• Title/Summary/Keyword: stretch ratio

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Characterization of Stretchable Polypyrrole Films Prepared by Chemical and Electrochemical Method (화학적 및 전기화학적 방법으로 합성한 연신성 폴리피롤 필름의 특성)

  • 장관식;문봉진;오응주;홍장후
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.323-329
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    • 2003
  • Stretchable Polypyrrole films using functionalized doping agent, di(2-ethylhexyl) sulfosuccinate sodium salt (NaDEHS), were synthesized by chemical and electrochemical method. Chemically and electrochemically Prepared Polypyrrole films were stretch-oriented (L/L$\_$0/= 1.0 ∼ 2.5) by zone drawing method and the electrical conductivities were measured. As the draw ratio was increased, the electrical conductivities were increased. This result was confirmed by the increase in crystallinity through the increase in draw ratio. The temperature dependence of electrical conductivity showed that 3D-variable range hopping model (L/L$\_$0/ = 1.0∼2.0) and ID-VRH model (L/L$\_$0/ = 2.5) gave the best fit to the data for stretched Ppy-DEHS films.

An Experimental Study on the Flame Characteristics of the Air/$C_3$$H_8$ Premixed Flame Using Large Axial Mean Velocity Variation (급격한 평균유속 변동에 의한 관내 Air/$C_3$$H_8$ 예혼합 화염의 소화특성에 관한 실험적 연구)

  • Kim, Nam-Il;Lee, Eun-Do;Sin, Hyeon-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.540-545
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    • 2001
  • Many previous researches on the premixed flame in a tube have treated the unsteady flame behaviors in which the shape, position and intensity of the flame varied, but more detail and fundamental research has been necessary. The flame stabilization condition in a tube, a unique steady state, and the unsteady behaviors, using the stabilization condition as an initial condition, were carried out in recent years. In this paper, propane-air premixed flame was stabilized in a tube and the flame behavior was observed when the mean velocity variation was imposed into the opposite direction of the initial mean velocity. The velocity variation is larger than the burning velocity and longer than the reaction time scale. During the period of the velocity variation flame is not extinguished. But after the period of the mean velocity variation the flame could be re-stabilized or be extinguished depending on the experimental conditions: equivalence ratio, period of velocity variation and magnitude of velocity variation. The extinction mechanisms were classified into the two cases, one is caused by the flame stretch in the shear layer near the wall, and the other is caused by the vortices and vortexes, which are generted by the acoustic waves.

Analysis of Bale Surface Pressure According to Stretch Film Layer Changes on Round Bale Wrapping

  • Hong, Sungha;Kang, Daein;Kim, Daeyeon;Lee, Sangsik
    • Journal of Biosystems Engineering
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    • v.42 no.3
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    • pp.136-146
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    • 2017
  • Purpose: This paper presents an appropriate wrapping method by analyzing the pressure distribution applied to a bale surface, along with the change in pressure according to an increase in the number of film layers in rice straw bales, which account for 74% of the total bulky feed supply in Korea. Methods: A model with the shape of an actual bale was fabricated to analyze the distribution of surface pressure in bale wrapping, and the pressure was measured. Experiments were conducted to analyze the pressure using eight different layer numbers (2, 4, 6, 8 10, 12, 14, and 16 layers) at five wrapping speeds (27, 29, 31, 33, and 35 rpm). Results: The maximum pressure applied to a circular bale by the film occurred at the center of the end of the bale, whereas the minimum pressure occurred at the center of the bale side. An extreme value ratio between the minimum and maximum pressures was distributed as 8.5-56.6%, which was improved with an increase in rotation speed. The an uneven pressure distribution occurred because the number of film overlaps was 8.24-times greater at the center of the bale's end than at the center of the ba le side. At a level 5 rotation speed, the minimum pressure was $P_{LV5-M1}=0.0625{\sigma}^2+36.173{\sigma}-36.753$ ($R^2=0.9845$) at $M_1$, and the maximum pressure was $P_{LV5-M6}=5.5552{\sigma}^2+41.05{\sigma}-39.071$ at $M_2$, revealing a correlation of $R^2=0.9983$. Conclusions: To replace four layers with six layers, 2-4 layers were added only to the side of the bale, and the minimum pressure at $M_1$ was then improved from that at four layers to that at six layers, and the amount of film consumed for 4-6 layers was reduced by 84.6%.

The Mechanical Properties of Thin Suede Fabric with Stretch Function (신축기능성 박지 Suede 직물의 역학적 성질 변화)

  • Park, Myung Soo
    • Textile Coloration and Finishing
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    • v.24 no.4
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    • pp.288-295
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    • 2012
  • Although some degree of mechanical properties of suede fabrics mainly related to non-woven suede fabric has some researched, the thin suede fabric has rarely been researched. In this study, polyester(DTY 50/72) was used for warp, and after producing latent yarn and sea-island yarn for weft, two yarns were compounded to produce sea-island DTY yarn. By using the two produced yarns for warp and weft, we produced thin suede fabric with stretch function. For weft 2ply, weft density 85, 90, 100(picks/in) were applied to weave fabric, and for weft 1ply, weft density 125, 135, 140(picks/in) were applied to produce weft face 5-end satin weave. The mechanical properties of the produced fabric were researched. The result are as followed. The weight loss ratio of the suede fabric produced for this experiment reached 15% on the conditions of temperature $90^{\circ}C$ and 20 minutes, so that island parts were completely separated. The strength of weft 1ply applied suede fabric was about 7.5kg and that of 2ply suede fabric and about 3.5kg. But the strain of two samples ranged from about 40 to 43%. Although Hari was high when weft was denser. The values of Koshi and Kisimi were low. And shear stiffness was high when sea-island DTY yarn was used. The WC value was higher in the case of 2ply than in that of 1ply sea-island DTY yarn for weft, so that we may conclude that Fukurami was more affected in the 2ply case.

Reflectance of Geological Media by Using a Field spectrometer in the Ungsang Area, Kyungsang Basin

  • Kang, Kyung-Kuk;Song, Kyo-Young;Ahn, Chung-Hyun;Won, Joong-Sun
    • Korean Journal of Remote Sensing
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    • v.17 no.2
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    • pp.165-181
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    • 2001
  • Using a field spectrometer having a spectral range of 0.4$\mu\textrm{m}$~2.5$\mu\textrm{m}$ with a spectral resolution of 1nm, the researchers measured the reflectance of granite, andesitic rocks, sedimentary rocks, and pyrophyllite ore in the Ungsang area, Kyungsang Basin, South Korea. Spectral characteristics of the geological media were investigated from the analysis. The in-situ measured sites were selected in well exposed rock outcrops. In case of unfavorable weather conditions, rocks were sampled and remeasured under natural solar condition. The reflectance of field data was measurd at three sistes for granite, six sites for andesitic rock three sites for sedimentary rocks, and two sites for pyrophyllite ore. The vibrational absorption bands for pyrophyllite are detected in the spectral range of 2.0$\mu\textrm{m}$~2.5$\mu\textrm{m}$. The absorption band for granites in study area is not distinctive. The reflectance measured under normal field conditions showed strong absorption at wavelengths of 1.4$\mu\textrm{m}$ and 1.9$\mu\textrm{m}$ due to the effect of moisture in the atmosphere. After the bands of 1.4$\mu\textrm{m}$ and 1.9$\mu\textrm{m}$ were removed, Hull Quotient method was applied to characterize absorption bands. The reflectances of field data were calculated to estimate the band ratio corresponding to the Landsat TM and EOS Terra ASTER. The researchers suggest here that the TM band2, band3, band4, and band7 or ASTER band2, band3, band4, and band9 are the best combination for discriminating outcrops. The researchers tested and demonstrated using a Landsat TM image in the study area. For geologic applications, decorrelation stretch is also an effective tool to enhance the exposed rock mass in images.

Measurement of Mechanical Material Properties of Rubber Compounds Sampled from a Pneumatic Tire (타이어에서 채취한 고무배합물의 기계적 물성 측정)

  • 김용우;김종국
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.04a
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    • pp.404-409
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    • 2002
  • Pneumatic tires usually contain a variety of rubber compositions, each designed to contribute some particular factor to overall performance. Rubber compounds designed for a specific function will usually be similar but not identical In composition and properties. Since 1970`s finite element analysis of tire has been performed extensively, which requires some energy density functions of rubber components of a tire. The conventional Mooney-Rivlin material model is one of the description that is commonly used in the analysis of tire. In this paper, we report the two material constants of gooney-Rivlin material model for some rubber compounds of a real pneumatic tire, which are obtained through uniaxial tension test.

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Combustion in Methane-Air Pre-Mixture with Water Vapor(1) - Progress of Flame Propagation (물 혼합에 의한 메탄-공기 예혼합기의 연소(1) - 화염전파과정)

  • Kwon, Soon-Ik
    • Journal of the Korean Society of Industry Convergence
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    • v.11 no.1
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    • pp.5-10
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    • 2008
  • A flame speed of methane mixture of water vapor and air have been measured to study the process of flame propagation using schlieren photographs. The quantity of water vapor contained were changed 5% and 10% of total mixture, and equivalence ratio of mixture between 0.8 and 1.2 were tested under the ambient temperature 323K and 373K. The results showed that the burning velocity was decreased by increasing the water vapor contents due to the interruption of flame development. And, the reduction rate of burning velocity was smaller by increasing the water contents under the same ambient temperature. The effects of ambient temperature on burning velocity was decreased by increasing the water vapor contents.

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Effect of Structural and Morphological Changes on the Conductivity of Stretched PANI-DBSA/HIPS Film

  • Lee, Jong-Hyeok;Kim, Eun-Ok
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2661-2665
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    • 2011
  • We studied the effect of structural and morphological changes on the conductivity of a stretched conducting polymer film. To improve the poor processability of polyaniline, we used dodecylbenzenesulfonic acid as both a surfactant and a dopant during emulsion polymerization, followed by blending with high-impact polystyrene. UV-Vis/NIR spectra were obtained to observe conformational changes, and SEM and AFM were used to investigate morphological changes. FT-IR dichroism was applied to determine the microscopic orientation, and XRD patterns were obtained for quantitative crystallinity analysis. The electrical conductivity (${\sigma}_{\parallel}/{\sigma}_{\perp}$) was measured as a function of draw ratio. We found a clear correlation between morphological changes and (${\sigma}_{\parallel}/{\sigma}_{\perp}$), especially at the stretching limit. The conductivity of the films can be modified according to the desired application by controlling their structure and morphology.

Polymer Light-Emitting Diodes Based on Poly(3-hexyl thiophene)

  • Chang, Seoul;Kim, Nam-Hee
    • Fibers and Polymers
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    • v.1 no.1
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    • pp.25-31
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    • 2000
  • Poly(3-hexyl thiophene)(P3HT) and poly(3-dodecyl thiophene)(P3DT) were polymerized by oxidative coupling with ferric chloride. The P3HT light-emitting device emitted red light and it could be observable in the ordinary indoor light. The device had the turn-on electric field of about 3$\times$$10^7$ V/m. The maximum electroluminescene (EL) intensity was obtained when the thickness of polymer layer was about 130 nm in IT0/P3HT/Al device. The maximum external quantum yield was 0.002%. The maximum luminance was 21 cd/$m^2$. The EL intensity decreases with increasing the crystallinity of the polymer layer. By using the oriented poly(3-alkyl thiophene)(PAT) layer as an electroluminescent layer in the ITO/polymer/Al light-emitting devices, the polarized EL light emission was observed. The EL intensity ratio of parallel to perpendicular direction to the stretch direction for P3HT was about 1.40.

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A Study on Fiber Formation and Physical Properties of Polyacrylonitrile Copolymer with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴 공중합체의 섬유제조 및 그 물성에 관한 연구)

  • Sin, Ik Gi;Lee, Sin Hui;Park, Su Min
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.109-109
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    • 2002
  • A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.