• Bulletin of the Korean Chemical Society
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• v.19 no.9
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• pp.934-942
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• 1998

$^13CO$ chemisorbed on platinum particles in L-zeolite has been investigated by static and magic angle spinning NMR spectroscopy. The representative spectra are composed of a broad asymmetric peak with a center of gravity at 230±30 ppm and a sharp symmetric peak at 124±2 ppm which is tentatively assigned to physisorbed $CO_2$, on inner walls of L-zeolite. Overall, the broad resonance component is similar to our previous results of highly dispersed (80-96%) CO/Pt/silica or CO/Pt/alumina samples, still showing metallic characters. The principal difference is in the first moment value. The broad peak in the spectra is assigned to CO linearly bound to Pt particles in the L-zeolites, and indicates a distribution of isotropic shifts from bonding site to bonding site. The NMR results reported here manifest that the Pt particles inside of the L-zeolites channels are not collectively the same with the ones supported on silica or alumina with similar dispersion in terms of Pt particle shape and/or ordering of Pt atoms in a particle. As a result, Pt particles of CO/Pt/L-zeolite were agglomerated accompanying CO desorption upon annealing. There were no definite changes in the NMR spectra due to differences of exchanged cations. Comparison of our observation on CO/Pt/L-zeolite with Sharma et al.'s reveals that even when the first moment, the linewidtb, and the relaxation times of the static spectra and the dispersion measured by chemisorption are similar, the properties of Pt particles can be dramatically different. Therefore, it is essential to take advantage of the strengths of several techniques together in order to interpret data reliably, especially for the highly dispersed samples.

• Earthquakes and Structures
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• v.26 no.2
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• pp.131-147
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• 2024

Damage caused by an earthquake depends on not just the intensity of an earthquake but also the region-specific construction practices. Past earthquakes in Asian countries have highlighted inadequate construction practices, which caused huge life and property losses, indicating the severe need to strengthen existing structures. Strengthening activities shall be proposed as per the proposed weighting factors, first at the higher weighted members to increase the capacity of the building immediately and thereafter, the other members. Through this study on gravity load-designed (GLD) buildings, relative weights are assigned to each storey and exterior and interior columns within a storey based on their contribution to the energy dissipation capacity of the building. The numerical study is conducted on mid-rise archetype GLD buildings, i.e., 4, 6, 8, and 10 stories with variable storey heights, in the high seismic zones. Non-linear static analysis is performed to compute weights based on energy dissipation capacities. The results obtained are verified with the non-linear time history analysis of 4 GLD buildings. It was observed that exterior columns have higher weightage in the energy dissipation capacity of the building than interior columns up to a certain building height. The damage in stories is distributed in a convex to concave parabolic shape from bottom to top as building height increases, and the maxima location of the parabola shifts from bottom to middle stories. Relative weighting factors are assigned as per the damage contribution. And the sequence for strengthening activities is proposed as per the computed weighting factors in descending order for regular RCC buildings. Therefore, proposals made in the study would increase the efficacy of strengthening activities.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.9 no.4
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• pp.772-776
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• 2005

To support abruptly increasing data traffic in these days, network management is needed. And also to maintain the steady infra, there is MPLS need which can support traffic engineering. It's necessary that MPLS doesn't only manage network to support recently booming data traffic, but has capacity to support traffic engineering to keep static infrastructure. Traffic engineering, method that a large-scale user shifts traffic to the beforehand designated routes that pass through specific nodes on network, is operation that is mapping traffic flow to the physical network topology. In this paper, we supplement the defect of the traditional RSVP traffic engineering and to construct far more steady infra, we suggest the way of its development of ERSVP signaling protocol.

• Applied Science and Convergence Technology
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• v.23 no.4
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• pp.192-199
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• 2014

The electronic property of graphene was investigated by hydrazine treatment. Hydrazine ($N_2H_4$) highly increases electron concentrations and up-shifts Fermi level of graphene based on significant shift of Dirac point to the negative gate voltage. We have observed contact resistance and channel length dependent mobility of graphene in the back-gated device after hydrazine monohydrate treatment and continuously monitored electrical characteristics under Nitrogen or air exposure. The contact resistance increases with hydrazine-treated and subsequent Nitrogen-exposed devices and reduces down in successive Air-exposed device to the similar level of pristine one. The channel conductance curve as a function of gate voltage in hole conduction regime keeps analogous value and shape even after Nitrogen/Air exposure specially whereas, in electron conduction regime change rate of conductance along with the level of conductance with gate voltage are decreased. Hydrazine could be utilized as the highly effective donor without degradation of mobility but the stability issue to be solved for future application.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• v.9 no.1
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• pp.105-108
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• 2005

To support abruptly increasing data traffic in these days. network management is needed. And also to maintain the steady infra, there is MPLS need which can support traffic engineering. It's necessary that MPLS doesn't only manage network to support recently booming data traffic, but has capacity to support traffic engineering to keep static infrastructure. Traffic engineering, method that a large-scale user shifts traffic to the beforehand designated routes that pass through specific nodes on network, is operation that is mapping traffic flow to the physical network topology. In this paper, we supplement the defect of the traditional RSVP traffic engineering and to construct far more steady infra, we suggest the way of its development of ERSVP signaling protocol.

• Journal of Intelligence and Information Systems
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• v.9 no.3
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• pp.23-47
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• 2003

Traditional studies for customer relationship management (CRM) generally focus on static CRM in a specific time frame. The static CRM and customer behavior knowledge derived could help marketers to redirect marketing resources fur profit gain at that given point in time. However, as time goes, the static knowledge becomes obsolete. Therefore, application of CRM to an online retailer should be done dynamically in time. Customer-based analysis should observe the past purchase behavior of customers to understand their current and likely future purchase patterns in consumer markets, and to divide a market into distinct subsets of customers, any of which may conceivably be selected as a market target to be reached with a distinct marketing mix. Though the concept of buying-behavior-based CRM was advanced several decades ago, virtually little application of the dynamic CRM has been reported to date. In this paper, we propose a dynamic CRM model utilizing data mining and a Monitoring Agent System (MAS) to extract longitudinal knowledge from the customer data and to analyze customer behavior patterns over time for the Internet retailer. The proposed model includes an extensive analysis about a customer career path that observes behaviors of segment shifts of each customer: prediction of customer careers, identification of dominant career paths that most customers show and their managerial implications, and about the evolution of customer segments over time. furthermore, we show that dynamic CRM could be useful for solving several managerial problems which any retailers may face.

• Journal of Distribution Science
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• v.14 no.1
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• pp.93-102
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• 2016

Purpose - The purpose of paper is studying the static and dynamic side for long-term memory storage properties, and increase the explanatory power regarding the long-term memory process by looking at the long-term storage attributes, Korea Composite Stock Price Index. The reason for the use of GPH statistic is to derive the modified statistic Korea's stock market, and to research a process of long-term memory. Research design, data, and methodology - Level shifts were subjected to be an empirical analysis by applying the GPH method. It has been modified by taking into account the daily log return of the Korea Composite Stock Price Index a. The Data, used for the stock market to analyze whether deciding the action by the long-term memory process, yield daily stock price index of the Korea Composite Stock Price Index and the rate of return a log. The studies were proceeded with long-term memory and long-term semiparametric method in deriving the long-term memory estimators. Chapter 2 examines the leading research, and Chapter 3 describes the long-term memory processes and estimation methods. GPH statistics induced modifications of statistics and discussed Whittle statistic. Chapter 4 used Korea Composite Stock Price Index to estimate the long-term memory process parameters. Chapter 6 presents the conclusions and implications. Results - If the price of the time series is generated by the abnormal process, it may be located in long-term memory by a time series. However, test results by price fixed GPH method is not followed by long-term memory process or fractional differential process. In the case of the time-series level shift, the present test method for a long-term memory processes has a considerable amount of bias, and there exists a structural change in the stock distribution market. This structural change has implications in level shift. Stratum level shift assays are not considered as shifted strata. They exist distinctly in the stock secondary market as bias, and are presented in the test statistic of non-long-term memory process. It also generates an error as a long-term memory that could lead to false results. Conclusions - Changes in long-term memory characteristics associated with level shift present the following two suggestions. One, if any impact outside is flowed for a long period of time, we can know that the long-term memory processes have characteristic of the average return gradually. When the investor makes an investment, the same reasoning applies to him in the light of the characteristics of the long-term memory. It is suggested that when investors make decisions on investment, it is necessary to consider the characters of the long-term storage in reference with causing investors to increase the uncertainty and potential. The other one is the thing which must be considered variously according to time-series. The research for price-earnings ratio and investment risk should be composed of the long-term memory characters, and it would have more predictability.

• Journal of Mechanical Science and Technology
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• v.18 no.2
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• pp.185-192
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• 2004

The aeroacoustic characteristics of a centrifugal fan for a vacuum cleaner and its noise reduction method are studied in this paper. The major noise source of a vacuum cleaner is the centrifugal fan. The impeller of the fan rotates at over 30000 rpm, and generates very high-level noise. It was revealed that the dominant noise source is the aerodynamic interaction between the rotating impeller and stationary diffuser. The directivity of acoustic pressure showed that most of the noise propagates backward direction of the fan-motor assembly. In order to reduce the high tonal sound generated from the aerodynamic interaction, unevenly pitched impeller and diffuser, and tapered impeller designs were proposed and experiments were performed. Uneven pitch design of the impeller changes the sound quality while the overall sound power level (SPL) and the performance remains similar. The effect of the tapered design of impeller was evaluated. The trailing edge of the tapered fan is inclined. This reduces the flow interaction between the rotating impeller and the stationary diffuser because of some phase shifts. The static efficiency of the new impeller design is slightly lower than the previous design. However, the overall SPL is reduced by about 4 dB(A). The SPL of the fundamental blade passing frequency (BPF) is reduced by about 6 dB (A) and the 2$\^$nd/ BPF is reduced about 20 dB (A). The vacuum cleaner with the tapered impeller design produces lower noise level than the previous one, and the strong tonal sound was dramatically reduced.

• Structural Engineering and Mechanics
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• v.89 no.6
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• pp.617-626
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• 2024

The study investigated the behavior of plain and fibered Ultra-High Performance Concrete (UHPC) beams under varying loading conditions using integrated analysis of the flexure and acoustic emission tests. The loading rate of testing is -0.25 -2 mm/min. It is observed that on increasing loading rate, flexural strength increases, and toughness decreases. The acoustic emission testing revealed that higher loading rates accelerate crack propagation. Fiber effect and matrix cracking are identified as significant contributors to the release of acoustic emission energy, with fiber rupture/failure and matrix cracking showing rate-dependent behavior. Crack classification analysis indicated that the rise angle (RA) value decreased under quasi-static loading. The average frequency (AF) value increased with the loading rate, but this trend reversed under rate-dependent conditions. K-means analysis identified distinct clusters of crack types with unique frequency and duration characteristics at different loading rates. Furthermore, the historic index and signal strength decreased with increasing loading rate after peak capacity, while the severity index increased in the post-peak zone, indicating more severe damage. The sudden rise in the historic index and cumulative signal strength indicates the possibility of several occurrences, such as the emergence of a significant crack, shifts in cracking modes, abrupt failure, or notable fiber debonding/pull-out. Moreover, there is a distinct rise in the number of AE knees corresponding to the increase in loading rate. The crack mapping from acoustic emission testing aligned with observed failure patterns, validating its use in structural health monitoring.

• Geophysics and Geophysical Exploration
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• v.19 no.1
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• pp.11-19
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• 2016

Two representative residual static methods of traveltime decomposition and stack-power maximization are discussed in terms of application to land seismic data. For the model data with synthetic shot/receiver statics (time shift) applied and random noises added, continuities of reflection event are much improved by stack-power maximization method, resulting the derived time-shifts approximately equal to the synthetic statics. Optimal parameters (maximum allowable shift, correlation window, iteration number) for residual statics are effectively chosen with diagnostic displays of CSP (common shot point) stack and CRP (common receiver point) stack as well as CMP gather. In addition to removal of long-wavelength time shift by refraction statics, prior to residual statics, processing steps of f-k filter, predictive deconvolution and time variant spectral whitening are employed to attenuate noises and thereby to minimize the error during the correlation process. The reflectors including horizontal layer of reservoir are more clearly shown in the variable-density section through repicking the velocities after residual statics and inverse NMO correction.