• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.137.2-137.2
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• 2010

본 연구는 스테인리스 스틸(STS)을 직접메탄올 연료전지(DMFC)용 바이폴라 플레이트에 적용하기 위한 것이다. 약산성의 연료전지 환경에서 부식저항성을 향상시키고자 오스테나이트계 STS 316L과 페라이트계 STS 430에 UBM(unbalanced magnetron) DC sputter로 CrN 코팅막을 제작하였다. CrN이 코팅된 스테인리스 스틸은 부식특성, 접촉 저항 및 접촉각 등을 측정하여 무 코팅의 스테인리스 스틸과 특성을 비교하였다. 그리고 이들 재료의 연료전지(DMFC) 적용 가능성을 알아보기 위하여 단위전지로 제작하여 연료전지 성능 등을 측정하고 평가하였다. 무 코팅 스테인리스 스틸(STS 316L, STS 430)과 CrN 코팅 스테인리스 스틸의 부식저항 특성은 동전위와 정전위 실험으로 조사하였다. 동전위 부식 실험은 -0.4~1.0 V로 0.001 M의 황산용액 또는 메탄올을 첨가하여 질소 또는 공기의 환경에서 실험을 실시하였으며, 정전위 부식 실험은 0.4 V 또는 0.6 V에서 진행하였다. 연료전지의 단전지 측정은 실제 DMFC의 운전조건에서 실시하였다. 부식실험과 단전지 실험 전/후 메탈 바이폴라 플레이트의 조직 변화는 SEM을 통해 관찰하였고, 부식산화물의 화학적 조성과 메탈 바이폴라의 표면은 EDS를 이용하여 측정하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.90.2-90.2
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• 2010

The coated metallic bipolar plates are getting attractive due to their good feasibility of mass production, low contact resistance, high electrical/thermal conductivity, low gas permeability and good mechanical strength comparing with graphite materials. Yet, metallic bipolar plates for polymer electrolyte membrane(PEM) fuel cells typically require coatings for corrosion protection. Other requirements for the corrosion protective coatings include low electrical contact resistance between metallic bipolar plate and gas diffusion layer, good mechanical robustness, low mechanical and fabrication cost. The authors have evaluated a number of protective coatings deposited on stainless steel substrate by electroplating. The coated metallic bipolar plates are investigated with an electrochemical polarization tests, salt dipping tests, adhesion tests for corrosion resistance and then the contact resistance was measured. The results showed that the selective samples electroplated with optimized method, satisfied the DOE target for corrosion resistance and contact resistance, and also were very stabilized in the typical fuel cell environments in the long-term.

• Journal of Environmental Health Sciences
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• v.23 no.3
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• pp.1-6
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• 1997

This research was conducted in the laboratory to investigate an alternative of Copper(Cu) removal from an heavymetal wastewater using the electrochemical precipitation(ECP) process. The ECP unit consisted of an electrolytic cell made of Titanium plate and Steel plate representing anode and cathode. The DC power source applied to the ECP unit had electrical potential(E) of 50$\pm$ 1V, respectively. The synthetic wastewater used in the experiments contained Cu in the 10 mg/l concentration and the electrode separation were 2, 3, 4 cm and the initial pH were 3, 6, 9, 12, and electrolytic concentration were 0.005, 0.0125, 0.025, 0.0375 mole, and the real heavymetal wastewater used in the experiments. From the experiment for removal efficiency according to pH variation, the low pH area doesn't give the coagulation effect by Ti(OH)$_4$ because process interfere with the coagulation and oxidation reaction, therefore the optimum pH was 4-7. The removal rate was 97.75% after the lapse of 30 minutes when copper concentration and electrolytic concentration were respectively 10 mg/l and 0.025 mole. The removal rate was 96.41% after the lapse of 30minutes when the real heavymetal wastewater used. The optimum consumption of power showed 27KWh/m$^3$ when copper concentration, electrolyte concentration and cell potential were respectively 10 mg/l, 0.025 mole and 50$\pm$ 1 Volt.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2003.10a
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• pp.133-144
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• 2003

Generally, diaphragms are installed in the box girder to prevent or decrease the distortion of tile cross section. In engineering practice, diaphragms are spaced in 5m intervals without reasonable basis. ANd the usual diaphragm type is solid-plate type. It is considered to be noneconomical design to the almost design engineers. In this paper, the parametric study was performed to present the design proposal about the diaphragm stiffness and spacing only in tire single cell box girder. For that, the distortional warping normal stress, bending normal stress and transverse bending normal stress were analyzed using finite element program 'SMB' for the accurate structural analysis.

• Steel and Composite Structures
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• v.43 no.5
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• pp.581-601
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• 2022

The main objective of this research work is to investigate the free vibration behavior of annular sandwich plates resting on the Kerr foundation at thermal conditions. This sandwich configuration is composed of two FGM face sheets as coating layer and a porous GPLRC (GPL reinforced composite) core. It is supposed that the GPL nanofillers and the porosity coefficient vary continuously along the core thickness direction. To model closed-cell FG porous material reinforced with GPLs, Halpin-Tsai micromechanical modeling in conjunction with Gaussian-Random field scheme is used, while the Poisson's ratio and density are computed by the rule of mixtures. Besides, the material properties of two FGM face sheets change continuously through the thickness according to the power-law distribution. To capture fundamental frequencies of the annular sandwich plate resting on the Kerr foundation in a thermal environment, the analysis procedure is with the aid of Reddy's shear-deformation plate theory based high-order shear deformation plate theory (HSDT) to derive and solve the equations of motion and boundary conditions. The governing equations together with related boundary conditions are discretized using the generalized differential quadrature (GDQ) method in the spatial domain. Numerical results are compared with those published in the literature to examine the accuracy and validity of the present approach. A parametric solution for temperature variation across the thickness of the sandwich plate is employed taking into account the thermal conductivity, the inhomogeneity parameter, and the sandwich schemes. The numerical results indicate the influence of volume fraction index, GPLs volume fraction, porosity coefficient, three independent coefficients of Kerr elastic foundation, and temperature difference on the free vibration behavior of annular sandwich plate. This study provides essential information to engineers seeking innovative ways to promote composite structures in a practical way.

• Steel and Composite Structures
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• v.51 no.1
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• pp.53-61
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• 2024

Aluminum foams sandwich panel (AFSP) has been used in engineering field, where cyclic loading is used in most of the applications. In this paper, the fatigue life of AFSP prepared by the bonding method was investigated through a three-point bending test. The mathematical statistics method was used to analyze the influence of different plate thicknesses and core densities on the bending fatigue life. The macroscopic fatigue failure modes and damage mechanisms were observed by scanning electron microscopy (SEM). The results indicate that panel thickness and core layer density have a significant influence on the bending fatigue life of AFSP and their dispersion. The damage mechanism of fatigue failure to cells in aluminum foam is that the initial fatigue crack begins the cell wall, the thinnest position of the cell wall or the intersection of the cell wall and the cell ridge, where stress concentrations are more likely to occur. The fatigue failure of aluminum foam core usually starts from the semi-closed unit of the lower layer, and the fatigue crack propagates layer by layer along the direction of the maximum shear stress. The results can provide a reference for the practical engineering design and application of AFSP.

• Corrosion Science and Technology
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• v.5 no.4
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• pp.129-136
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• 2006

High temperature corrosion behavior of AISI-type 316L stainless steel for the MCFC(molten carbonate fuel cell) bipolar application was studied by immersion test and penetration attack method in anode environment ($650^{\circ}C$, $Li_2CO_3/K_2CO_3=62/38$ mol%, $H_2/CO_2=80/20$ vol%) without or with different $CaCO_3$ content. Not only immersion test method but also morphological observation of samples in the carbonate melts are adopted as experimental methods. With aid of the morphological observation of cross section of samples immersed in a carbonate melt was possible to obtain penetration attack. The concentration effect of $CaCO_3$ inhibitor was investigated in order to verify the optimum concentration for practical application in MCFC stack operation. The corrosion rate in the presence of $CaCO_3$ was proven to be decreased as a function of $CaCO_3$ concentration. The corrosion rate in the presence of $CaCO_3$ was measured with a value of 6.9 mpy which is 2.4 times lower than that of inhibitor-free electrolyte. The cross section microscopy revealed that the internal penetration by oxidation in molten carbonate is very severe. In this case, the attack was occurred not only dissolution loss in the electrolyte by corrosion reaction but also weight gain through oxide layer by internal penetration.

• Steel and Composite Structures
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• v.46 no.1
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• pp.15-31
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• 2023

Organic solar cells utilized natural polymers to convert solar energy to electricity. The demands for green energy production and less disposal of toxic materials make them one of the interesting candidates for replacing conventional solar cells. However, the different aspects of their properties including mechanical strength and stability are not well recognized. Therefore, in the present study, we aim to explore the chaotic responses of these organic solar cells. In doing so, a specific type of organic solar cell constructed from layers of material with different thicknesses is considered to obtain vibrational and chaotic responses under different boundaries and initial conditions. A square plate structure is examined with first-order shear deformation theory to acquire the displacement field in the laminated structure. The bounding between different layers is considered to be perfect with no sliding and separation. On the other hand, nonlocal elasticity theory is engaged in incorporating the structural effects of the organic material into calculations. Hamilton's principle is adopted to obtain governing equations with regard to boundary conditions and mechanical loadings. The extracted equations of motion were solved using the perturbation method and differential quadrature approach. The results demonstrated the significant effect of relative glass layer thickness on the chaotic behavior of the structure with higher relative thickness leading to less chaotic responses. Moreover, a comprehensive parameter study is presented to examine the effects of nonlocality and relative thicknesses on the natural frequency of square organic solar cell structure.

• Journal of Powder Materials
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• v.18 no.5
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• pp.430-436
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• 2011

Joining of NiO-YSZ to 316 stainless steel was carried out with B-Ni2 brazing alloy (3 wt% Fe, 4.5 wt% Si, 3.2 wt% B, 7 wt% Cr, Ni-balance, m.p. 971-$999^{\circ}C$) to seal the NiO-YSZ anode/316 stainless steel interconnect structure in a SOFC. In the present research, interfacial (chemical) reactions during brazing at the NiO-YSZ/316 stainless steel interconnect were enhanced by the two processing methods, a) addition of an electroless nickel plate to NiO-YSZ as a coating or b) deposition of titanium layer onto NiO-YSZ by magnetron plasma sputtering method, with process variables and procedures optimized during the pre-processing. Brazing was performed in a cold-wall vacuum furnace at $1080^{\circ}C$. Post-brazing interfacial morphologies between NiO-YSZ and 316 stainless steel were examined by SEM and EDS methods. The results indicate that B-Ni2 brazing filler alloy was fused fully during brazing and continuous interfacial layer formation depended on the method of pre-coating NiO-YSZ. The inter-diffusion of elements was promoted by titanium-deposition: the diffusion reaction thickness of the interfacial area was reduced to less than 5 ${\mu}m$ compared to 100 ${\mu}m$ for electroless nickel-deposited NiO-YSZ cermet.

• Steel and Composite Structures
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• v.39 no.3
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• pp.275-290
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• 2021

The main purpose of this research work is to investigate the critical buckling load of functionally graded (FG) porous plates with graphene platelets (GPLs) reinforcement using generalized differential quadrature (GDQ) method at thermal condition. It is supposed that the GPL nanofillers and the porosity coefficient vary continuously along the plate thickness direction. Generally, the thermal distribution is considered to be nonlinear and the temperature changing continuously through the thickness of the nanocomposite plates according to the power-law distribution. To model closed cell FG porous material reinforced with GPLs, Halpin-Tsai micromechanical modeling in conjunction with Gaussian-Random field scheme are used, through which mechanical properties of the structures can be extracted. Based on the third order shear deformation theory (TSDT) and the Hamilton's principle, the equations of motion are established and solved for various boundary conditions (B.Cs). The fast rate of convergence and accuracy of the method are investigated through the different solved examples and validity of the present study is evaluated by comparing its numerical results with those available in the literature. A special attention is drawn to the role of GPLs weight fraction, GPLs patterns through the thickness, porosity coefficient and distribution of porosity on critical buckling load. Results reveal that the importance of thermal condition on of the critical load of FGP-GPL reinforced nanocomposite plates.