• Title/Summary/Keyword: state coupling

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Effects of iron atom, substrate on two-dimensional C2N crystals

  • Noh, Min Jong;Kim, Yong Hoon
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.288-291
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    • 2016
  • Recently, there has been a lot of researches related to two-dimensional (2D) materials due to their new properties and applications emerging upon 2D confinement. A new type of graphene like two-dimensional layer material, nitrogenated holey two-dimensional structure C2N-h2D, that is possession of evenly distributed holes and nitrogen atoms with proper bandgap has been synthesized. Previous calculation studies already have shown that the variance of the orbital interaction, band structure of few-layer C2N-h2D suggests that interlayer coupling does play an important role in its electronic properties. In this point, using first-principles density functional theory calculation, we here explore the effect of porous embedded iron atom and iron substrate on encapsulated few layer C2N-h2D. We show the atomic structures and the corresponding electronic structures of Fe@C2N to elucidate the effect of iron. Finally, this study demonstrates that embedded iron C2N has AA-stacking as most favorable stacked structure in contrast to pure C2N. In addition, iron substrate modifies its encapsulated C2N from semi-metallic states to metallic state.

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An Electric-Field Coupled Power Transfer System with a Double-sided LC Network

  • Xie, Shi-Yun;Su, Yu-Gang;Zhou, Wei;Zhao, Yu-Ming;Dai, Xin
    • Journal of Power Electronics
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    • v.18 no.1
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    • pp.289-299
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    • 2018
  • Electric-field coupled power transfer (ECPT) systems employ a high frequency electric field as an energy medium to transfer power wirelessly. Existing ECPT systems have made great progress in terms of increasing the transfer distance. However, the topologies of these systems are complex, and the transfer characteristics are very sensitive to variations in the circuit parameters. This paper proposes an ECPT system with a double-sided LC network, which employs a parallel LC network on the primary side and a series LC network on the secondary side. With the same transfer distance and output power, the proposed system is simpler and less sensitive than existing systems. The expression of the optimal driving voltage for the coupling structure and the characteristics of the LC networks are also analyzed, including the transfer efficiency, parameter sensitivity and total harmonic distortion. Then, a design method for the system parameters is provided according to these characteristics. Simulations and experiments have been carried out to verify the system properties and the design method.

Islanding Detection for a Micro-Grid based on the Instantaneous Active and Reactive Powers in the Time Domain (시간영역에서 순시 유효/무효전력을 이용한 마이크로그리드의 단독운전 판단)

  • Lee, Young-Gui;Kim, Yeon-Hee;Zheng, Tai-Ying;Kim, Tae-Hyun;Kang, Yong-Cheol
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.1
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    • pp.22-27
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    • 2012
  • Correct and fast detection of a micro-grid (MG) islanding is essential to the MG since operation, control and protection of the MG depend on an operating mode i.e., an interconnected mode or an islanding mode. When islanding occurs, the frequency of the point of common coupling (PCC) is not the nominal frequency during the transient state owing to the frequency rise or drop of generators in the MG. Thus, the active and reactive power calculated by the frequency domain based method such as Fourier Transform might contain some errors. This paper proposes an islanding detection algorithm for the MG based on the instantaneous active and reactive powers delivered to the dedicated line in the time domain. During the islanding mode, the instantaneous active and reactive powers delivered to the dedicated line are constants, which depend on the voltage of the PCC and the impedance of the dedicated line. In this paper, the instantaneous active and reactive powers are calculated in the time domain and used to detect islanding. The performance of the proposed algorithm is verified under various scenarios including islanding conditions, fault conditions and load variation using the PSCAD/EMTDC simulator. The results indicate that the algorithm successfully detects islanding for the MG.

A Study on the Dielectric and Piezoelectric Properties of xPb($Y_{1/2}Ta_{1/2})O_3-(1-x)Pb(Zr_{0.52}Ti_{0.48})O_3$Ceramics (xPb($Y_{1/2}Ta_{1/2})O_3-(1-x)Pb(Zr_{0.52}Ti_{0.48})O_3$ 세라믹스의 유전 및 압전 특성에 관한 연구)

  • 강도원;김태열;김범진;김명호;박태곤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.294-296
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    • 1999
  • Solid solution ceramics having various ratios between xPb( $Y_{1}$2/T $a_{1}$2/) $O_3$ and Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_3$were synthesized by a conventional solid state reaction for well sintered specimens, dielectric and piezoelectric prperties were studied as a function of composition. The dielectric constant of PYT-PZT ceramics of 4 mol% PYT was 1,424 at room temperature. The maximum value of electromechanical couping facotr $k_{p}$ of 51% $k_{t}$ of 30% were obtained at the composition of 4 mol% PYT, howerver mechanical quality factor( $Q_{m}$) had a minimum value of 69 at 4 mol% PYT. Also the maximum value of piezoelectric constant of $D_{33}$(310[pC/N]) and $d_{31}$(-131[pC/N]) were obtained at the composition of 4 mol% PYT content.ntent.t.t.t.

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Dielectric and Piezoelectric Properties of (Na,K,Li)(Nb,Sb,Ta)O3 Ceramics as a Function of CuO Addition (CuO 첨가에 따른 (Na,K,Li)(Nb,Sb,Ta)O3 세라믹스의 유전 및 압전 특성)

  • Lee, KabSoo;Kim, YouSeok;Yoo, JuHyun;Mah, Sukbum
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.10
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    • pp.630-634
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    • 2014
  • $(Na_{0.525}K_{0.4425}Li_{0.0375})(Nb_{0.9975}Sb_{0.065}Ta_{0.0375})O_3+0.3 wt%CoO$ ceramics were fabricated as a function of CuO addition by traditional solid state sintering process in order to develop excellent lead-free piezoelectric ceramics composition. The addition of CuO in the LNKNTS composition ceramics can effectively enhance the densification of the ceramics, resulting in the oxygen vacancies as hardening effect. The excellent piezoelectric properties of electromechanical coupling factor($k{\small}_P$) of 0.378, piezoelectric constant($d_{33}$) of 152 pC/N were obtained from the 1.0 mol% CuO doped LNKNTS ceramics sintered at $1,020^{\circ}C$ for 3 h.

Feasibility of Streaming Potential Signal on Estimation of Solute Transport Characteristics

  • Kabir, Mohammad Lutful;Ji, Sung- Hoon;Lee, Jin-Yong;Koh, Yong- Kwon
    • Journal of Soil and Groundwater Environment
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    • v.20 no.2
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    • pp.41-46
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    • 2015
  • The drag of the excess charge in an electrical double layer at the solid fluid interface due to water flow induces the streaming current, i.e., the streaming potential (SP). Here we introduce a sandbox experiment to study this hydroelectric coupling in case of a tracer test. An acrylic tank was filled up with homogeneous sand as a sand aquifer, and the upstream and downstream reservoirs were connected to the sand aquifer to control the hydraulic gradient. Under a steady-state water flow condition, a tracer test was performed in the sandbox with the help of peristaltic pump, and tracer samples were collected from the same interval of five screened wells in the sandbox. During the tracer test, SP signals resulting from the distribution of 20 nonpolarizable electrodes were measured at the top of the tank by a multichannel meter. The results showed that there were changes in the observed SP after injection of tracer, which indicated that the SP was likely to be related to the solute transport.

The structures and catalytic activities of metallic nanoparticles on mixed oxide

  • Park, Jun-Beom
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.339-339
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    • 2010
  • The metallic nanoparticles (Pt, Au, Ag. Cu, etc.) supported on ceria-titania mixed oxide exhibit a high catalytic activity for the water gas shift reaction ($H_2O\;+\;CO\;{\leftrightarrow}\;H_2\;+\;CO_2$) and the CO oxidation ($O_2\;+\;2CO\;{\leftrightarrow}\;2CO_2$). It has been speculated that the high catalytic activity is related to the easy exchange of the oxidation states of ceria ($Ce^{3+}$ and $Ce^{4+}$) on titania, but very little is known about the ceria titanium interaction, the growth mode of metal on ceria titania complex, and the reaction mechanism. In this work, the growth of $CeO_x$ and Au/$CeO_x$ on rutile $TiO_2$(110) have been investigated by Scanning Tunneling Microscopy (STM), Photoelectron Spectroscopy (PES), and DFT calculation. In the $CeO_x/TiO_2$(110) systems, the titania substrate imposes on the ceria nanoparticles non-typical coordination modes, favoring a $Ce^{3+}$ oxidation state and enhancing their chemical activity. The deposition of metal on a $CeO_x/TiO_2$(110) substrate generates much smaller nanoparticles with an extremely high activity. We proposed a mechanism that there is a strong coupling of the chemical properties of the admetal and the mixed-metal oxide: The adsorption and dissociation of water probably take place on the oxide, CO adsorbs on the admetal nanoparticles, and all subsequent reaction steps occur at the oxide-admetal interface.

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Parameter Optimization for Vibration Control of a Cantilever Beam Using Piezoelectric Shunt Damping System (압전분기회로를 이용한 보 구조물의 진동제어 파라미터 최적화 해석)

  • Lim K.C.;Cho D.S.;Park W.C.;Kee C.D.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.918-921
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    • 2005
  • According to the mechanical-electrical coupling characteristics and the electrical Impedance property of resistor-inductor-capacitor(RLC) series resonant circuit, the mechanical impedance analysis of a bimorph piezoceramic patch shunted with a series RLC resonant circuit is conducted. The displacement transfer function of a cantilever beam bonded with a piezoelectric shunt damping module is deduced in the case of single mode vibration of the beam. By the use of vibration damping theory of tuned mass damper system, the parameter optimization of piezoelectric shunt damping system is performed. The optimal resonant state of the shunting circuit can be obtained when the resister and conductor are optimally adjusted. Test results show that the vibration control effect as well improved with optimized piezoelectric shunt system.

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PROTEIN CONFORMATIONS OF OCTOPUS RHODOPSIN AND ITS DEPROTONATED PHOTOCYCLE INTERMEDIATE MONITORED BY ABSORPTION AND PROTEIN FLUORESCENCE

  • Jang, Du-Jeon;Lee, SunBae
    • Journal of Photoscience
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    • v.2 no.1
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    • pp.19-25
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    • 1995
  • Picosecond time-resolved and static protein fluorescence spectra and absorption spectra of octopus rhodopsin, a photorecepting protein, are measured and compared with those of bacteriorhodopsin, a photon-induced proton pumping protein, to understand the protein conformations and functions of octopus rhodopsin and its deprotonated photocycle intermediate. The bluer and weaker absorption of retinal indicates that octopus rhodopsin is better in thermal noise suppression but less efficient in light harvesting than bacteriorhodopsin. The protein fluorescence of octopus rhodopsin shows the characteristic of Trp only and the uantum efficiency and lifetime variations may result primarily from variations in the coupling strength with the retinal. The stronger intensity by four times and larger red shift by 12 nm of fluorescence suggest that octopus rhodopsin has more open and looser structure compared with bacteriorhodopsin. Fluorescence decay profiles reveal two decay components of 300 ps (60%) and 2 ns (40%). The deprotonation of protonated Schiff's base increases the shorter decay time to 500 ps and enhances the fluorescence intensity by 20%. The fluorescence and its decay time from Trp residues near retinal are influenced more by the deprotonation. The increase of fluorescence intimates that protein structure becomes loosened and relaxed further by the deprotonation of protonated Schiff's base. The driving force of sequential changes initiated by absorption of a photon is too exhausted after the deprotonation to return the intermediate to the ground state of the begun rhodopsin form.

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A Study on Machining of A V-groove on the Optical Fiber Connector Using a Miniaturized Machine Tool (소형공작기계를 이용한 광커넥터용 V 홈 가공에 관한 연구)

  • 이재하;박성령;양승한;이영문
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.5
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    • pp.38-45
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    • 2004
  • As optical communication is being substituted for telecommunication, the demand of a large variety of fiber optic components is increasing. V-groove substrates, one of the module components, are used to connect optical fibers to optical planar circuits and to arrange fibers. Their applications are multi-channel optical connectors and optical waveguide fiber coupling, etc. Because these substrates are a critical part of the splitter in a multiplexer and a multi fiber connector, precise and reliable fabrication process is required. For precisely aligning core pitch between fibers, machined core pitch tolerance should be within sub-microns. Therefore, these are generally produced by state-of-the-art micro-fabrication like MEMS. However, most of the process equipment is very expensive. It is also difficult to change the process line for custom designs to meet specific requirements using various materials. For various design specifications such as different values of the V angle and low-priced process, the fabrication method should be flexible and low cost. To achieve this goal, we have suggested a miniaturized machine tool with high accuracy positioning system. Through this study, it is shown that this cutting process can be applied to produce V-groove subtracts. We also show the possibility of using a miniaturized machining system for producing small parts.