• Bulletin of the Korean Chemical Society
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• 제20권12호
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• pp.1493-1500
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• 1999

The electronic transitions from the ground state to low-lying excited states of CF₃OH have been investigated using high level ab initio quantum mechanical techniques. Also the possible photodissociation procedures of CF₃OH have been considered. The highest level employed in this study is TZP CCSD(T) level of theory. The possible four low-lying excited states can result by the excitation of the lone pair electron (n) in oxygen to σ$^*$ molecular orbital in C-O or O-H bond. The vertical transition (n → σ$^*$) energy is predicted to be 220.5 kcal/mol (130 nm) at TZ2P CISD level to theory. The bond dissociation energies of CF₃OH to CF₃O +H and CF₃+OH have been predicted to be 119.5 kcal/mol and 114.1 kcal/mol, respectively, at TZP CCSD level of theory. In addition, the transition state for the unimolecular decomposition of CF₃OH into CF₂O + HF has been examined. The activation energy and energy separation for this decomposition have been computed to be 43.6kcal/mol and 5.0 kcal/mol including zero-point vibrational energy corrections at TZP CCSD(T) level of theory.ed phenols were also estimated.

• 한국음향학회지
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• 제13권4호
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• pp.40-49
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• 1994

본 논문에서는 단어 인식 시스템의 성능 개선을 위하여 다음과 같은 두가지 방법을 제안한다. 첫번째 방법은 VQ 코드간의 천이를 안정화시키기 위하여 음성신호의 특징벡터 시퀀스에 관성을 적용하는 방법이고, 두번째 방법은 이산 HMM 모델에서 인접 프레임 간의 시간 상관성을 고려하기 위하여 VQ 코드의 천이행렬을 출력 심벌의 관측확률에 가중치로 이용하여 새로운 관측확률을 발생하는 방법이다. 특징벡터 시퀀스에 관성을 도입함으로서, SOFM상의 각 단어에 대한 반응경로에서 확률분포가 중첩되는 것을 억제하여 HMM의 상태천이를 안정화 시킬 수 있다. 기존의 이산 HMM에 VQ 코드의 천이행렬을 가중치로 적용함으로써, 특징벡터의 확률분포를 더욱 세분화하고, 특징분포를 적당한 영역으로 제한함으로써 인식시스템의 성능을 개선할 수 있다. 제안한 방법을 평가하기 위하여 50개의 DDD 지역명을 대상으로 인식 실험을 수행하였다. 실험 결과에 의하면, 제안된 방법이 기존의 HMM 모델에 비해 화자종속 실험에서는 $4.2\%$의 인식률 향상과 화자 독립 실험에서는 $12.45\%$의 인식률 향상을 얻을 수 있었다.

• 한국재료학회지
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• 제29권12호
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• pp.741-746
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• 2019

New triple tungstate phosphors NaPbLa(WO₄)₃:Yb³⁺/Ho³⁺ (x = Yb³⁺/Ho³⁺ = 7, 8, 9, 10) are successfully fabricated by microwave assisted sol-gel synthesis and their structural and frequency upconversion (UC) characteristics are investigated. The compounds crystallized in the tetragonal space group I4₁/a and the NaPbLa(WO₄)₃ host have unit cell parameters a = 5.3927(1) and c = 11.7961(3) Å, V = 343.05(2) ų, Z = 4. Under excitation at 980 nm, the phosphors have yellowish green emissions, which are derived from the intense ⁵S₂/⁵F₄→⁵I₈ transitions of Ho³⁺ ions in the green spectral range and strong ⁵F₅→⁵I₈ transitions in the red spectral range. The optimal Yb³⁺:Ho³⁺ ratio is revealed to be x = 9, which is attributed to the quenching effect of Ho³⁺ ions, as indicated by the composition dependence. The UC characteristics are evaluated in detail under consideration of the pump power dependence and Commission Internationale de L'Eclairage chromaticity. The spectroscopic features of Raman spectra are discussed in terms of the superposition of Ho³⁺ luminescence and vibrational lines. The possibility of controlling the spectral distribution of UC luminescence by the chemical content of tungstate hosts is demonstrated.

• Korea-Australia Rheology Journal
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• 제21권4호
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• pp.213-223
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• 2009

Taylor-Couette flow (i.e., flow between concentric, rotating cylinders) has long served as a paradigm for studies of hydrodynamic stability. For Newtonian fluids, the rich cascade of transitions from laminar, Couette flow to turbulent flow occurs through a set of well-characterized flow states (Taylor Vortex Flow, wavy Taylor vortices, modulated wavy vortices, etc.) that depend on the Reynolds numbers of both the inner and outer cylinders ($Re_i$ and $Re_o$). While extensive work has been done on (a) the effects of weak viscoelasticity on the first few transitions for $Re_o=0$ and (b) the effects of strong viscoelasticity in the limit of vanishing inertia ($Re_i$ and $Re_o$ both vanishing), the viscoelastic Taylor-Couette problem presents an enormous parameter space, much of which remains completely unexplored. Here we describe our recent experimental efforts to examine the effects of drag reducing polymers on the complete range of flow states observed in the Taylor-Couette problem. Of particular importance in the present work is 1) the rheological characterization of the test solutions via both shear and extensional (CaBER) rheometry, 2) the wide range of parameters examined, including $Re_i$, $Re_o$ and Elasticity number E1, and 3) the use of a consistent, conservative protocol for accessing flow states. We hope that by examining the stability changes for each flow state, we may gain insights into the importance of particular coherent structures in drag reduction, identify simple ways of screening new drag reducing additives, and improve our understanding of the mechanism of drag reduction.

• 한국재료학회지
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• 제19권4호
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• pp.220-223
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• 2009

Lithium dihydrogen phosphate ($LiH_2PO_4$) powder was purchased from Aldrich Chemical Co. From the scanning electron microscope (SEM) observation, these polycrystals have dimensions in the range of $25-250{\mu}m$. The electrical conductivity was measured at a measuring frequency of 1 kHz on heating polycrystalline lithium dihydrogen phosphate ($LiH_2PO_4$) from room temperature to 493 K. Two anomalies appeared at 451 K ($T_{p1}$) and 469 K ($T_{p2}$). The electrical conductivity reached the magnitude of the superprotonic phases: $3{\times}10^{-2}{\Omega}^{-1}cm^{-1}$ at 451 K ($T_{p1}$) and $1.2{\times}10{\Omega}^{-1}cm^{-1}$ at 469 K ($T_{p2}$). It is uncertain whether the superprotonic phase transformations are due to polymorphic transitions in the bulk, surface transitions, or chemical reactions (thermal decomposition) at the surface. Considering several previous thermal studies (differential scanning calorimetry and thermogravimetry), our experimental results seem to be related to the last case: chemical reactions (thermal decomposition) at the surface with the progressive solid-state polymerization.

• 한국컴퓨터정보학회논문지
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• 제26권8호
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• pp.173-180
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• 2021

이 연구의 목적은 고등학교 진학 청소년이 지각하는 부모의 양육방식이 삶의 만족도에 미치는 영향을 파악하고 이 두 변수 사이에서 자아존중감이 매개변수로 기능하는지 확인하는 것이다. 이를 위해 지각된 양육방식, 자아존중감, 삶의 만족도 사이의 매개효과 관계를 가정하는 연구모형을 설계하였다. 연구모형을 검증하기 위해 분석한 자료는 한국아동·청소년패널조사(2010-2016)의 초4패널의 6차와 7차 자료이다. 주요 분석결과는 다음과 같다. 첫째, 부모의 민주적 양육방식은 삶의 만족도를 높이는 긍정적 효과를 나타냈으나, 통제적 양육방식이 삶의 만족도에 미치는 영향은 유의하지 않았다. 둘째, 자아존중감은 민주적 양육방식과 삶의 만족도 사이의 관계를 부분매개하였다. 셋째, 자아존중감은 통제적 양육방식과 삶의 만족도 사이의 관계를 완전매개하였다. 이와 같은 분석 결과를 바탕으로 부모의 양육방식 개선과 청소년 자녀의 자아존중감 강화를 위한 함의에 대하여 논의하였다.

• 한국전기전자재료학회논문지
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• 제36권5호
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• pp.505-512
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• 2023

This study investigated crystal structures, microstructures, and electric-field-induced strain (EFIS) properties of Bi-based lead-free ferroelectric/relaxor composites. Bi_1/2Na_0.82K_0.18)_1/2TiO₃ (BNKT) as a ferroelectric material and 0.78Bi_1/2(Na_0.78K_0.22)_1/2TiO₃-0.02LaFeO₃ (BNKT2LF) as a relaxor material were synthesized using a conventional solid-state reaction method, and the resulting BNKT2LF powders were subjected to high-energy ball milling (HEBM) after calcination. As a result, HEBM proved a larger average grain size of sintered samples compared to conventional ball milling (CBM). In addition, the increased sintering time led to grain growth. Furthermore, HEBM treatment and sintering time demonstrated a significant effect on EFIS of BNKT/BNKT2LF composites. At 6 kV/mm, 0.35% of the maximum strain (S_max) was observed in the HEBM sample sintered for 12 h. The unipolar strain curves of CBM samples were almost linear, indicating almost no phase transitions, while HEBM samples displayed phase transitions at 5~6 kV/mm for all sintering time levels, showing the highest S_max/E_max value of 700 pm/V. These results indicated that HEBM treatment with a long sintering time might significantly enhance the electromechanical strain properties of BNT-based ceramics.

• Journal of Mechanical Science and Technology
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• 제18권9호
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• pp.1512-1518
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• 2004

Rescaled Simulated Annealing (RSA) has been adapted to solve combinatorial optimization problems in which the available computational resources are limited. Simulated Annealing (SA) is one of the most popular combinatorial optimization algorithms because of its convenience of use and because of the good asymptotic results of convergence to optimal solutions. However, SA is too slow to converge in many problems. RSA was introduced by extending the Metropolis procedure in SA. The extension rescales the state's energy candidate for a transition before applying the Metropolis criterion. The rescaling process accelerates convergence to the optimal solutions by reducing transitions from high energy local minima. In this paper, structural optimization examples using RSA are provided. Truss structures of which design variables are discrete or continuous are optimized with stress and displacement constraints. The optimization results by RSA are compared with the results from classical SA. The comparison shows that the numbers of optimization iterations can be effectively reduced using RSA.

• 전기학회논문지
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• 제57권1호
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• pp.109-116
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• 2008

Model matching problem of asynchronous sequential machines is addressed in this paper. The main topic is to design a corrective controller such that the closed-loop behavior of the asynchronous sequential machine can follow a given model, i.e., their models can be "matched" in stable states. In particular, we assume that the considered asynchronous machine suffers from the presence of an input disturbance that can cause undesirable state transitions. The proposed controller can realize both model matching and elimination of the adverse effect of the input disturbance. Necessary and sufficient condition for the existence of a corrective controller that solves model matching problem is presented. Whenever controller exists, algorithms for their design are outlined and demonstrated in a case study.

• 한국콘텐츠학회:학술대회논문집
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• 한국콘텐츠학회 2007년도 추계 종합학술대회 논문집
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• pp.197-200
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• 2007

동적 전력 관리는 서로 다른 전력소모를 갖는 전력상태들을 시스템 구성 요소에 할당하고 상황별로 전력상태를 관리함으로써 시스템의 전력 소모를 현저하게 줄여줄 수 있다. 전력관리의 주 기능은 구성요소의 상태천이를 언제 수행하느냐 이며 이를 위하여 추계적 프로세스에 기반한 동적 전력관리 모델을 개발한다. 동적 모델은 시스템 큐와 다양한 모델링 기능을 표현할 수 있는 페트리 네트의 확장형인 SRN(Stochastic Reward Nets)을 이용하여 개발되며 성능분석을 함께 수행한다.