• Title/Summary/Keyword: stable inversion

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Formation of Thin $CoSi_2$by Layer Inversion of Co/Nb bi-layer (Co/Nb 이중층 구조의 막역전을 이용한 박막 $CoSi_2$의 형성)

  • Lee, Jong-Mu;Gwon, Yeong-Jae;Lee, Byeong-Uk;Kim, Yeong-Uk;Lee, Su-Cheon
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.779-785
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    • 1996
  • Thin $700^{\circ}C$films were formed through layer inversion of Co/Nb bilayer during rapid thermal annealing(RTA). The Nb interlayer seems to effectively prevent over-consumption of Si and to control the silicidation reaction by forming Co-Nb intermetallic compounds and removing the native oxide formed on Si substrate which interferes the uniform Co-Si interaction. The final layer structure of the Co/Nb bilayer after $700^{\circ}C$ RTA was found to be ${Nb}_{2}{O}_{3}$/${Co}_{2}$Si.CoSi/${NbCo}_{x}$/Nb(O, C)/${CoSi}_{2}$/ Si. The layer inversion and the formation of a stable CoSi, phase occurred above $700^{\circ}C$, and the Nb silicides were not found at any annealing temperature. These may be due to the formation of very stable Co-Nb intermetallic compounds and Nb oxides which limit the moving of Co and Si.

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Prediction of Atomic Configuration in Binary Nanoparticles by Genetic Algorithm (유전알고리즘을 이용한 이원계 나노입자의 원자배열 예측)

  • Oh, Jung-Soo;Ryou, Won-Ryong;Lee, Seung-Cheol;Choi, Jung-Hae
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.493-498
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    • 2011
  • Optimal atomic configurations in a nanoparticle were predicted by genetic algorithm. A truncated octahedron with a fixed composition of 1 : 1 was investigated as a model system. A Python code for genetic algorithm linked with a molecular dynamics method was developed. Various operators were implemented to accelerate the optimization of atomic configuration for a given composition and a given morphology of a nanoparticle. The combination of random mix as a crossover operator and total_inversion as a mutation operator showed the most stable structure within the shortest calculation time. Pt-Ag core-shell structure was predicted as the most stable structure for a nanoparticle of approximately 4 nm in diameter. The calculation results in this study led to successful prediction of the atomic configuration of nanoparticle, the size of which is comparable to that of practical nanoparticls for the application to the nanocatalyst.

Preparation and Characterization of the Asymmetric Microporous Poly(vinylidene fluoride) (PVDF) Blend Membranes with Hydrophilic Surfaces

  • Hwang, Jeong-Eun;JeGal, Jong-Geon
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.1-11
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    • 2007
  • To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.

A study on the construction of nic circuit and ists application to oscilation circuit (Nic 회로의 구성 및 발진회로에의 응용에 관한 연구)

  • 김명기
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.11 no.6
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    • pp.16-24
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    • 1974
  • In this paper the method of constructing short and open stable voltage inversion negative immittance converter (VNIC) circuits is proposed according to simplified equivalent models witch consist of a parameter control circuit, and a voltage or a current control circuit. VNIC characteristics can be obtained as gate voltage of common gate connection is controlled by the output of the parameter control circuit corresponding to its input. Constructed circuits are analysed, and the experimental results are compared and cheeked with the calculated results. Errors are found less than 11%. Oscillation behavior of constructed VNIC oscillator is compared with that of negative resistance oscillator.

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A Study on the Design of the Voltage Down Converter for Low Power, High Speed DRAM (DRAM의 저전력, 고속화에 따른 VDC 설계에 관한 연구)

  • 주종두;곽승욱
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.707-710
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    • 1998
  • This paper presents a new voltage down converter(VDC) for low power, high speed DRAM. This VDC Consists of RVG(Reference Voltage Generator) and Driver Circuit. And it is independent of temperature variation, and Supply Voltage. Using weak inversion region, this RVG dissipates low power. Internal Voltage Source of this VDC is stable in spite of high speed operation of memory array. This circuit is designed with a $0.65\mu\textrm{m}$ nwell CMOS technology. In HSPICE simulation results, Temperature dependency of this RVG is $20\muV/^{\circ}C,$ supply voltage dependency is $\pm0.17%,$ $VCC=3.3V\pm0.3V,$ and current dissipation is $5.22\muA.$ Internal voltage source bouncing of this VDC is smaller than conventional VDC.

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Nonlinear Adaptive Control Law for ALFLEX Using Dynamic Inversion and Disturbance Accommodation Control Observer

  • Higashi, Daisaku;Shimada, Yuzo;Uchiyama, Kenji
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.1871-1876
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    • 2005
  • In this paper, We present a new nonlinear adaptive control law using a disturbance accommodating control (DAC) observer for a Japanese automatic landing flight experiment vehicle called ALFLEX. A future spaceplane must have ability to deal with greater fluctuations in the stability and control derivatives of flight dynamics, because its flight region is much wider than that of conventional aircraft. In our previous studies, digital adaptive flight control systems have been developed based on a linear-parameter-varying (LPV) model depending on dynamic pressure, and obtained good simulation results. However, under previous control laws, it is difficult to accommodate uncertainties represented by disturbance and nonlinearity, and to design a stable flight control system. Therefore, in this study, we attempted to design a nonlinear adaptive control law using the DAC Observer and inverse dynamic methods. A good tracking property of the obtained system was confirmed in numerical simulation.

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Periodically Poled $KNbO_3$ Crystals for Quasi-Phase-Matching

  • Kim, Joong-Hyun;Lee, Sooseok;Yoon, Choon-Sup
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.18-18
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    • 2002
  • Although it was suggested in 1962 that an efficient wavelength conversion could be achieved using ferroelectric crystals of periodic 180° domains, it was not until 1990's that quasi-phase-matching (QPM) became realized, as technology for periodic poling of LiNbO₃ crystals was readily available. Since ferroelectric domain inversion brings about change of the sign of second-order nonlinear susceptibility, periodically poled ferroelectric structures provide an ideal way of achieving QPM for second-harmonic generation and optical parametric oscillation. Periodically poled ferroelectric domains can also be utilized for optical devices, such as Brags electrooptic modulators. fabrication of stable periodic domain structures depends on a number of poling parameters of a ferroelectric crystal, such as coercive field, internal field and electrical conductivity. We present poling kinetics of KNbO₃ crystals, which involve domain nucleation and growth, backswitching, relaxation of internal field. Optimum poling conditions were established by designing a proper wave shape of external field. We demonstrate an efficient second-harmonic generation using QPM in a periodically poled KNbO₃ crystal.

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Atomic structures and Energies of Planar defects in w-GaN (GaN 평면결함의 구조와 형성에너지에 관한 연구)

  • Moon, Won-Ha;Choi, Chang-Hwan
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.567-568
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    • 2006
  • We investigate the structures and the formation energy of inversion domain boundaries (IDBs) using the Tersoff empirical potential. Four kinds of IDBs ( A and B types for IDB* and Holt ) are considered. The IDBs with A type are energetically favorable compared to B type with the structural instability. The IDB* is also more stable than the Holt type in spite of fourfold and eightfold rings of bonds. We calculate the atomic configurations of the Holt IDBs induced by the interactions of the IDB* with the stacking faults $I_1$ and $I_2$. The stacking fault $I_2$ interacted with $I_1$ on the IDB induces the structural transformation from IDB* to Holt type.

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Characterization of Emulsion Properties for Modified Amino Polysiloxanes (아미노 변성 폴리실록산의 유화 특성)

  • 하윤식;서무룡;이정경;박경일;장윤호
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.61-67
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    • 1999
  • Silicone oil has organic and inorganic properties, and its skeleton is polysiloxane bonding that silicon is bonded hydrogen or organic group. Silicone compounds are very smooth and lubricant properties by low surface tension, low temperature dependence, and nonadhesive properties. Because of these properties, silicone compounds are used as many parts of chemicals, softener, smooth and libricant agents, water-repellent agent, and defoaming agent, etc. Emulsion was prepared with the inversion emulsification method which adopted the agent-in-oil method dissolving the polyoxyethylene(7) tridecyl ether(HLB 12.2) into methoxy terminated poly(dimethyl-co-methyl amino) siloxane and hydroxy terminated poly(dimethyl-co-methyl amino) siloxane in water. At this time, processed emulsion was almost microemulsion. When ratio of emulsifier increases, emulsion is stable bacuause microemulsion is solubilized by emulsion drop size and zeta-potential are decreased. But, when amount of electrolyte is increase, emulsion became unstable because emulsion drop size is increased.

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Monetary Policy Independence during Reversal Phases of Domestic-Foreign Interest Rate Differentials

  • Kyunghun Kim
    • East Asian Economic Review
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    • v.28 no.2
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    • pp.221-244
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    • 2024
  • This study examines how the independence of monetary policy changes in situations where the interest rate differential between domestic and foreign rates inverts, utilizing the trilemma indices. For analysis, this paper uses the trilemma indices developed by Kim et al. (2017) to analyze the relationship between the monetary policy independence index and the other two trilemma indices, namely the capital account openness index and the exchange rate stability index, across 45 countries from 2002 to 2018. The analysis reveals that the trilemma's validity is contingent. In particular, no statistically significant negative correlation was found between the monetary policy independence index and exchange rate stability index during periods of interest rate differential inversion. A positive correlation emerges between exchange rate stability and the independence of monetary policy, particularly when the inverted interest rate differential exceeds a certain threshold. This situation, where the exchange rate remains stable despite low domestic interest rates, implies that the central bank is effectively managing monetary policy to appropriately respond to economic conditions, which is reflected in the monetary policy independence index.