• Title/Summary/Keyword: stack operation

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kW-class Diesel Autothermal Reformer with Microchannel Catalyst for Solid Oxide Fuel Cell System (고체산화물 연료전지 시스템을 위한 kW급 마이크로채널 촉매 디젤 자열 개질기)

  • Yoon, Sang-Ho;Kang, In-Yong;Bae, Gyu-Jong;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.7
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    • pp.558-565
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    • 2008
  • Solid oxide fuel cell(SOFC) has a higher fuel flexibility than low temperature fuel cells, such as polymer electrolyte fuel cell(PEMFC) and phosphoric acid fuel cell(PAFC). SOFCs also use CO and $CH_4$ as a fuel, because SOFCs are hot enough to allow the CH4 steam reformation(SR) reaction and water-gas shift(WGS) reaction occur within the SOFC stack itself. Diesel is a good candidate for SOFC system fuel because diesel reformate gas include a higher degree of CO and $CH_4$ concentration than other hydrocarbon(methane, butane, etc.) reformate gas. Selection of catalyst for autothermalr reforming of diesel was performed in this paper, and characteristics of reforming performance between packed-bed and microchannel catalyst are compared for SOFC system. The mesh-typed microchannel catalyst also investigated for diesel ATR operation for 1kW-class SOFC system. 1kW-class diesel microchannel ATR was continuously operated about 30 hours and its reforming efficiency was achieved nearly 55%.

Grid-tied Power Conditioning System for Fuel Cell Composed of Three-phase Current-fed DC-DC Converter and PWM Inverter

  • Jeong, Jong-Kyou;Lee, Ji-Heon;Han, Byung-Moon;Cha, Han-Ju
    • Journal of Electrical Engineering and Technology
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    • v.6 no.2
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    • pp.255-262
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    • 2011
  • This paper proposes a grid-tied power conditioning system for fuel cell, which consists of three-phase current-fed DC-DC converter and three-phase PWM inverter. The three-phase current-fed DC-DC converter boosts fuel cell voltage of 26-48 V up to 400 V with zero-voltage switching (ZVS) scheme, while the three-phase PWM(Pulse Width Modulation) inverter controls the active and reactive power supplied to the grid. The operation of the proposed power conditioning system with fuel cell model is verified through simulations with PSCAD/EMTDC software. The feasibility of hardware implementation is verified through experimental works with a laboratory prototype with 1.2 kW proton exchange membrane (PEM) fuel cell stack. The proposed power conditioning system can be commercialized to interconnect the fuel cell with the power grid.

Study on Development of the Isolation Resistance Measurement System for Hydrogen Fuel Cell Vehicle (수소연료전지자동차용 절연저항 측정시스템 개발에 관한 연구)

  • Lee, Ki-Yeon;Kim, Dong-Ook;Moon, Hyun-Wook;Kim, Hyang-Kon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.5
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    • pp.1068-1072
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    • 2011
  • Hydrogen Fuel Cell Vehicle(HFCV) is system that uses electrical energy of fuel cell stack to main power source, which is different system with other vehicles that use high-voltage, large-current. Isolation performance of this system which is connected with electrical fire and electrical shock is important point. Isolation resistance of electric installation is divided according to working voltage, it follows criterion more than $100{\Omega}$/VDC (or $500{\Omega}$/VAC) about system operation voltage in a hydrogen fuel cell vehicle. Although measurement of isolation resistance in a hydrogen fuel cell vehicle is two methods, it uses mainly measurement by megger. However, the present isolation resistance measurement system that is optimized to use in electrical facilities is unsuitable for isolation performance estimation of a hydrogen fuel cell vehicle because of limit of maximum short current and difference of measurement resolution. Therefore, this research developed the isolation resistance measurement system so that may be suitable in isolation performance estimation of a hydrogen fuel cell vehicle, verified isolation performance about known resistance by performance verification of laboratory level about developed system, and executed performance verification through comparing results of developed system by performance verification of vehicle level with ones of existing megger. Developed system is judged to aid estimation and upgrade of isolation performance in a hydrogen fuel cell vehicle hereafter.

Life cycle impact assessment of the environmental infrastructures in operation phase: Case of an industrial waste incineration plant

  • Kim, Hyeong-Woo;Kim, Kyeong-Ho;Park, Hung-Suck
    • Environmental Engineering Research
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    • v.22 no.3
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    • pp.266-276
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    • 2017
  • A life cycle impact assessment was applied in an industrial waste incineration plant to evaluate the direct and indirect environmental impacts based on toxicity and non-toxicity categories. The detailed life cycle inventory of material and energy inputs and emission outputs was compiled based on the realistic data collected from a local industrial waste incineration plant, and the Korean life cycle inventory and ecoinvent database. The functional unit was the treatment of 1 tonne of industrial waste by incineration and the system boundary included the incineration plant and landfilling of ash. The result on the variation of the impact by the unit processes showed that the direct impact was decreased by 79.3, 71.6, and 90.1% for the processes in a semi dry reactor, bag filter, and wet scrubber, respectively. Considering the final impact produced from stack, the toxicity categories comprised 91.7% of the total impact. Among the toxicity impact categories, the impact in the eco-toxicity category was most significant. A separate estimation of the impact due to direct and indirect emissions showed that the direct impact was 97.7% of the total impact. The steam recovered from the waste heat of the incineration plant resulted in a negative environmental burden.

Study on the Suppression of Sulfur Trioxide in High Sulfur Boiler (고유황 보일러에서의 Sulfur Trioxide의 억제에 대한 연구)

  • Choi, Sung-Bu
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.455-463
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    • 2011
  • The average sulfur content of crude oil is 2.2%. Coal is about 0.3 to 4.0 percent of the sulfur gases or particles being discharged into the atmosphere through the chimney as 1 to 2% $SO_3$(Sulfur trioxide) and about 95% of the $SO_2$ is reported. $SO_3$ gas, which has many different causes of, as the combustion of sulfur containing fuel during the air due to the excess $SO_2$ gas is oxidized to $SO_3$ gas. Sulfur trioxide emitted from high sulfur heavy oil fired boiler caused white plume in stack and high temperature and cold end corrosion of facilities. So, in order to control sulfur trioxide concentration of Fuel gas in boiler, various of additives are used in other foreign. They are injected to Fuel Oil and consumed in boiler and reduce ash and the conversion rate of sulfur trioxide. In domestic, MgO compounds are used as additives but the total volume of them are made from other foreign company. In this study, MgO compounds were developed with liquid MgO compounds and field application was accomplished. The effect of newly developed chemicals and process were nearly equal to foreign products. In Consequent, the chemicals and process produced by newly developed technology can be substituted for foreign products and reduce the cost of plant operation.

Design of lava Hardware Accelerator for Mobile Application (모바일 응용을 위한 자바 하드웨어 가속기의 설계)

  • 최병윤;박영수
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.8 no.5
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    • pp.1058-1067
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    • 2004
  • Java virtual machine provides code compactness, simple execution engines, and platform-independence which are important features for small devices such as mobile or embedded device, but it has a big problem, such as low throughput due to stack-oriented operation. In this paper hardware lava accelerator targeted for mobile or embedded application is designed to eliminate the slow speed problem of lava virtual machine. The designed lava accelerator can execute 81 instructions of Java virtual machine(JVM)'s opcodes and be used as Java coprocessor of conventional 32-bit RISC processor with efficient coprocessor interface and instruction buffer. It consists of about 14,300 gates and its maximum operating frequency is about 50 Mhz under 0.35um CMOS technology.

The Real Role of 4,4'-Bis[N-[4-{N,N-bis(3-methylphenyl)amino}phenyl]-N-phenylamino] biphenyl (DNTPD) Hole Injection Layer in OLED: Hole Retardation and Carrier Balancing

  • Oh, Hyoung-Yun;Yoo, Insun;Lee, Young Mi;Kim, Jeong Won;Yi, Yeonjin;Lee, Seonghoon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.929-932
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    • 2014
  • We explored interfacial electronic structures in indium tin oxide (ITO)/DNTPD/N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,1'-biphenyl-4,4'-diamine (NPB) layer stack in an OLED to clarify the real role of an aromatic amine-based hole injection layer, DNTPD. A hole injection barrier at the ITO/DNTPD interface is lowered by 0.20 eV but a new hole barrier of 0.36 eV at the DNTPD/NPB is created. The new barrier at the DNTPD/NPB interface and its higher bulk resistance serve as hole retardation, and thus those cause the operation voltage for the ITO/DNTPD/NPB to increase. However, it improves current efficiency through balancing holes and electrons in the emitting layer.

Thermal and Flow Analysis in a Proton Exchange Membrane Fuel Cell

  • Jung, Hye-Mi;Koo, Ja-Ye
    • Journal of Mechanical Science and Technology
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    • v.17 no.9
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    • pp.1358-1370
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    • 2003
  • The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

Degradation of SOFC Cell/Stack Performance in Relation to Materials Deterioration

  • Yokokawa, Harumi;Horita, Teruhisa;Yamaji, Katsuhiko;Kishimoto, Haruo;Brito, M.E.
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.11-18
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    • 2012
  • The characteristic features of solid oxide fuel cells are reviewed from the viewpoint of the thermodynamic variables to be developed inside cells/stacks particularly in terms of gradients of chemical potential, electrical potential and temperature and corresponding flows of air, fuel, electricity and heat. Examples of abrupt destruction of SOFC systems were collected from failures in controlling their steady flows, while continuous degradation was caused by materials behaviors under gradients of chemical potentials during a long operation. The local equilibrium approximation has been adopted in NEDO project on the durability/reliability of SOFC stacks/systems; this makes it possible to examine the thermodynamic stability/reactivity as well as mass transfer under the thermodynamic variable gradients. Major results of the NEDO project are described with a focus on degradation/deterioration of electrolyte and electrode materials.

Concept research of fuel cell system for the UUV (무인잠수정용 연료전지 시스템 개념 연구)

  • Kim, Hyeong-Dong
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.751-760
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    • 2014
  • The unmanned underwater vehicle(UUV) requires the highly dense energy source because of its limited space. Especially, for the UUV designed for long-term operation, it should be reviewed first whether it is possible to install the energy source against required total power. Therefore, this study identifies whether it is possible to install the energy source for the energy requirement of the UUV. And fuel and oxidizer requirement for the fuel cell system are calculated to determine its location and layout inside of the vehicle. Finally, we design the closed type 1kW polymer-electrolytic fuel cell system and check the applicability to underwater operations with UUV.