• Bulletin of the Korean Chemical Society
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• v.10 no.3
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• pp.262-269
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• 1989

The gas phase thermal decomposition of 1-bromo-3-chloropropane in the presence of radical inhibitor was studied by using the conventional static system. The mechanism of unimolecular elimination channel is shown below. [...] In this scheme, the total molecular dissociation rate constant, ($k_1\;+\;k_2$), for the decomposition of $BrCH_2CH_2CH_2Cl$ was determined by pyrolyzing the $BrCH_2CH_2CH_2Cl$ in the temperature range of $380-420^{\circ}C$ and in the pressure range of 10∼100 torr. To obtain $k_3\;and\;k_4,\;and\;to\;obtain\;k_1\;and\;k_2$ independently, the thermal decompositions of allyl chloride and allyl bromide were also studied. The Arrhenius parameters for each step are as follows; $log\;A_{\infty}\;=\;14.20(sec^{-1}),\;E_a$ = 56.10(kcal/mol) for reaction path 1; $log\;A_{\infty}\;=\;12.54(sec^{-1}),\;E_a$ = 49.75(kcal/mol) for reaction path 2; $log\;A_{\infty}\;=\;13.41(sec^{-1}),\;E_a$ = 50.04(kcal/mol) for reaction path 3; $log\;A_{\infty}\;=\;12.43(sec^{-1}),\;E_a$ = 52.78(kcal/mol) for reaction path 4; Finally, the experimentally observed pressure dependence of the rate constants in each step is compared with the theoretically predicted values that are obtained by the RRKM calculations.

• Structural Engineering and Mechanics
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• v.78 no.5
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• pp.519-528
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• 2021

One of the most efficient designs of solar trackers for photovoltaic panels is the single-axis tracker, which holds the panels along a torque tube that is driven by a motor at the central section. These trackers have evolved to become extremely slender structures due to mechanical optimization against static load and the need of cost reduction in a very competitive market. Owing to the corresponding decrease in mechanical resistance, some of these trackers have suffered aeroelastic instability even at moderate wind speeds, leading to catastrophic failures. In the present work, an analytical and experimental approach has been developed to study that phenomenon. The analytical study has led to identify the dimensionless parameters that govern the motion of the panel-tracker structure. Also, systematic wind tunnel experiments have been carried out on a 3D aeroelastic scale model. The tests have been successful in reproducing the aeroelastic phenomena arising in real-scale cases and have allowed the identification and a close characterization of the phenomenon. The main results have been the determination of the critical velocity for torsional galloping as a function of tilt angle and a calculation methodology for the optimal sizing of solar tracker shafts.

• Journal of the Society of Naval Architects of Korea
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• v.57 no.6
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• pp.365-372
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• 2020

Ice induced abrasion is known as a critical problem in concrete gravity based offshore structures, which are mainly used in the arctic regions. Although many researches on ice abrasion have been conducted for the last several decades, there still are some difficulties in designing concrete gravity based offshore structures against abrasion problem because there is no standardized method yet due to the uncertain physics involved in. This paper presents an experimental study for the evaluation of concrete abrasion characteristics due to ice friction on concrete surface. For the test, a testing machine capable of abrasion and friction was designed and produced, and standardized procedure was proposed to produce ice specimen used for abrasion test. For the experiment, compressive strength of the ice specimen were explored through a static compression test. Then the friction test between ice specimen and concrete surface was performed and friction coefficients were derived using measured vertical and horizontal forces. Dependency of friction coefficients on some test parameters were studied and discussed as well.

• Corrosion Science and Technology
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• v.19 no.6
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• pp.288-295
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• 2020

This study investigated the erosion-corrosion characteristics of 5038-H321 aluminum alloy in a natural seawater solution through various electrochemical experiments and flow rate parameters. Cathodic polarization experiments were conducted at flow rates ranging from 4 to 12 knots. Considering the concentration polarization section representing a relatively low current density, the range of the potentiostatic experiment was determined to be -1.6 to -1.0 V. The potentiostatic experiment was conducted at various potentials for 180 minutes in seawater. After the experiment, the corrosion characteristics were evaluated by observing surface morphology and measuring surface roughness. As a result, as the applied potential was lower, the amount of calcareous deposits increased and the roughness tended to increase. On the other hand, it was confirmed that the roughness was larger in the static condition than the flow rate condition due to the influence of the flow velocity. Variations in the chemical composition with flow rate variations were analyzed by energy-dispersive spectroscopy (EDS). In conclusion, the cathodic potential of AA5083-H321 in seawater was determined to be -1.0 V.

• Structural Engineering and Mechanics
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• v.77 no.6
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• pp.819-830
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• 2021

To evaluate the performance of concrete load bearing walls in a structure under horizontal loads after being exposed to real fire, two steps were followed. In the first step, an experimental study was performed on the thermo-mechanical properties of concrete after heating to temperatures of 200-1000℃ with the purpose of determining the residual mechanical properties after cooling. The temperature was increased in line with natural fire curve in an electric furnace. The peak temperature was maintained for a period of 1.5 hour and then allowed to cool gradually in air at room temperature. All specimens were made from calcareous aggregate to be used for determining the residual properties: compressive strength, static and dynamic elasticity modulus by means of UPV test, including the mass loss. The concrete residual compressive strength and elastic modulus values were compared with those calculated from Eurocode and other analytical models from other studies, and were found to be satisfactory. In the second step, experimental analysis results were then implemented into structural numerical analysis to predict the post-fire load-bearing capacity response of the walls under vertical and horizontal loads. The parameters considered in this analysis were the effective height, the thickness of the wall, various support conditions and the residual strength of concrete. The results indicate that fire damage does not significantly affect the lateral capacity and stiffness of reinforced walls for temperature fires up to 400℃.

• Steel and Composite Structures
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• v.38 no.5
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• pp.583-597
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• 2021

This article develops a nonclassical model to analyze bending response of squared perforated microbeams considering the coupled effect of microstructure and surface stress under different loading and boundary conditions, those are not be studied before. The corresponding material and geometrical characteristics of regularly squared perforated beams relative to fully filled beam are obtained analytically. The modified couple stress and the modified Gurtin-Murdoch surface elasticity models are adopted to incorporate the microstructure as well as the surface energy effects. The differential equations of equilibrium including the Poisson's effect are derived based on minimum potential energy. Exact closed form solution is obtained for bending behavior of the proposed model considering the classical and nonclassical boundary conditions for both uniformly distributed and concentrated loads. The proposed model is verified with results available in the literature. Influences of the microstructure length scale parameter, surface energy, beam thickness, boundary and loading conditions on the bending behavior of perforated microbeams are investigated. It is observed that microstructure and surface parameters are vital in investigation of the bending behavior of perforated microbeams. The obtained results are supportive for the design, analysis and manufacturing of perforated nanobeams that commonly used in nanoactuators, nanoswitches, MEMS and NEMS systems.

• Atmosphere
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• v.30 no.4
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• pp.319-333
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• 2020

Aircraft observations constitute one of the major sources of temperature observations which provide three-dimensional information. But it is well known that the aircraft temperature data have warm bias against sonde observation data, and therefore, the correction of aircraft temperature bias is important to improve the model performance. In this study, the algorithm of the bias correction modified from operational KMA (Korea Meteorological Administration) global model is adopted in the preprocessing of aircraft observations, and the effect of the bias correction of aircraft temperature is investigated by conducting the two experiments. The assimilation with the bias correction showed better consistency in the analysis-forecast cycle in terms of the differences between observations (radiosonde and GPSRO (Global Positioning System Radio Occultation)) and 6h forecast. This resulted in an improved forecasting skill level of the mid-level temperature and geopotential height in terms of the root-mean-square error. It was noted that the benefits of the correction of aircraft temperature bias was the upper-level temperature in the midlatitudes, and this affected various parameters (winds, geopotential height) via the model dynamics.

• Structural Engineering and Mechanics
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• v.83 no.1
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• pp.123-134
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• 2022

The stability of cable-stayed bridges is an important factor considered during design. In recent years, the novel spatial diamond-shaped bridge pylon has shown its advantages in various aspects, including the static response and the stability performance with the development of cable-stayed bridge towards long-span and heavy-load. Based on the energy approach, this paper presents a practical calculation method of the completed state stability of a cable-stayed bridge with two spatial diamond-shaped pylons. In the analysis, the possible transverse buckling of the girder, the top pylon column, and the mid pylon columns are considered simultaneously. The total potential energy of the spatial diamond-shaped pylon cable-stayed bridge is calculated. And based on the principle of stationary potential energy, the transverse buckling coefficients and corresponding buckling modes are obtained. Furthermore, an example is calculated using the design parameters of the Changtai Yangtze River Bridge, a 1176 m cable-stayed bridge under construction in China, to verify the effectiveness and accuracy of the proposed method in practical engineering. The critical loads and the buckling modes derived by the proposed method are in good agreement with the results of the finite element method. Finally, cable-stayed bridges varying pylon and girder stiffness ratios and pylon geometric dimensions are calculated to discuss the applicability and advantages of the proposed method. And a further discussion on the degrees of the polynomial functions when assuming buckling modes are presented.

• Structural Engineering and Mechanics
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• v.83 no.1
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• pp.45-51
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• 2022

The need to account for accidental torsion in seismic design is no longer debatable, however, the seismic codes' requirement for accidental eccentricity has recently faced criticism. In order to get as close to real conditions as possible, this study investigated the impact of accidental torsion in symmetric RC multistory buildings caused by one of its many sources, the torsional earthquake component, and compared the results to those obtained by using the accidental eccentricity recommended by the codes (shifting the center of mass). To cover a wide range of frequencies and site conditions, two types of torsion seismic components were used: a recorded torsion accelerogram and five others generated using translation accelerograms. The main parameters that govern seismic responses, such as the number of stories (to account for the influence of all modes of vibration) and the frequency ratio (Ω) variation, were studied in terms of inter-story drift and displacement responses, as well as torsional moment. The results show that the eccentricity ratio of 5% required by most codes for accidental torsion should be reexamined and that it is prudent for computer analysis to use the static moment approach to implement the accidental eccentricity while waiting for new seismic code recommendations on the subject.

• Steel and Composite Structures
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• v.43 no.6
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• pp.707-723
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• 2022

This article aims to investigate the size dependent bending behavior of perforated nanobeams incorporating the nonlocal and the microstructure effects based on the nonlocal strain gradient elasticity theory (NSGET). Shear deformation effect due to cutout process is studied by using Timoshenko beams theory. Closed formulas for the equivalent geometrical characteristics of regularly squared cutout shape are derived. The governing equations of motion considering the nonlocal and microstructure effects are derived in comprehensive procedure and nonclassical boundary conditions are presented. Analytical solution for the governing equations of motion is derived. The derived non-classical analytical solutions are verified by comparing the obtained results with the available results in the literature and good agreement is observed. Numerical results are obtained and discussed. Parametric studies are conducted to explore effects of perforation characteristics, the nonclassical material parameters, beam slenderness ratio as well as the boundary and loading conditions on the non-classical transverse bending behavior of cutout nanobeams. Results obtained are supportive for the design, analysis and manufacturing of such nanosized structural system.