• Title/Summary/Keyword: speific surface area

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Adsorption Isotherms Models and Moisture Adsorption Characteristics of Tobacco (담배의 수분 흡착 특성과 흡착 등온식의 모델에 관한 연구)

  • O, In-Hyeok;Kim, Gi-Hwan;Jeong, Gyeong-Rak
    • Journal of the Korean Society of Tobacco Science
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    • v.18 no.2
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    • pp.150-159
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    • 1996
  • In this study, to obtain the basic data for the optimum moisture control system, moisture adsorption characteristics, adsorption isotherms models for water and surface physical characteristics of burley and flue-cured tobacco were investigated. By the hypothesis' the phenomenon of moisture adsorption of tobacco is the same as the first order reaction, the wetting constant (k) and equilibrium moisture content were obtained. And activation energy, frequency factors were also calculated by applying its data to Arrhenius equation. The Kamei's empirical formula of moisture adsorption isotherms showed the best agreement with the experimental data and its correlation coefficient (r) was 0.997. It can be seen that specific surface area of burley is 157 m2/g, that of flue-cured is 152 m2/g, -△H1 of adsorbed monolayer is 45,972 J/mol, 45,486 J/mol, respectively, and the condensation heat (40,595 J/mol) being caught in adsorbed multilayer is less than that of monolayer.

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Performance and Safety of EDLC of PVdF-PVP Mixed Binder (PVdF-PVP 복합결합제를 이용한 EDLC의 성능과 안정성)

  • 김경민;오호성;정세일;이용욱;강안수
    • Proceedings of the Safety Management and Science Conference
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    • 2001.05a
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    • pp.319-324
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    • 2001
  • High surface area and high pore volume activated carbon was prepared by KOH activation of rice hull. The electrodes were fabricated by compounding the commercial and rice hull activated carbons with PVdF and PVdF-PVP mixed binders without addition of conductivity improver. The electrodes fabricated with rice hull activated carbon and PVdF-PVP mixed binders showed the best performance because the PVP played as a pore-forming agent. The electrode exhibited excellent electrochemical characteristics having 7.9 W.h/kg of energy density, 33.5 F/g of speific capacitance, 0.7 $\Omega$ of ESR and good efficiency of self-discharge compared with that fabricated with commercial activated carbons.

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