• Title/Summary/Keyword: spectra

Search Result 7,309, Processing Time 0.029 seconds

A Study on the Applicatin of Design Response Spectrum to a Specific Soil Profile (특정지반에 적용할 설계응답스펙트럼에 대한 고찰)

  • 박형기
    • Proceedings of the Earthquake Engineering Society of Korea Conference
    • /
    • 2001.04a
    • /
    • pp.91-99
    • /
    • 2001
  • This paper is for a reasonable selection of design response spectra for the seismic design of specific types of soil-structure interaction systems, e.g., underground structure within flexible soil profiles of structures on the shallow soil layers on the stiff bed rock. the existing backup data used for determining the design response spectra of the Code have been investigated and evaluated. For this purpose, various types of free field analyses have been performed using one-dimensional wave propagation theory considering the nonlinear properties of the soil profile. As a result, a reasonable approach of determining input response spectra for specific soil profiles has been proposed to be compatible to the design response spectra of the Code.

  • PDF

1 - 5 Micron Spectra of Titan: The Spectral and Altitudinal Variation of Haze

  • Kim, Sang-Joon
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.39 no.2
    • /
    • pp.96.2-96.2
    • /
    • 2014
  • Using solar occultation data obtained by Cassini/Visual Infrared Mapping Spectrometer (VIMS), we were able to retrieve the 1 - 5 mm optical-depth spectra of the Titanian haze, for which only selected wavelength and altitudinal ranges were previously analyzed. We found that the gross 1 - 5 mm shapes of the retrieved haze spectra are significantly different from the spectra of tholin samples in the literature. We also derived the vertical variation of the spectral structure of the $3.3-3.4{\mu}m$ absorption feature of the Titan haze from the VIMS data recorded between 250 and 700 km altitude. We found a marked change between 480 and 580 km in the relative amplitudes of the 3.33 and $3.38{\mu}m$ features which are characteristic of aromatic (double C=Cchains or rings) or aliphatic (single C-C chains) structural groups, respectively. Dicussions on this spectral and altitudinal variation will be presented.

  • PDF

HIGH RESOLUTION NEAR-INFRARED SPECTRA OF NEARBY QUASAR, PG1426+015

  • Le, Huynh Anh Nguyen;Pak, Soo-Jong;Im, Myung-Shin;Ho, Luis C.
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.37 no.1
    • /
    • pp.51.1-51.1
    • /
    • 2012
  • We observed low-z quasar PG1426+015 (z=0.086), using the near-IR high resolution echelle spectrometer, IRCS, at the SUBARU 8.2 m telescope. Using an Adoptive Optics system, the full width at half maximum of the point spread function was about 0.3 arcsec, which can effectively separate the quasar spectra from the host galaxy spectra. We also maximize the total exposure time up to several hours per target, and develop data reduction methods to increase the signal-to-noise ratios. This poster presents the data reduction processes and sample spectra from the quasar and its host galaxy. These spectral lines will be used to study the physical mechanism of quasars, and the velocity dispersions of the stars in the bugle of the host galaxy.

  • PDF

Development of Identification System of Derivative Spectra of Pharmaceuticals by Fast Hartley Transform (고속 하틀리 변환에 의한 의약품 미분스펙트럼의 확인 시스템의 개발)

  • 이숙연;노일협;박만기;박정일;조정환
    • YAKHAK HOEJI
    • /
    • v.35 no.1
    • /
    • pp.1-6
    • /
    • 1991
  • Fast Hartley transform(FHT) was used for the identification of derivative UV spectra of pharmaceuticals, with the advantages of relatively shorter computing time of FHT and more precise results. The arccosine value of dot product of two vectors of normalized FHT coefficients calculated from two compared derivative spectra was a reasonable parameter for the spectral identification. Using this parameter, the similar patterns of derivative spectra of 13 penicillins can be differenciated from each other. The concentration difference and the minor contamination did not interfere the results of identification procedures. All these procedures of identification were accomplished successfully by the computer program, [SPECMAN PLUS] version 1.30, which was developed for this article.

  • PDF

A Study of Azo-Hydrazone Tautomerism in 3-Phenyl-4-arylazo-5-isozaolones by $^H-NMR$ spectra of $^{15}N-labeled$ Compounds and HMO Method

  • Shawali, Ahmad S.;Salkaabi, harifia S.;Abdallah, Magda A.
    • Archives of Pharmacal Research
    • /
    • v.14 no.3
    • /
    • pp.237-241
    • /
    • 1991
  • The tautomerism in 3-phenyl-4-arylazo-5-isoxazolones 1 was examined by $^1H-NMR$ spectra of $^15N-labeled$ compound and by HMO method. Both spectra data $(^1H-NMR\;and\;IR)$ and bonding energies are in support of the assignment of the hydrazone structure to such compounds. It is further shown that intermolecular and intramolecular hydrogen bondings favor the hydrazone tautomer.

  • PDF

Recovery of spectral absolute acceleration and spectral relative velocity from their pseudo-spectral counterparts

  • Papagiannopoulos, George A.;Hatzigeorgiou, George D.;Beskos, Dimitri E.
    • Earthquakes and Structures
    • /
    • v.4 no.5
    • /
    • pp.489-508
    • /
    • 2013
  • Design spectra for damping ratios higher than 5% have several important applications in the design of earthquake-resistant structures. These highly damped spectra are usually derived from a 5%-damped reference pseudo-acceleration spectrum by using a damping modification factor. In cases of high damping, the absolute acceleration and the relative velocity spectra instead of the pseudo-acceleration and the pseudo-velocity spectra should be used. This paper elaborates on the recovery of spectral absolute acceleration and spectral relative velocity from their pseudo-spectral counterparts. This is accomplished with the aid of correction factors obtained through extensive parametric studies, which come out to be functions of period and damping ratio.

Photoisomerization of Cellulose Derivatives Obtained from Homogeneous System (균질계에서 얻은 셀룰로오스 유도체의 광이성질화 현상 연구)

  • No, Young-Ran;Park, Keun-Ho;Lee, Soo
    • Journal of the Korean Applied Science and Technology
    • /
    • v.17 no.4
    • /
    • pp.273-278
    • /
    • 2000
  • Cellulose tosylate(CT) was prepared by reaction of cellulose with p- toluenesulfonylchloride in DMAc/LiCl homogeneous system. In order to study a reversible photoisomerization of disperse red 1(DR-1) attached on natural polymer, cellulose tosylate containing DR-1(DR-1/CT adduct) was prepared at $110^{\circ}C$ in DMAc, and the changes of UV/Vis spectra of its solutions and thick film were investigated by alternate irradiation technique. Form the UV/Vis spectra of DR-1/CT adduct dissolved in cosolvents, such as DMAc, DMAc/THF, DMAc/benzene, and DMAc/chloroform and irradiated with 360 nm and 450 nm ligths, we found out changes of UV/Vis spectra were reversible in all solvents systems and we found out changes of UV/Vis spectra were reversible at thick film, also.

Nondestructive Classification between Normal and Artificially Aged Corn (Zea mays L.) Seeds Using Near Infrared Spectroscopy

  • Min, Tai-Gi;Kang, Woo-Sik
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.53 no.3
    • /
    • pp.314-319
    • /
    • 2008
  • Near infrared (NIR) spectroscopy was used to classify normal and artificially aged nonviable corn (Zea mays L., cv. 'Suwon19') seeds. The spectra at 1100-2500nm were scanned with normal and artificially aged single seeds and analyzed by principle component analysis (PCA). To discriminate normal seeds from artificially aged seeds, a calibration modeling set was developed with a discriminant partial least square 2 (PLS 2) method. The calibration model derived from PLS 2 resulted in 100% classification accuracy of normal and artificially aged (aged) seeds from the raw, the 1st and 2nd derivative spectra. The prediction accuracy of the unknown normal seeds was 88, 100 and 97% from the raw, the $1^{st}$ and $2^{nd}$ derivative spectra, and that of the unknown aged seeds was 100% from all the raw, the $1^{st}$ and $2^{nd}$ derivative spectra, respectively. The results showed a possibility to separate corn seeds into viable and non-viable using NIR spectroscopy.

Conditions for Parameter Convergence of Model Reference Adaptive Control System using Power Spectrum Analysis (파워 스펙트럼 해석을 이용한 기준 모델 적응제어 시스템의 파라미터 수렴조건)

  • Kim, Sung-Duck
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.38 no.7
    • /
    • pp.557-568
    • /
    • 1989
  • Using Power Spectrum Analysis, conditions of parameter convergence for a Model Reference Adaptive Control (MRAC) system are described. The general Persistent Excitation (PE) condition given in time domain can be transformed to the positiveness of auto-correlation matrix which is represented in frequency domain by the spectra of reference input signal. For an MRAC system designed with relative degree one, the existence and the uniqueness of parameter nominal values due to the variation of input spectra can be analyzed by the PE condition in frequency domain. If the input signal has 2n spectra or more, it can be shown that the nominal values exist independent of adaptive gain, input amplitudes, and magnitudes or numbers of their spectra.

  • PDF

Electronic and Vibrational Spectroscopy of cis-Diisothiocyanato(1,4,8,11-tetraazacyclotetradecane)chromium(Ⅲ) Thiocyanate

  • Choi, Jong-Ha;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
    • /
    • v.24 no.3
    • /
    • pp.384-388
    • /
    • 2003
  • The emission and excitation spectra of $cis-[Cr(cyclam)(NCS)_2]NCS$ (cyclam = 1,4,8,11-tetraazacyclotetradecane) taken at 77 K are reported. The infrared and visible spectra at room temperature are also measured. The vibrational intervals due to the electronic ground state are extracted from the far-infrared and emission spectra. The ten pure electronic origins due to spin-allowed and spin-forbidden transitions are assigned by analyzing the absorption and excitation spectra. Using the observed transitions, a ligand field analysis has been performed to determine the bonding properties of the coordinated ligands in the title chromium(Ⅲ) complex. According to the results, it is found that nitrogen atoms of the cyclam ligand have a strong σ-donor character, while the NCS ligand has medium σ- and π-donor properties toward chromium(Ⅲ) ion.