• 제목/요약/키워드: spectroscopic analysis method

검색결과 207건 처리시간 0.023초

Fast Analysis of Film Thickness in Spectroscopic Reflectometry using Direct Phase Extraction

  • Kim, Kwangrak;Kwon, Soonyang;Pahk, Heui Jae
    • Current Optics and Photonics
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    • 제1권1호
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    • pp.29-33
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    • 2017
  • A method for analysis of thin film thickness in spectroscopic reflectometry is proposed. In spectroscopic reflectometry, there has been a trade-off between accuracy and computation speed using the conventional analysis algorithms. The trade-off originated from the nonlinearity of spectral reflectance with respect to film thickness. In this paper, the spectral phase is extracted from spectral reflectance, and the thickness of the film can be calculated by linear equations. By using the proposed method, film thickness can be measured very fast with high accuracy. The simulation result shows that the film thickness can be acquired with high accuracy. In the simulation, analysis error is lower than 0.01% in the thickness range from 100 nm to 4 um. The experiments also show good accuracy. Maximum error is under $40{\AA}$ in the thickness range $3,000-20,000{\AA}$. The experiments present that the proposed method is very fast. It takes only 2.6 s for volumetric thickness analysis of 640*480 pixels. The study suggests that the method can be a useful tool for the volumetric thickness measurement in display and semiconductor industries.

Analysis of the Scattering Coefficients of Microspheres Using Spectroscopic Optical Coherence Tomography

  • Song, Woosub;Lee, Seung Seok;Lee, Byeong-il;Choi, Eun Seo
    • Current Optics and Photonics
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    • 제5권3호
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    • pp.278-288
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    • 2021
  • We propose a characterization method for the scattering property of microspheres using spectroscopic optical coherence tomography (OCT). To prove the effectiveness of the proposed method, we prepare solutions of different concentrations using microspheres ranging from 28 to 2300 nm in diameter. Time-frequency analysis is performed on the measured interference spectrum of each solution, and the resulting spectroscopic information is converted into histograms for centroid wavelengths. The histograms present a very sensitive response to changes in the concentration and size of microspheres. We classify them into three categories according to their characteristics. When the histogram of each category is replaced with the corresponding calculated value of the scattering coefficient, each category is mapped to a different scattering-coefficient region. It is expected that the proposed method could be used to investigate the optical characteristics of a biological sample from OCT images, which would be helpful for optical diagnostic and therapeutic applications.

Adsorption Kinetics for Polymeric Additives in Papermaking Aqueous Fibrous Media by UV Spectroscopic Analysis

  • Yoon, Sung-Hoon;Chai, Xin-Sheng
    • Bulletin of the Korean Chemical Society
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    • 제27권11호
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    • pp.1819-1824
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    • 2006
  • The general objective of the present study was to investigate the potential application of the UV spectroscopic method for determination of the polymeric additives present in papermaking fibrous stock solutions. The study also intended to establish the surface-chemical retention model associated with the adsorption kinetics of additives on fiber surfaces. Polyamide epichlorohydrin (PAE) wet strength resin and imidazolinium quaternary (IZQ) softening agents were selected to evaluate the analytical method. Concentrations of PAE and IZQ in solution were proportional to the UV absorption at 314 and 400 nm, respectively. The time-dependent behavior of polymeric additives obeyed a mono-molecular layer adsorption as characterized in Langmuir-type expression. The kinetic modeling for polymeric adsorption on fiber surfaces was based on a concept that polymeric adsorption on fiber surfaces has two distinguishable stages including initial dynamic adsorption phase and the final near-equilibrium state. The simulation model predicted not only the real-time additive adsorption behavior for polymeric additives at high accuracy once the kinetic parameters were determined, but showed a good agreement with the experimental data. The spectroscopic method examined on the PAE and IZQ adsorption study could potentially be considered as an effective tool for the wet-end retention control as applied to the paper industry.

Interferometric Snapshot Spectro-ellipsometry: Calibration and Systematic Error Analysis

  • Dembele, Vamara;Choi, Inho;Kheiryzadehkhanghah, Saeid;Choi, Sukhyun;Kim, Junho;Kim, Cheong Song;Kim, Daesuk
    • Current Optics and Photonics
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    • 제4권4호
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    • pp.345-352
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    • 2020
  • We describe a calibration method to improve the accuracy of interferometric snapshot spectroscopic ellipsometry employing a dual-spectrometer sensor scheme. Conventional spectral wavelength calibration of a spectrometer has been performed by using a calibration lamp having multiple peaks at specific wavelength. This paper shows that such a conventional spectrometer calibration method is inappropriate for the proposed interferometric snapshot spectroscopic ellipsometry to obtain highly accurate ellipsometric phase information. And also, systematic error analysis of interferometric snapshot spectroscopic ellipsometry is conducted experimentally.

The Weatherproof Detection System of Sea Fog by Remote Sensing and its Applications

  • Bao, Xianwen;Wang, Xin;Sun, Litan;Zhou, Faxiu
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.1380-1382
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    • 2003
  • Detection of sea fog by remote sensing with spectroscopic analysis method and structural analysis method is introduced in this paper. On this base, designing principles and frame of weatherproof detection system of sea fog by remote sensing are systemically explained. Using GMS5 and NOAA visible and infrared channel data, progresses of sea fog on yellow sea on April 17,18, 2001 is monitored which accord with the observing.

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레이저 유도 분해 분광법과 라만 분광법을 이용한 우주 광물의 정성 및 정량 분석 기법 (Qualitative and Quantitative Analysis of Space Minerals using Laser-Induced Breakdown Spectroscopy and Raman Spectroscopy)

  • 김동영;여재익
    • 한국항공우주학회지
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    • 제46권6호
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    • pp.519-526
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    • 2018
  • 우주 자원을 분석하기 위해서는 지구로 가져와야 한다는 단점이 있었다. 하지만, 레이저 유도 분해 분광법(Laser-induced breakdown spectroscopy, LIBS)고 라만 분광법(Raman spectroscopy)을 활용한다면 우주 광물의 실시간 정성 정량적으로 분석이 가능하다. 레이저 유도 분해 분광법은 높은 에너지의 레이저를 물질 표면에 집중시켜 플라즈마를 생성한후, 방출되는 빛을 분광기를 통해 획득하여 원자 구성을 분석하는 분광법이다. 라만 분광법은 레이저를 물질 표면에 조사시켜 산란되는 빛을 측정하여 분자구조를 분석하는 분광법이다. 이 두 가지 분광법은 각각 미지의 광물의 원자 분자를 분석하는 상호보완적인 분광법으로 우주탑재체로서 효율적인 장점을 가지고 있다. 본 연구에서는 주성분 분석법(Principal Component Analysis, PCA)을 활용하여 광물을 정성적으로 분석했다. 또한, 두 가지 광물을 혼합한 시료를 제작하여 구성 성분 비율에 따른 신호 세기로부터 물질의 구성 비율을 예측하는 정량분석을 시행하였다.

Physiological and Spectroscopic Changes of Rice by Nitrogen Fertilization Conditions

  • Jung-Il Cho;Dongwon Kwon;Hoejeong Jeong;Wan-Gyu Sang;Sungyul Chang;Jae-Kyeong Baek
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2022년도 추계학술대회
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    • pp.106-106
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    • 2022
  • An appropriate amount of nitrogen fertilizer input during rice cultivation is essential for rice growth, quality control, and reduction of greenhouse gases in paddy fields. Therefore, it is necessary to develop a technology that can check whether an appropriate amount of fertilizer is applied in paddy fields. In this study, we tried to derive a method for diagnosing nitrogen fertilization level using spectroscopic diagnosis, physiological analysis, and molecular indicator genes. Nitrogen fertilization treatment was performed in a greenhouse by dividing into five treatment conditions: no fertilization (N0), low fertilization (N0.5), standard fertilization (N1.0), excessive fertilization (N1.5), and double fertilization (N2.0), respectively. Growth characteristics analysis was investigated by nitrogen fertilization conditions and growth stages, and the height of the canopy was analyzed using a laser scanner. Physiological and spectroscopic analyses were performed by analyzing chlorophyll and sugar contents and measuring SPAD and leaf spectrometer on rice leaves. In addition, real-time PCR experiment was performed to check the relative expression levels of several known nitrogen metabolism related genes. These results suggest that spectroscopic techniques can be helpful in diagnosing the level of nitrogen fertilization in rice paddy fields.

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근적외 분광분석법에 의한 분말고추중의 씨앗 및 꼭지혼입량의 신속한 측정 (Rapid Determination of Seed and Stem Content in Red Pepper Powder by Near-Infrared Reflectance Spectroscopic Analysis)

  • 조래광;손미령;안재진
    • 한국식품과학회지
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    • 제23권4호
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    • pp.447-451
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    • 1991
  • 분말고추가루에 씨앗이나 꼭지를 혼입시켜 저장시킨 결과 capsanthin, capsaicin, total-sugars 등의 성분이 감소되었으며 특히 꼭지가 혼입된 시료보다 씨앗이 혼입된 시료에 있어서 품질의 열화정도가 큼을 알 수 있었다. 이와 관련하여 씨앗이나 꼭지의 함량을 근적외 분광분석법으로 측정할 수 있는지의 가능성을 조사한 결과 씨앗의 혼입량은 1.76%의 측정오차로, 꼭지의 혼입량은 0.43%의 측정오차로 각각 30초 이내에 통시 측정할 수 있음을 확인하였다.

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High resolution spectroscopic study of the peculiar globular cluster M22 (NGC 6656)

  • Kim, Hyeong-Jun;Lee, Jae-Woo
    • 천문학회보
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    • 제42권2호
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    • pp.65.1-65.1
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    • 2017
  • We present the high-resolution spectroscopic study of the red-giant branch (RGB) stars in the peculiar globular cluster M22 (NGC 6656). We obtained high-resolution spectra of 55 RGB stars using the CTIO 4-m telescope and the HYDRA multi-object spectrograph. By employing an improved LTE analysis method, we measured accurate elemental abundances. In this talk, we will discuss the differences in the chemical composition between the two stellar populations in the context of the formation of M22.

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수환경 내 용존성 유기물질의 총 유기탄소 및 총 질소 안정동위원소 신규 분석법 소개 (Introduction of a New Method for Total Organic Carbon and Total Nitrogen Stable Isotope Analysis of Dissolved Organic Matter in Aquatic Environments)

  • 박시영;최희주;홍서연;임보라;최서영;김은미;허유정;이수형;김민섭
    • 생태와환경
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    • 제56권4호
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    • pp.339-347
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    • 2023
  • 본 연구는 TOC/TN-IRMS를 이용하여 총 유기탄소 및 총 질소 안정동위원소 분석법을 연구하였으며, 수환경 중저농도 시료에서도 분석이 가능하게 시스템을 구축하였다. 수생태계로 유입되는 다양한 유기탄소 기원을 파악하기 위하여 형광지표와 δ13C-DOC 안정동위원소비를 활용한다면 효율적인 수질 관리를 위한 해석기능을 제공할 것이며, 추후 유역 오염원의 대표값(end member)의 지속적인 조사를 통하여 자료구축이 이루어져야 할 것이다.