• Title/Summary/Keyword: stripping

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Stripping of Fe(III) from the Loaded Mixture of D2EHPA and TBP with Sulfuric Acid Containing Reducing Agents

  • Liu, Yang;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2109-2113
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    • 2014
  • Solvent extraction of Fe(III) from chloride solution by using a mixture of D2EHPA (Di-(2-ethylhexyl)-phosphoric acid) and TBP (Tri-butyl phosphate) and the reductive stripping of Fe(III) from the loaded organic were investigated. Quantitative extraction of Fe(III) from the solution (Fe concentration = 90 g/L) was accomplished in two cross-current extraction stages by using the mixture of D2EHPA and TBP. In order to facilitate the stripping efficiency, a reductive stripping method was employed by using $H_2SO_3$ or $Na_2SO_3$ as a reducing agent. The addition of $H_2SO_4$ into reducing agents led to improvement in the stripping efficiency while high concentration acid would suppress it. Both of the mixtures of $H_2SO_4+H_2SO_3$ and $H_2SO_4+Na_2SO_3$ showed good efficiency for the stripping of Fe(III), while the latter was recommended as the stripping solution based on the economics and experimental condition.

A study on the dither-stripping with dither motion sensor of a ring laser gyroscope (링레이저 자이로의 몸체진동 검출센서를 이용한 dither-stripping 연구)

  • Sim, Gyu Min;Im, Hu Jang
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.5
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    • pp.63-71
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    • 2003
  • In this paper we dicuss the dither-stripping methods by V-F(voltage to frequency) conversion of the output of angular velocity sensor which is for detecting the dither motion of the ring laser cavity. In this case, it is very important to evaluate the pulse-to-pulse scale factor between the ring lase output pulse and V-F output pulse, and also to compensate the zero offset of the V-F output pulse. In the case of the dither-stripping by the V-F conversion of angular velocity sensor output, there is a big angle uncertainty in the process of compensating the zero offset due to the dither noise for compensating the V-F output. By differential, the phase of the V-F output is changed. So, to compensate it, we change 90deg of the phase of angular velocity sensor output and delay half sampling time of the phase of ring laser output in advance. In this case the pulse-to-pulse scale factor can be evaluated by the standard deviation of each pulse. We can get the good result of the dither-stripping output by this angle differential method.

Composite copper powder from Kelex 100 (Kelex100로부터 구리입자 분말 합성)

  • ;P.R Taylor
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.131-137
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    • 1998
  • A composite copper coated powder was generated by pressure hydrogen stripping copper from Kelex 100 solvent extractant in the presence of silica powder. Within the limitation of solvent extraction under constant conditions, both loading level and stripping rate were reproducible. The stripping copper kinetics are reduced from a divalent state to a metallic state and then deposited on the surface of the silica powder. Copper nucleates heterogeneously on the seed particles. They are giving an agglomerated and non - uniform powder.

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A Study on the Decompressed Ammonia Stripping from Ammonia Contained Wastewater (폐수의 감압 암모니아 탈기에 관한 연구)

  • 신대윤;오유경
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.93-99
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    • 2001
  • This study aims at finding out pertinent reaction conditions for treating high concentration ammonia contained in N-chemical factory wastewater with decompressed ammonia stripping method that was designed. And it also tries to investigate adsorption capability of removed ammonia to soil. The results from experiments are as follows ; 1. The removal rate of N $H_3$-N of synthetic wastewater was under 85% at pH 10 with decompressed ammonia stripping method. The reaction time in pressure 360 mmHg at pH 11 and 12 was shorter than in 460 mmHg, and the removal rate of N $H_3$-N with decompressed ammonia stripping method at 9$0^{\circ}C$ was 11~15% higher than air stripping 2. The optimum conditions for decompressed ammonia stripping with synthetic sample were shown as pH 12, temperature 9$0^{\circ}C$, internal reaction pressure 460 mmHg and reaction time 50 minutes. These conditions were applied to treat the wastewater containing organic-N 290.5mg/$\ell$, N $H_3$-N 168.9mg/$\ell$, N $O_2$-N 23.2mg/$\ell$, N $O_3$-N 252.4mg/$\ell$, T-N 735mg/$\ell$. Organic-N turned out to be removed 60%, the removal rate of N $H_3$-N IS 94%, T-N is 50%. But N $O_2$-N and N $O_3$-N were increased with 7.8% and 14.9% respectively. 3. The CO $D_{Sr}$ removal rate in decompressed ammonia stripping reaction was 42% and S $O_4$$^{2-}$ was removed 8.2%. It was turned out caused with higher pH and thermolysis. 4. In soil adsorption of ammonia desorbed from the decompressed stripping process of wastewater, the recovery rate was 76% in wet soil.

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Removal of High Strength Nitrogen in Dyeing Wastewater by Decomposition-Air Stripping Process (분해탈기법에 의한 염색폐수 중의 고농도 질소 제거에 관한 연구)

  • Cho, Byeung-Rak
    • Journal of the Korean Society of Industry Convergence
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    • v.5 no.3
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    • pp.213-218
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    • 2002
  • Total nitrogen is a major pollutant which mostly causes eutrophication and red tide. Wastewater effluent from printing of cotton-viscose rayon containing high concentrations of total nitrogen can not be effectively treated with a typical biological treatment process. This paper provides a new treatment process and experimental results for the removal of high strength nitrogen from dyeing wastewater. The optimum conditions of air stripping for the removal of total nitrogen include around pH 12, temperature $60^{\circ}C$ with 60 minutes of stripping time. In case of a filtration-air stripping process, an initial level ($500mg/{\ell}$) of total nitrogen was significantly reduced to below $60mg/{\ell}$. Deconite was synthesised for further decomposition of organic nitrogen. Thus, a filtration-decomposition-air stripping process was possibly achieved, by which a high level ($900mg/{\ell}$) of total nitrogen was effectively removed to below $60mg/{\ell}$ P. Finally, a continuous new process for the removal of total nitrogen is proposed and confirmed, based on batch experimental results, and its process validity is further discussed throughout.

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Industrial scale extraction and stripping devices for continuous recovery of gallic acid from Chinese nutgall processing wastewater

  • Wu, Yundong;Xia, Xihe;Dong, Shuyu;Zhou, Kanggen
    • Environmental Engineering Research
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    • v.22 no.3
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    • pp.288-293
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    • 2017
  • In this study, we report the industrial application of an efficient technology for the recovery of gallic acid from Chinese nutgall processing wastewater. The recovery of gallic acid by industrial scale extraction and stripping devices was performed, with tributyl phosphate as the extractant and kerosene as the diluent. The results showed that the theoretical extraction stage was four, while the theoretical stripping stage was two. A closed-cycle system was studied for the continuous countercurrent extraction and stripping, with a five-stage extraction device and a three-stage reflux stripping device. The results showed that the multistage extraction-stripping system could steadily run for a long period, the average gallic acid level in the raffinate was $0.85g{\cdot}L^{-1}$, and the gallic acid content recovered in the strip liquor was higher than $120g{\cdot}L^{-1}$. The average extraction yield of gallic acid was 94.14%. When the strip liquor was used as raw material for production, the average production yield increased by 8.64%. In addition, after extraction, the $COD_{Cr}$ in the wastewater decreased by 38.19%, and the biodegradability of wastewater improved by 1.6 times. This study provided a new impetus for the sustainable development of the Chinese nutgall processing industry.

Detection of Trace Copper Metal at Carbon Nanotube Based Electrodes Using Squarewave Anodic Stripping Voltammetry

  • Choi, Changkun;Jeong, Youngsam;Kwon, Yongchai
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.801-809
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    • 2013
  • We investigate sensitivity and limit of detection (LOD) of trace copper (Cu) metal using pristine carbon nanotube (CNT) and acidified CNT (ACNT) electrodes. Squarewave based anodic stripping voltammetry (SWASV) is used to determine the stripped Cu concentration. Prior to performing the SWASV measurements, its optimal conditions are determined and with that, effects of potential scan rate and $Cu^{2+}$ concentration on stripping current are evaluated. The measurements indicate that (1) ACNT electrode shows better results than CNT electrode and (2) stripping is controlled by surface reaction. In the given $Cu^{2+}$ concentration range of 25-150 ppb, peak stripping current has linearity with $Cu^{2+}$ concentration. Quantitatively, sensitivity and LOD of Cu in ACNT electrode are 9.36 ${\mu}A\;{\mu}M^{-1}$ and 3 ppb, while their values are 3.99 ${\mu}A\;{\mu}M^{-1}$ and 3 ppb with CNT electrode. We evaluate the effect of three different water solutions (deionized water, tap water and river water) on stripping current and the confirm types of water don't affect the sensitivity of Cu. It turns out by optical inspection and cyclic voltammetry that superiority of ACNT electrode to CNT electrode is attributed to exfoliation of CNT bundles and improved interfacial adhesion occurring during oxidation of CNTs.

Testing for Dust Stripping of Virgo Cluster Galaxies According to HI Gas Stripping Stage

  • Lee, Hye-Ran;Zabludoff, Ann;Lee, Joon Hyeop;Park, Byeong-Gon
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.75.2-75.2
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    • 2017
  • We Investigate dust stripping of Virgo cluster galaxies that are known to suffer HI gas stripping. The gas stripping phenomena of these galaxies may result from either ram pressure induced by the hot intracluster medium or gravitational tidal interactions between galaxies. While much efforts have been made to directly detect gas removed from cluster galaxies, the spatial distributions of dust, which should also be affected, are hardly known. Several previous studies have tried to directly detect the morphology of gas or dust using radio or infrared observations, but such approaches are hard to widely apply because of the limit of observational resolution and sensitivity. In this study, we try a different approach using optical data: measuring the background galaxy reddening by the dust stripped from the Virgo cluster members. Based on optical color excess maps of the background galaxies, we compare the ambient dust distribution with the HI morphology of the Virgo galaxies. We discuss how efficiently dust stripping can be detected with this method and how the stripped dust is associated with the removed gas according to HI gas stripping stage over the sample.

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Removal of Taste and Odor by Powdered Activated Carbon Adsorption and Air Stripping (분말활성탄 흡착 및 탈기에 의한 이취미 제거)

  • Jun, Hang-Bae;Na, Kwang-Ju;Seo, Tae-Kyeong;Park, Sang-Min
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.4
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    • pp.455-460
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    • 2008
  • Powered activated carbon(PAC) has been widely applied for controling odor causing compounds(OCCs) from water treatment plants. Because of their volatility, the OCCs can also be removed from water by air stripping methods. In this study, OCCs removal was tested with PAC adsorption, air stripping, and both PAC adsorption and air stripping from the Taecheong lake water. Removal efficiency of OCCs in terms of threshold odor number(TON) were 39.6% by both PAC (15mg/L) adsorption and aeration for 30 min, 33.6% by PAC(15mg/L) adsorption alone for 30 min, and 22.9% by aeration alone for 30 min, respectively. OCCs could be removed up to 50% by aeration for 120 min without PAC adsorption. At an extended aeration with 15mg/L of PAC, OCCs removal occurred mainly by PAC adsorption within 30 min aeration while it continued by air stripping afterward. At simulated jar tests with the raw water, removal efficiencies of geosmin and MIB were 48.3, 36.1% by coagulation and sedimentation without PAC addition. With 15mg/L of PAC on the same jar tests, the removal efficiencies were 83.1, 60.1%, respectively. Without PAC, OCCs could be possibly removed by stripping during the agitation processes.

An Efficient Photoresist Stripping Process on the ITO Surface Using the Dipping Method (딥핑 방식을 이용한 ITO 표면의 효율적인 포토레지스트 박리공정)

  • Kim, Joon Hyun;Sim, Jae Myung;Joo, Gi-Tae;Kim, Young Sung;Jeong, Byung Hyun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.4
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    • pp.281-289
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    • 2016
  • Agitation is a secondary process used to increase the PR stripping force on an ITO-glass surface; it is an efficient approach to stripping during production. It activates the stripper to chemically penetrate the PR layer and assists by breaking down the physical bonding forces at the surface. In this study, different stripping tests were conducted by varying the dipping time, the composition, the strip temperature, and the stripper concentration. Optimal PR strip conditions were estimated by using comparative visual inspection of stripped sample surfaces. The stripping process was affected by changes in the moving speeds and the sample positions. It was confirmed that the stripping capability improved at a dilute stripper ratio of 20-40% and a strip temperature of $30-40^{\circ}C$ and within 60 s of strip time.