• 대한기계학회논문집B
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• 제30권9호
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• pp.882-890
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• 2006

The present study investigates the pressure drop characteristics in rotating two-pass ducts. The duct has an aspect ratio (W/H) of 0.5 and a hydraulic diameter $(D_h)$ of 26.67mm. Rib turbulators are attached parallel in the four different arrangements on the leading and trailing surfaces of the test ducts. The ribs have a rectangular cross section of $2m(e){\times}3mm(w)$ and an attack angle of $70^{\circ}C$. The pitch-to-rib height ratio (p/e) is 7.5, and the rib height-to-hydraulic diameter ratio $(e/D_h)$ is 0.075. The results show that the highest pressure drop among each region appears in the turning region for the stationary case, but appears in the upstream region of the second pass for the rotating case. Effects of parallel rib arrangements are almost the same in the first pass for the stationary and rotating cases. In the second pass, however, heat transfer and pressure drop are high for the cases with parallel NN or PP type ribs in the stationary ducts. In the rotating ducts, they are high for the cases with parallel NN or PN type ribs.

• 응용통계연구
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• 제31권6호
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• pp.751-759
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• 2018

Cho 등 (Communications for Statistical Applications and Methods, 23, 423-432, 2016)은 잉여금이 적정수준에 이르면 연속적으로 투자가 이루어지는 보험상품 리스크 모형을 소개하고, 잉여금 과정의 정상분포함수를 연구하였다. 본 논문에서는 잉여금이 적정수준을 넘어 또 다른 충분한 수준에 이르게 되면 추가로 즉시 투자가 이루어진다고 가정하고 기존의 연구를 확장한다. 잉여금 과정의 정상분포함수를 명확히 구하고, 보험청구액의 분포가 지수분포인 경우를 예제로 다룬다.

• 분석과학
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• 제36권4호
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• pp.143-151
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• 2023

Considering the greater role of α-amino acids in our daily lives, the enantiomer resolution of seven α-amino acids derivatized with fluorogenic reagent (4-fluoro-7-nitro-2,1,3-benzoxadiazole, NBD-F) by chiral HPLC on amylose or cellulose trisphenylcarbamate derived chiral stationary phases (CSPs) under simultaneous ultraviolet (UV) and fluorescence (FL) detection was performed. The degree of enantioseparation and resolution was affected by nature and selector backbones of the CSPs as well as the kind of amino acids. Baseline enantiomer separation and resolutions were observed for the enantiomers of all analytes as NBD derivatives especially on coated type amylose tris(3,5-dimethylphenylcarbamate) derived CSPs (Chiralpak AD-H and Lux Amylose-1). The other CSPs also showed good enantioselectivity except for the CSPs (Chiralpak IB, Chiralcel OD-H and Lux Cellulose-1) having cellulose tris(3,5-dimethylphenylcarbamate) as chiral selectors. The developed analytical chiral method was applied to determine the enantiomeric purity of seven commercially available L-α-amino acids and the impurities as D-forms were found to be in the range 0.08-0.87 %, respectively. The intra- and interday accuracy and precision assays showed high accuracy and precision of the developed analytical method. This chiral HPLC method for the enantiomer resolution of amino acids using fluorescent derivatization could be useful for the determination of enantiomeric purity of pharmaceuticals and biological study for amino acid type compounds among chiral drugs.

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.823-825
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• 2005

• Bulletin of the Korean Chemical Society
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• 제25권12호
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• pp.1977-1979
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• 2004

• Bulletin of the Korean Chemical Society
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• 제10권6호
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• pp.578-581
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• 1989

Two enantiomers of various 2-hydroxy acid esters have been resolved as the 3,5-dinitrophenyl carbamates on chiral stationary phases (CSPs) derived from ${\alpha}-arylalkylamines.$ Two CSPs, each of which contains the same type of chiral moiety, but shows different mode of connection to a silica support, have been found to show the contrasting resolution behaviors. From the contrasting resolution behaviours of two CSPs used in this study, two competing chiral recognition mechanisms are proposed.

• 대한약학회:학술대회논문집
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• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.1
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• pp.285.1-285.1
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• 2003

ChiroSil RCA(+) and SCA(-) HPLC chiral stationary phases (CSPs) developed by covalently bonding (+)- and (-)-(18-crown-6)-2,3,11,12-tetracarboxylic acid (18-C-6-T A) to silica gel were employed for enantioresolution of racemic amino compounds, respectively. Also, these 18-C-6-TA covalently bonded CSPs were compared to a commercially available Crownpak CR CSP prepared by coating chiral crown ether as a chiral selector on ODS column. (omitted)

• 대한약학회:학술대회논문집
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• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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• pp.224.2-224.2
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• 2003

Pyrethroic acids are essential chiral intermediates of the pyrethroids, which account for about 25% of the world insecticide market and are found to be some of the most effective commercially available pesticides. It was demonstrated that polysaccharide-derived chiral stationary phases (CSPs) are very efficient for the separation of the enantiomers of pyrethroid acids. It was observed that the enantioseparation of pyrethroic methyl ester and ethyl derivatives was well accomplished on brush-type WhelkO-1. (omitted)

• Bulletin of the Korean Chemical Society
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• 제34권9호
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• pp.2623-2628
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• 2013

Three di-acyl chlolide reagents, adipoyl chloride, terephthaloyl chloride and isophthaloyl chloride, were used as spacer reagents to prepare bonded type of three cellulose (3,5-dimethylphenyl)carbamate (CDMPC) chiral stationary phases (CSPs). The CDMPC CSPs were prepared using these three acid chlorides as spacer agents at the 6-position of the primary hydroxyl group on the glucose unit of cellulose regioselectively. The chiral recognition ability of the prepared CSPs for five racemates was evaluated by normal-phase high-performance liquid chromatography (HPLC) with the following mobile phases: hexane/isopropanol (IPA), hexane/IPA/tetrahydrofuran (THF) and hexane/IPA/chloroform. The result showed that these prepared CSPs can be used in THF and chloroform solutions and the chiral recognition abilities of the CSPs were improved depending on the eluents and chiral samples.

• 대한수학회지
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• 제38권4호
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• pp.807-842
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• 2001

This paper summarizes recent development of analytical and algorithmical results for stationary FIFO queues with multiple Markovian arrival streams, where service time distributions are general and they may differ for different arrival streams. While this kind of queues naturally arises in considering queues with a superposition of independent phase-type arrivals, the conventional approach based on the queue length dynamics (i.e., M/G/1 pradigm) is not applicable to this kind of queues. On the contrary, the workload process has a Markovian property, so that it is analytically tractable. This paper first reviews the results for the stationary distributions of the amount of work-in-system, actual waiting time and sojourn time, all of which were obtained in the last six years by the author. Further this paper shows an alternative approach, recently developed by the author, to analyze the joint queue length distribution based on the waiting time distribution. An emphasis is placed on how to construct a numerically feasible recursion to compute the stationary queue length mass function.