphous and crystalline TiO₂. On the other hand, crystalline TiO₂ was mainly present in the TiO₂ thin film of the TBc sample, and needle-shaped particles and tiny ones were mixed. The adsorption capacity for methylene blue and the degradation rate of the TBc sample were less than 10 % compared with those of the TB sample, and the adsorption capacity and degradation rate of the TBc sample decreased similarly as the amount of TiO₂ coating increased. The amount of toluene adsorption for the TBc sample (46 mg/g) was smaller than that of the TB sample with the same coating amount, but the degradation rate was similar. In the case of the TB sample, the degradation rate for toluene decreased less than the adsorption capacity as the amount of TiO₂ coating increased. This result is considered to be because, in the non-calcined TB sample, the active site reduction of the crystalline particles occurred less and the specific surface area of the amorphous texture decreased as the amount of TiO₂ coating increased.

• Journal of the Korea Concrete Institute
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• v.23 no.5
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• pp.637-645
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• 2011

It is well known that high strength concrete with compressive strength higher than 50 MPa shows severe material and structural damages under fire due to spalling. To understand degradation of structural capacity of fire damaged high strength concrete structures, not only thermo-mechanical behavior needs to be defined, but also structural behavior of high strength concrete member under high temperature needs to be investigated. In this study, structural tests are performed by applying axial loads on high strength concrete columns exposed at elevated temperatures for assigned amount of time. The tested columns are prepared to have different concrete strength and polypropylene fiber percentage. The test results show that structural capacity of the columns decreased with increased compressive strength of concrete under same heating condition. Especially, it is interesting to note that high strength concrete columns with polypropylene fiber for spalling proof did not improve structural capacity compared to the columns without polypropylene fiber. The findings from the test are able to improve fire proof design of high strength concrete structural members and predicting structural performance of fire damaged structural members.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.6
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• pp.55-61
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• 2023

In this study, a basic research was conducted to establish a maintenance plan considering the environmental factors and deterioration characteristics of port facilities. The precise safety diagnosis reports for Incheon and Busan port facilities were referenced to examine the extent of deterioration and damage. The relationship with the degradation environmental assessment presented in the current guidelines was also analyzed. The analysis of the damage level of Incheon and Busan port facilities revealed that Incheon Port exhibited approximately three times higher damage rate compared to Busan Port. In the case of Incheon Port, reinforcement corrosion and external damage showed similar proportions, while in Busan Port, reinforcement corrosion had a higher proportion compared to external damage. On the other hand, when comparing with the degradation environmental assessment presented in the guidelines, it was found that there were some limitations in performing quantitative evaluation based on the guidelines for assessing port facilities. Therefore, an analysis based on tidal range was conducted by referring to existing literature. The analysis of tidal range in Incheon and Busan regions showed that Incheon had approximately five times higher difference compared to Busan. It is considered that this can be utilized as a differentiated item from existing degradation environmental assessment criteria.