• 제목/요약/키워드: strong unit

검색결과 489건 처리시간 0.023초

Synthesis and Photovoltaic Properties of Polymers Based on Cyclopentadithiophene and Benzimidazole Units

  • Song, Su-Hee;Park, Sei-Jung;Kwon, Soon-Cheol;Shim, Joo-Young;Jin, Young-Eup;Park, Sung-Heum;Kim, Il;Lee, Kwang-Hee;Suh, Hong-Suk
    • Bulletin of the Korean Chemical Society
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    • 제33권6호
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    • pp.1861-1866
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    • 2012
  • The new semiconducting copolymers with 4,4-dialkyl-$4H$-cyclopenta[2,1-$b$:3,4-$b^{\prime}$]dithiophene and 2,2-dimethyl-$2H$-benzimidazole units were synthesized. The fused aromatic rings, such as cyclopentadithiophene (CPDT) unit, can make the polymer backbone more rigid and coplanar, which induces long conjugation length, narrow band gap, and strong intermolecular ${\pi}-{\pi}$ interaction. The stacking ability was controlled through attaching of linear or branched alkyl side chains. The spectra of PEHCPDTMBI and PHCPDTMBI in the solid films show absorption bands with maximum peaks at 401, 759 and 407, 768 nm, and the absorption onsets at 925 and 954 nm, corresponding to band gaps of 1.34 and 1.30 eV, respectively. The devices comprising PHCPDTMBI with $TiO_X$ showed a $V_{OC}$ of 0.39 V, a $J_{SC}$ of 1.14 $mA/cm^2$, and a $FF$ of 0.34, giving a power conversion efficiency of 0.15%. The PHCPDTMBI with linear alkyl chain on CPDT shows good solubility in organic solvent with higher PCE value than that of PEHCPDTMBI.

STARBURST AND AGN CONNECTIONS AND MODELS

  • SCOVILLE NICK
    • 천문학회지
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    • 제36권3호
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    • pp.167-175
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    • 2003
  • There is accumulating evidence for a strong link between nuclear starbursts and AGN. Molecular gas in the central regions of galaxies plays a critical role in fueling nuclear starburst activity and feeding central AGN. The dense molecular ISM is accreted to the nuclear regions by stellar bars and galactic interactions. Here we describe recent observational results for the OB star forming regions in M51 and the nuclear star burst in Arp 220 - both of which have approximately the same rate of star formation per unit mass of ISM. We suggest that the maximum efficiency for forming young stars is an Eddington-like limit imposed by the radiation pressure of newly formed stars acting on the interstellar dust. This limit corresponds to approximately 500 $L_{\bigodot} / M_{\bigodot}$ for optically thick regions in which the radiation has been degraded to the NIR. Interestingly, we note that some of the same considerations can be important in AGN where the source of fuel is provided by stellar evolution mass-loss or ISM accretion. Most of the stellar mass-loss occurs from evolving red giant stars and whether their mass-loss can be accreted to a central AGN or not depends on the radiative opacity of the mass-loss material. The latter depends on whether the dust survives or is sublimated (due to radiative heating). This, in turn, is determined by the AGN luminosity and the distance of the mass-loss stars from the AGN. Several AGN phenomena such as the broad emission and absorption lines may arise in this stellar mass-loss material. The same radiation pressure limit to the accretion may arise if the AGN fuel is from the ISM since the ISM dust-to-gas ratio is the same as that of stellar mass-loss.

초음파 조사에 의한 두부의 열 감도 (Thermal Sensitivity of the Bean Curd by Ultrasonic Irradiation)

  • 조문재;윤용현;부유천;김용태
    • 한국음향학회지
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    • 제23권7호
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    • pp.503-513
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    • 2004
  • 본 논문에서는 단위 음향파워에 대한 온도 변화인 열 감도 (thermal sensitivity)를 새로이 정의하였으며, 이 물리량으로 조직모사물질의 성능을 평가 할 수 있다는 것을 제안하였다. 실험에 사용된 시료는 공장에서 생산되는 식용 두부이고, 초음파의 주파수를 8 MHz로 고정하고 조사 (irradiation) 시간, 음향파워, 시료 표면으로 부터의 깊이 및 초음파 변환기와의 거리에 따른 온도 변화를 측정하였다. 아울러 깊이와 초음파 변환기와의 거리를 고정하고 일정한 음향파워 조건에서 주파수에 따른 온도 변화도 측정하였다. 측정된 온도변화를 열 감도로 변환하여 고찰한 결과 조직모사물질의 성능인자로 사용하기에 충분한 것으로 판명되었다. 특히 조직모사물질로 선택한 두부는 10 MHz 에서 열 감도가 최대로 나타났으며. 이 결과는 실제 인체 조직에서 열 감도가 주파수에 민감하게 의존 할 수 있다는 가능성을 함축하는 중요한 결과이다.

Gum guaiac 혼합물을 이용한 혈흔검출 예비시험의 평가와 혈흔의 유전자 분석에 미치는 효과 (Preliminary Test of Forensic Identification Bloodstain Using Guaiac Mixture and It's Effect on Genetic Analysis)

  • 임채원;김양호;김진각
    • 대한임상검사과학회지
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    • 제42권1호
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    • pp.22-31
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    • 2010
  • The most common sources of biological trace material which are found in crime scene are the human bloodstains. Reliable identification in the forensic casework is important as it provides crucial insights into crime scene reconstruction and can thus contribute towards solving crimes. Blood-stains are routinely tested in forensic practise using various methods including the leucomalachite green (LMG) test, Kastle-Meyer phenolphthalein test, tetramethylbenzidine test, orthotolidine test, or the luminol chemoluminescence test with the latter cleaning attempts. All these presumptive thus indicative but not identifying tests take advantage of the peroxidase-like activity of the heme unit of the hemoglobin molecule in human blood. Therefore, false-positive results can be caused by the presence of strong oxidants, such as chlorine-containing detergents or by true peroxidases (e.g., from plants). In this study, composition for Gum guaiac was evaluated for the forensic identification of bloodstain and compared with the LMG. The sensitivity and specificity of the composition for Gum guaiac were examined more stable in bloodstain. The positive of Composition for Gum guaiac shown even with the 100,000-fold diluted bloodstain, which was no difference in comparison with LMG test. It was shown that composition for Gum guaiac was very stable to resist boiling for 20 minutes and the effect of bacteria did not affect the genetic analysis as well. The above result of the crime scene investigation, composition for Gum guaiac is easily expected to help identifying bloodstain in the evidences.

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건강가정기본법의 이념과 체계 (The Ideologies and the Systems of the Healthy Family Act)

  • 조희금;박미석
    • 가정과삶의질연구
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    • 제22권5호
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    • pp.331-344
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    • 2004
  • Korean society recently realized the needs for a system that may effectively prevent and/or resolve different family problems caused by the rapidly changing modem society. In order to carry out this objectives. The Healthy Family Act has been legislated and is to be enforced from the 1st of January, 2005. Legislating the law is a means to establish an administrative and institutional structure that may bring in the total welfare system centered around family, so as to promote healthy families in our society. This is also a land marking event that has shifted the paradigm from the welfare system focusing on individual protection to the total welfare system based upon family units. Hence, this study is to examine the specific concepts of 'healthy family,' which is the goal of The Healthy Family Act, and thus to propose the objectives of the law by analysing the institutional system of it. The Healthy Family Act, which consists of major 37 items of 5 chapters with supplementary provisions, aims at the five ideals as follows. The first is to promote the healthy family which is the basis of individual welfare and well-to-do society. The second is to emphasize the importance of family and to provide total service system for family unit. The third is to establish the family value which supports gender-equality and democracy. The fourth is to reinforce the governmental support for independence and cooperation of family. And the fifth is to promote the in-advance and precautionary support for family problems. The law also includes administrative methods for Strong Families Center, different projects and programs for promoting healthy families, roles of Healthy Family Specialist and means to cultivating them, and the policies to specifically carry out the ideas of the law. It is now important to recognize that the development of nation is based on the healthy families and to put much effort in carrying out the ideas and goals of The Healthy Family Act.

PECCP LB 박막을 발광층으로 사용한 유기 발광 다이오드의 특성 (Characteristics of Organic Light-Emitting Diodes using PECCP Langmuir-Blodgett(LB) Film as an Emissive Layer)

  • Lee, Ho-Sik;Lee, Won-Jae;Park, Jong-Wook;Kim, Tae-Wan;Dou--Yol Kang
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.111-114
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    • 1999
  • Electroluminescence(EL) devices based on organic thin films have been attracted lots of interests in large-area light-emitting display. In this stuffy, an emissive layer was fabricated using Langmuir-Blodgett(LB) technique in organic light-emitting (OLEDs). This emissive organic material was synthesized and named PECCP[poly(3.6-N-2-ethylhexyl carbazolyl cyanoterephthalidene)] which has a strong electron donor group and an electron acceptor group in main chain repeated unit. This material has good solubility in common organic solvents such as chloroform. THF, etc, and has a good stability in air. The Langmuir-Blodgett(LB) technique has the advantage of precise control of the thickness down to the molecular scale, In particular, by varying the film thickness it is possible to investigate the metal/polymer interface. Optimum conditions for the LB film deposition are usually determined by investigating a relationship between a surface pressure $\pi$ and an effective are A occupied by one molecule on the subphase. The LB films were deposited on an indium-tin-oxide(ITO) glass at a surface pressure of 10 mN/m and dipping speed of 12 mm/min after spreading PECCP solution on distilled water surphase at room temperature, Cell structure was ITO/PECCP LB film/Alq$_3$/Al. We considered PECCP as a hole -transport layer inserted between the emissive layer and ITO. We also used Alq$_3$ as an emissive layer and an electron transport layer. We measured current-voltage(I-V) characteristics, UV/visible absorption, PL spectrum and EL spectrum of the OLEDs.

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성장온도에 따른 Cu(In1Ga)Se2박막 태양전지의 광전특성 분석 (Photovoltaic Properties of Cu(In1Ga)Se2Thin film Solar Cells Depending on Growth Temperature)

  • 김석기;이정철;강기환;윤경훈;송진수;박이준;한상옥
    • 한국전기전자재료학회논문지
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    • 제16권2호
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    • pp.102-107
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    • 2003
  • This study puts focus on the optimization of growth temperature of CIGS absorber layer which affects severely the performance of solar cells. The CIGS absorber layers were prepared by three-stage co-evaporation of metal elements in the order of In-Ga-Se. The effect of the growth temperature of 1st stage was found not to be so important, and 350$^{\circ}C$ to be the lowest optimum temperature. In the case of growth temperature at 2nd/3rd stage, the optimum temperature was revealed to be 550$^{\circ}C$. The XRD results of CIGS films showed a strong (112) preferred orientation and the Raman spectra of CIGS films showed only the Al mode peak at 173cm$\^$-1/. Scanning electron microscopy results revealed very small grains at 2nd/3rd stage growth temperature of 480$^{\circ}C$. At higher temperatures, the grain size increased together with a reduction in the number of the voids. The optimization of experimental parameters above mentioned, through the repeated fabrication and characterization of unit layers and devices, led to the highest conversion efficiency of 15.4% from CIGS-based thin film solar cell with a structure of Al/ZnO/CdS/CIGS/Mo/glass.

파력발전 적지 선정을 위한 제주 해역 파랑에너지 분포특성 연구 (Wave Energy Distribution at Jeju Sea and Investigation of Optimal Sites for Wave Power Generation)

  • 홍기용;류황진;신승호;홍석원
    • 한국해양공학회지
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    • 제18권6호
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    • pp.8-15
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    • 2004
  • Wave power distribution is investigated to determine the optimal sites for wave power generation at Jeju sea which has the highest wave energy density in the Korean coastal waters. The spatial and seasonal variation of wave power per unit length is calculated in the Jeju sea area based on the monthly mean wave data from 1979 to 2002 which is produced by the SWAN wave model simulation in prior research. The selected favorable locations for wave power generation are compared in terms of magnitude of wave energy density and distribution characteristics of wave parameters. The results suggest that Chagui-Do is the most optimal site for wave power generation in the Jeju sea. The seasonal distribution of wave energy density reveals that the highest wave energy density occurs in the northwest sea in the winter and it is dominated by wind waves, while the second highest one happens at south sea in the summer and it is dominated by a swell sea. The annual average of wave energy density shows that it gradually increases from east to west of the Jeju sea. At Chagui-Do, the energy density of the sea swell sea is relatively uniform while the energy density of the wind waves is variable and strong in the winter.

Louis I. Kahn의 미술관 건축에 나타난 평면구성에 관한 연구 - Yale University Art Gallery Extension을 중심으로 - (Plan Composition Expressed in the Architecture of Art Gallery Designed by Louis I. Kahn - Focus on the Yale University Art Gallery Extension -)

  • 김홍배
    • 한국실내디자인학회논문집
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    • 제21권3호
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    • pp.128-135
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    • 2012
  • The purpose of this study is to investigate and analyze the compositional elements of plan of art museums by selecting architectural works, which have strong symbolic meaning when evaluating value, from architectural works by Louis Kahn. First, the centrality of artworks, which are being displayed at the Yale Art Gallery, is complex. It includes three patterns of Void (spatial) Centrality+Symbolic Centrality+Functional Centrality among the five patterns suggested in this study. Second, the ratio system of interior space, which is expressed in the extension of the Yale Art Gallery, can be classified into the floor and walls. The floor used the square 1:1 ratio system. The ceiling used the grid patterns of equilateral triangles (regular tetrahedrons). It was applying a geometric ratio system when creating forms by using one side as a beam and the other sides as decorations of the ceiling. Third, the contours of interior space, which were expressed in Kahn's works, used the method of forming separate space according to the contouring rule (structural unit) defined by columns, and they were used in constructing the entire space through the integration of separate spaces. Fourth, according to the characteristics that were expressed by artworks displayed within the Yale Art Gallery Extension, the concept of accessibility was not as clear as that of residential buildings, because an approach of respecting existing architecture and context was used, rather than the starting point of interior space, or differentiated circulation, which has the function of a determined position.

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