• Title/Summary/Keyword: spectroscopic techniques

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The use of spectroscopic Ellipsometey for the observation of diamond thin film growth by microwave plasma chemical vapor deposition (마이크로웨이브 플리즈마 화학기상증착에 의한 다이아몬드 박막의 성장 관찰을 위한 분광 Ellipsometry의 이용)

  • 홍병유
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.240-248
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    • 1998
  • The plasma chemical vapor deposition is one of the most utilized techniques for the diamond growth. As the applications of diamond thin films prepared by plasma chemical vapor deposition(CVD) techniques become more demanding, improved fine-tuning and control of the process are required. The important parameters in diamond film deposition include the substrate temperature, $CH_4/H_2$ gas flow ratio, total, gas pressure, and gas excitation power. With the spectroscopic ellipsometry, the substrate temperature as well as the various parameters of the film can be determined without the physical contact and the destructiveness under the extreme environment associated with the diamond film deposition. It is introduced how the real-time spectroscopic ellipsometry is used and the data are analyzed with the view of getting the growth condition and the accompanied features for a good quality of diamond films. And it is determined the important parameters during the diamond film growth, which include the final sample will be measured with Raman spectroscopy to confirm the diamond component included in the film.

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Ultrafast Time-Resolved Laser Spectroscopic Studies of trans-Bis(ferrocene-carboxylato)(tetraphenyl-porphyrinato)tin(IV): Intramolecular Electron-Transfer Dynamics

  • Jang, Joon-Hee;Kim, Hee-Jung;Kim, Hee-Joon;Kim, Chul-Hoon;Joo, Tai-Ha;Cho, Dae-Won;Yoon, Min-Joong
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1967-1972
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    • 2007
  • Photophysical properties of a newly-synthesized porphyrin derivative, trans-bis(ferrocene carboxylato)- (5,10,15,20-tetraphenylporphyrinato)tin(IV) [Sn(TPP)(FcCOO)2] were investigated by means of steady-state and fs-time resolved laser spectroscopic techniques, and compared with those of a standard molecule, trans-dichloro( 5,10,15,20-tetraphenyl-porphrinato)tin(IV) [Sn(TPP)Cl2]. The fluorescence spectrum of Sn(TPP)- (FcCOO)2 was observed to exhibit dual emission bands originating from the S2-state and the S1-state, which was greatly quenched as compared to those of Sn(TPP)Cl2. The fs-time resolved fluorescence and transient absorption spectroscopic measurements revealed that the fluorescence quenching is due to formation of the long-lived charge transfer state by intramolecular electron transfer from ferrocene to the S2-excited SnTPP in addition to the enhanced non-radiative deactivation processes.

EXPANSION VELOCITY AND SPECTROSCOPIC CLASSIFICATION OF NOVA DELPHINI 2013

  • AZALIAH, RHISA;MALASAN, HAKIM L.;HAANS, GABRIELA K.;AKHYAR, SAEFUL
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.251-254
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    • 2015
  • Low resolution spectra of Nova Delphini 2013 (V339 Del) in the optical range have been obtained at Bosscha Observatory, Indonesia during its maximum light (V = 4.3). Spectra were observed from August 16 to 27, 2013. The GAO-ITB RTS 20.3 cm telescope, and SBIG DSS-7 spectrograph and SBIG ST-7 XE as the detector have been employed throughout the observations. The spectra show P-Cygni profiles in Balmer, NaI'D' and Fe II lines, from which we determined shell expansion velocities of $1421.66{\pm}39.18km/s$, $1227.54{\pm}21.57km/s$ and 1402.86 km/s, respectively. Our spectroscopic observations followed the spectral evolution of V339 Del from the pre-maximum phase to early Orion phase. The characteristics of the nova Delphini 2013 resembles those of Fe II-type novae.

Interaction of flavins and some alcohols on the molecular level

  • Yu, Byung-Sul;Chung, Hyun-Ho;Lee, Sang-Jong;Kim, Yang-Bae;Kim, Chong-Kook
    • Archives of Pharmacal Research
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    • v.4 no.1
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    • pp.43-51
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    • 1981
  • The effect of some alcohols on the riboflavin derivatives in non-polar solvent was studied by various spectroscopic method in order to support the view point that alcohol may directly interect with the isoalloxazine moiety of FAD, the coenzyme of D-amino-acid oxidase. The most possible association complex between alcohol and riboflavin is the 1:1 complex through the 2-C carbonyl function of the isollaxazine ring nd the hydroxyl proton of alcohol. It is appeared that methanol has a larger association constant than any other alcohols, and the association constant decreases with the carbon number increases and being bulkier in the alkyl group of alcohols.

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Convolution and Deconvolution Algorithms for Large-Volume Cosmological Surveys

  • Park, KeunWoo;Rossi, Graziano
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.50.4-51
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    • 2015
  • Current and planned deep multicolor wide-area cosmological surveys will map in detail the spatial distribution of galaxies and quasars over unprecedented volumes, and provide a number of objects with photometric redshifts more than an order of magnitude bigger than that of spectroscopic redshifts. Photometric information is statistically more significant for studying cosmological evolution, dark energy, and the expansion history of the universe at a fraction of the cost of a full spectroscopic survey, but intrinsically carries a bias due to noise in the distance estimates. We provide convolution- and deconvolution-based algorithms capable of removing this bias -- thus able to exploit the full cosmological information -- in order to reconstruct intrinsic distributions and correlations between distance-dependent quantities. We then show some direct applications of our techniques to the VIMOS Public Extragalactic Redshift Survey (VIPERS) and the Sloan Digital Sky Survey (SDSS) datasets. Our methods impact a broader range of studies, when at least one distance-dependent quantity is involved; hence, they will be useful for upcoming large-volume surveys, some of which will only have photometric information.

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AKARI INFRARED CAMERA SURVEY OF THE LARGE MAGELLANIC CLOUD

  • Shimonishi, T.;Kato, D.;Ita, Y.;Onaka, T.;AKARI/IRC LMC team
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.83-85
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    • 2017
  • We conducted an unbiased near- to mid-infrared imaging and spectroscopic survey of the Large Magellanic Cloud (LMC) as a part of the AKARI Mission Program "Large-area Survey of the LMC" (LSLMC, PI: T. Onaka). An area of about 10 square degrees of the LMC was observed by five photometric bands (3.2, 7, 11, 15, and $24{\mu}m$) and a low-resolution slitless prism ($2-5{\mu}m$, R ~20) equipped with AKARI /IRC. We constructed and publicly released photometric and spectroscopic catalogues of point sources in the LMC based on the survey data. The catalogues provide a large number of near-infrared spectral data, coupled with complementary broadband photometric data. Combined use of the present AKARI LSLMC catalogues with other infrared point source catalogues of the LMC possesses scientific potential that can be applied to various astronomical studies.

SPECTROSCOPIC STUDIES IN X-RAY ASTRONOMY (X-선 천문 분야의 분광관측 연구)

  • CHOI CHUL-SUNG
    • Publications of The Korean Astronomical Society
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    • v.15 no.spc1
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    • pp.73-83
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    • 2000
  • X-ray astronomy deals with measurements of the electromagnetic radiation in the energy range of $E\~0.1-100 keV (\lambda\~0.12-120{\AA})$. The wavelength of X-ray is comparable to the size of atoms, so that the photons in the X-ray range are usually produced and absorbed by the atomic processes. Since the launch of the first X-ray astronomy satellite 'Uhuru' in 1970, technological advances in a launch capability and a detection capability make X-ray astronomy one of the most rapidly evolving fields of astronomical research. Particularly, a spectral resolving power $E/{\Delta}E$ has been increased by an order of 2 - 3 (in the energy range of 0.1 - 10 keV) during the past 30years. In this paper, I briefly review a developing process of the resolving power and spectroscopic techniques. Then I describe important emission/absorption lines in X-ray astronomy, as well as diagnostics of gas property with line parameters.

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FABRY-PEROT SPECTROMETER IN ASTRONOMY (FABRY-PEROT 분광기의 특성과 천문학의 적용)

  • PAK SOOJONG
    • Publications of The Korean Astronomical Society
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    • v.15 no.spc1
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    • pp.127-132
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    • 2000
  • The purposes of spectroscopy in astronomy are to measure the radiation flux of the spectroscopic emission or absorption line and to measure the dynamical parameters of the line profile. In order to use an appropriate instrument for the scientific purpose, we need to understand the characteristics of various spectrometers, e.g., a prism spectrometer, a grating spectrometer, and a Fabry-Perot spectrometer (FPS), which are being used in ultra-violet, optical, and infrared bands. The Fabry­Perot spectrometer is not very popular compared to the grating spectrometer, because of its complex and tricky operations. The Fabry-Perot spectrometer, however, can get a two-dimensional image at one exposure, so we can study radiation mechanisms and dynamical properties of extended sources, e.g., clusters, nebula, and galaxies.

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Photometric Variability of Symbiotic Stars at All Time Scales - Magellanic Cloud Systems

  • Angelnoi, Rodlfo
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.38.1-38.1
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    • 2017
  • Symbiotic stars are long-orbital-period interacting binaries characterized by extended emission over the whole electromagnetic range and by complex photometric and spectroscopic variability. In this contribution, I will present some high-cadence, long-term optical light curves of confirmed and candidate symbiotic stars in the Magellanic Clouds. By careful visual inspection and combined time series analysis techniques, we investigate for the first time in a systematic way the photometric properties of these astrophysical objects, trying in particular to distinguish the evolutionary status of the cool component, to provide its first-order pulsation ephemeris and to link all this information with the physical parameters of the binary system as a whole. Finally, I will discuss a new, promising photometric technique, potentially able to discover Symbiotic Stars in the Local Group of Galaxies without the recourse to costly spectroscopic follow-up.

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Investigation on the Interaction of Gabapentin with Bovine Serum Albumin by Spectroscopic Techniques

  • Ashoka, S.;Seetharamappa, J.;Kandagal, P.B.;Shaikh, S.M.T.
    • Journal of Photoscience
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    • v.12 no.3
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    • pp.113-117
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    • 2005
  • Spectroscopic investigations on the interaction of gabapentin (GBP) with bovine serum albumin (BSA) were reported. The association constant of GBP-BSA system was determined at different temperatures (298, 302, 306 and 311 K) based on the fluorescence quenching results. The GBP was found to quench the fluorescence of BSA through static mechanism. Thermodynamic parameters, the standard enthalpy change, $({\Delta}H^o)$ and the standard entropy change $({\Delta}S^o)$ were observed to be $-9.61{\pm}0.008\;kJ\;mol^{-1}$ and $3.58{\pm}0.011\;Jmol^{-1}K{-1}$ respectively. These indicated that the hydrophobic and electrostatic forces played a role in the interaction of GBP with BSA. The negative value of ${\Delta}G^o$ revealed that the binding reaction is spontaneous. The circular dichroism studies indicated the conformational changes in BSA upon interaction with GBP. The effect of some metal ions on the binding constant was also investigated.

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