• Title/Summary/Keyword: strength increment

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Biocompatibility of oxidized alginate/gelatin/BCP -based hydrogel composites

  • Phuong, Nguyen Thi;Min, Young-Ki;Yang, Hun-Mo;Song, Ho-Yeon;Lee, Byong-Teak
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.40.2-40.2
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    • 2010
  • In this study, oxidized alginate/gelatin/biphase calcium phosphate (BCP)- based hydrogel composites were fabricated. Alginate sodium was oxidized by periodate. The oxidized product was confirmed by using $^1H$ and $^{13}C$ NMR spectra. The number average molecular weight ($M_n$), the average molecular weight ($M_w$) of the oxidized alginate were determined by Gel Permeation Chromatography (GPC). The hydrogel was formed from the oxidized alginate and gelatin solution via Schift-base reaction. The hydrogel showed a highly porosity by a Scanning Electron Microscope (SEM) and Mercury Intrusion Porosimetry (MIP). Crosslinked density of the gel matrix were assessd by trinitrobenzene sulfonic acid (TNBS) assay that shows a high effect on swelling ratio. Increment of the crosslinked desity resulted in enhancing compressive strength of the hydrogel composite. The cytotoxity of hydrogel was assessed with osteoblast MG-63. The hydrogel composites show a high compatibility. The obtained results showed a potential application for bone regeneration in future.

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Biological Treatment of OCC Flake in Fine Screen Rejects for Recovery of Fibrous Materials (생물학적 처리에 의한 OCC 스크린 리젝트 내 미해리분의 재활용)

  • Sung Yong Joo;Ryu Jeong-Yong;Song Bong Keun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.1 s.109
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    • pp.17-24
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    • 2005
  • The increase of using low grade ace, the unsorted mixed grade, as fibrous raw materials for the packaging paper results in the increment of fine screen reject owing to the strong tendency to reduce the slot width. Since the most of screen reject consists of undispersed fiber flake, the suitable treatment of the flake could increase the yield of ace recycling and decrease the amount of solid waste. In this work, the novel method combined the mild mechanical treatment by using Tumbling pulper with the biological treatment was developed and applied to the wet strength flake and the fine screen tail line reject originated from a packaging paper mill. The results showed the new method could provide much better efficiency for the disintegration of undispersed flake and for the recovery of fiber from the rejects. The application of the laboratory scaled-Pack pulper showed the possible separation technique for mill application by fractioning effectively the fiber from the treated solid waste.

Ultimate Analysis of Reinforced Concrete Shear Walls with Opening (개구부가 있는 철근콘크리트 전단벽의 극한해석)

  • Hu, Nam-Ryun;You, Young-Hwa;Kim, Woon-Hak
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.5 no.1
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    • pp.195-205
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    • 2001
  • An analytical finite element approach to nonlinear behavior of reinforced concrete shear walls with opening under monotonic loading was presented in this paper. In order to achieve the objectives of present paper, the orthogonal anisotropic models for cracked reinforced concrete element based on smeared crack concept were used as the nonlinear material models of biaxial state of stress. The stiffness of cracked concrete was evaluated through the combined use of tension and compression stiffness models in and parallel directions of crack, respectively and shear transfer effect due to the aggregate interlocking at crack surface. The stress and strain of reinforcement in concrete was evaluated using the average stress and average strain relation with bond effect. based on smeared crack concept. The diagonal reinforcing bar was modeled using truss element with bond effect. A special significance of diagonal reinforcement near opening was given to the shear wall with opening and an effective distribution of diagonal reinforcement was presented in order to give an ultimate strength increment as well as a crack control.

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Effect of Austempering Factors and Mn Addition on Mechanical Properties of ADI (오스템퍼링 조건과 Mn의 양이 ADI의 기계적 성질에 미치는 영향)

  • Suh, Kwan-Soo;Ye, Byung-Joon
    • Journal of Korea Foundry Society
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    • v.12 no.5
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    • pp.390-396
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    • 1992
  • In this study, we investigated effect of austempering factors and Mn addition on mechanical properties of ADI with ferrite-bainite matrix by pearlite-bainite transformation treatment. Ductile cast iron specimens containing various of Mn were austenitized at 875$^{\circ}C$ for 350 sec or 925$^{\circ}C$ for 160 sec and then austempered at 300$^{\circ}C$ or 400$^{\circ}C$ for the various periods(5 to 30 min). Manganese increased pearlite volume fraction in as cast ductile cast iron. The obtained results are as follows ; 1) In austenitizing, hardness of sepecimens austenitized at 875$^{\circ}C$ for 350 sec was higher than that of 925$^{\circ}C$ for 160 sec. 2) In effect of austempering temperature, tensile strength and handness of specimens austempered at 300$^{\circ}C$ was higher than that of 400$^{\circ}C$. However, elongation had reverse tendency. 3) Increasing austempering time decreased hardness due to the increment of bainite and retained austenite fractions. However, toughness are increased.

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An Analysis on the Protection Mechanism of Some Inert Reactive Cassettes (비활성 요소의 방호 메커니즘 분석)

  • Joo, Jae-Hyun;Choi, Joon-Hong;Lee, Heon-Joo;Lee, Chang-Hyun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.5
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    • pp.550-556
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    • 2012
  • In this study, a series of ballistic experiments have been performed to investigate the protection mechanism of some inert reactive cassettes against shaped charge jet. Three kinds of material were tested as a core material of the inert cassettes, i.e. one of rubber materials, a high modulus and high strength composite material used for ballistic protection and a mixture of energetic materials. Parameters such as deformation of the cassettes, occurrence time of jet distortion, leading jet length and residual penetration depth were investigated from the experiments and they were compared to each other quantitatively according to the jet incidence angles. The results show that the increment of cassette deformation caused jet distortion to occur early and jet distortion brought decrease of the length of leading jet. Then the decrease of the length of leading jet accompanied the decrease of residual penetration depth.

Linear Low Density Polyethylene (LLDPE)/Zeolite Microporous Composite Film

  • Jagannath Biswas;Kim, Hyun;Soonja Choe;Patit P. Kundu;Park, Young-Hoon;Lee, Dai-Soo
    • Macromolecular Research
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    • v.11 no.5
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    • pp.357-367
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    • 2003
  • The linear low density polyethylene (LLDPE)/zeolite composite using novel inorganic filler, zeolite, is prepared by a conventional compounding procedure using a twin-screw extruder. The observed scanning electron microscopic (SEM) morphology shows a good dispersion and adhesion of zeolite in the LLDPE matrix. The mechanical properties in terms of the Young's modulus, the yield stress, the impact strength, and the elongation at break were enhanced with a successive increment of zeolite content up to 40 wt%. The X-ray diffraction measurement is of supportive for the improved mechanical properties and the complex melt viscosity is as well. Upon applying a certain level of strain on the composites, the dewetting, the air hole formation and its growth are characterized. The dewetting originates around the filler particles at low strain and induces elliptical micropores upon further stretching. The microporosity such as the aspect ratio, the number and the total area of the air holes is also characterized. Thus, the composites loaded 40 % zeolite and 300 % elongation may be applicable for breathable microporous films with improved modulus, impact and yield stress, elongation at break, microporosity and air hole properties.

Study on the Electron Injection of Newly Synthesized Organic Sensitizer in Dye-Sensitized Solar Cell

  • Gang, Tae-Yeon;Lee, Do-Gwon;Go, Min-Jae;Kim, Gyeong-Gon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.310-310
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    • 2010
  • Electronic and photovoltaic characteristics of two sensitizers (TA-BTD-CA and TA-BTD-St-CA), composed of a different $\pi$-conjugation in the linker group, have been investigated by theoretical and experimental methods. The electronic structure, transition dipole moment and oscillator strengths of two sensitizers have been scrutinized by using density functional theory (DFT) and time-dependent DFT (TD-DFT) method. The LUMO level and the oscillator strength of TA-BTD-St-CA was higher than that of TA-BTD-CA, which may facilitate the electron injection process as well as increase the absorption coefficient. The relative efficiencies of the electron injection from the excited sensitizer to nanocrystalline TiO2 and SnO2 films have also been investigated by nanosecond transient absorption spectroscopy. The relative electron injection efficiency of TA-BTD-St-CA exhibited similar injection efficiency for two different semiconductors. However, in the case of TA-BTD-CA sensitizer, electron injection into SnO2 was approximately three times larger than that into TiO2. This enhancement of electron injection of TA-BTD-CA for the SnO2 is due to the increment of the driving force caused by positive shift of conduction band of semiconductor, which was also confirmed from the investigation for the photovoltaic characteristics according to the electrolyte additive, such as LiI additive.

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Effect of Subsequent Annealing Temperature on Dynamic Deformation and Fracture Behavior of Submicrocrystalline Al-4.4%Mg Alloy via Equal-Channel Angular Pressing (ECAP 가공된 초미세 결정립 Al-4.4%Mg 합금의 동적 변형 및 파괴거동에 미치는 후-열처리 온도의 영향)

  • Kim, Y.G.;Ko, Y.G.;Shin, D.H.;Lee, C.S.;Lee, S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.427-430
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    • 2008
  • The influence of subsequent annealing treatment on the dynamic deformation and the fracture behavior of submicrocrystalline Al-4.4%Mg alloy is investigated in this study. After inducing an effective strain of 8 via equal-channel angular pressing at $200^{\circ}C$, most of the grains are considerably reduced to nearly equiaxed grains of $0.3{\mu}m$ in size. With an increment of various subsequent heat treatments for 1 hour, resultant microstructures are found to be fairly stable at temperatures up to $200^{\circ}C$, suggesting that static recovery will be dominantly operative, whereas grain growth is pronounced above $250^{\circ}C$. The results of tensile tests show that yield and ultimate tensile strength decrease, but elongation-to-failure and strain hardening rate increase with an increase in annealing temperatures. The dynamic deformation and the fracture behavior retrieved with a series of torsional tests are explored with respect to annealed microstructures. Such mechanical response is analyzed in relation to resultant microstructure and fracture mode.

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Determination of crack spacing and crack width in reinforced concrete beams

  • Piyasena, R.;Loo, Yew-Chaye;Fragomeni, Sam
    • Structural Engineering and Mechanics
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    • v.15 no.2
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    • pp.159-180
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    • 2003
  • In this paper spacing and width of flexural cracks in reinforced concrete beams are determined using two-dimensional finite element analysis. At early loading stages on the beam the primary crack spacing is based on the slip length, which is the development length required to resist the steel stress increment that occurs at a cracked section on the formation of the first flexural crack. A semi-empirical formula is presented in this paper for the determination of the slip length for a given beam. At higher load levels, the crack spacing is based on critical crack spacing, which is defined as the particular crack spacing that would produce a concrete tensile stress equal to the flexural strength of concrete. The resulting crack width is calculated as the relative difference in extensions of steel reinforcement and adjacent concrete evaluated at the cracked section. Finally a comparative study is undertaken, which indicates that the spacing and width of cracks calculated by this method agree well with values measured by other investigators.

Influence of ground motion selection methods on seismic directionality effects

  • Cantagallo, Cristina;Camata, Guido;Spacone, Enrico
    • Earthquakes and Structures
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    • v.8 no.1
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    • pp.185-204
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    • 2015
  • This study investigates the impact of the earthquake incident angle on the structural demand and the influence of ground motion selection and scaling methods on seismic directionality effects. The structural demand produced by Non-Linear Time-History Analyses (NLTHA) varies with the seismic input incidence angle. The seismic directionality effects are evaluated by subjecting four three-dimensional reinforced concrete structures to different scaled and un-scaled records oriented along nine incidence angles, whose values range between 0 and 180 degrees, with an increment of 22.5 degrees. The results show that NLTHAs performed applying the ground motion records along the principal axes underestimate the structural demand prediction, especially when plan-irregular structures are analyzed. The ground motion records generate the highest demand when applied along the lowest strength structural direction and a high energy content of the records increases the structural demand corresponding to this direction. The seismic directionality impact on structural demand is particularly important for irregular buildings subjected to un-scaled accelerograms. However, the orientation effects are much lower if spectrum-compatible combinations of scaled records are used. In both cases, irregular structures should be analyzed first with pushover analyses in order to identify the weaker structural directions and then with NLTHAs for different incidence angles.