• 제목/요약/키워드: specific viscosity

검색결과 319건 처리시간 0.025초

Organic Solvent Absorption Characteristics of Split-type Microfiber Fabrics

  • Lee Kwang Ju;Kim Seong Hun;Oh Kyung Wha
    • Fibers and Polymers
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    • 제5권4호
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    • pp.280-288
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    • 2004
  • Split-type nylon/polyester microfiber and polyester microfiber fabrics possess drapeability, softness, bulkiness, and smoothness, so that they can be applied in various industrial fields. In particular, these fabrics are able to absorb various organic solvents, and can be used as clean room materials. To investigate the chemical affinity between solvents and the compositional materials of these fabrics, the contact angle of thermally pressed film fabrics was measured with different solvents. The thermally pressed nylon/polyester fabric films showed a chemical attraction to formamide. The sorption properties of the microfiber fabrics were investigated using a real time testing device, and these tests showed that the sorption behavior was more influenced by the structure of the fibrous assembly than by any chemical attraction. The effect of the fabric density, specific weight, and sample structure on the sorption capacity and rate was examined for various organic solvents. The sorption capacity was influenced by the density and the specific weight of the fibrous assembly, and knitted fabric showed a higher sorption capacity than woven fabric. However, the sorption rate was less affected in lower viscosity solvents. On applying Poiseuille's Law, the lower viscosity solvents showed higher initial sorption rates, and more easily penetrated into the fibrous assembly.

아세틸화가 Glycinin의 구조에 미치는 영향 (Effect of Acetylation on Conformation of Glycinin)

  • 김강성;이준식
    • 한국식품과학회지
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    • 제21권5호
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    • pp.714-720
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    • 1989
  • 콩의 주요 저장 단백질인 glycinin의 라이신 잔기를 적당량의 acetic anhydride를 이용하여 28, 65, 85, 95%로 아세틸화시켰다. 아세틸화에 의한 구조적 변화를 solvent perturbant 방법으로 측정한 결과 자연상태의 단백질에 있어서는 타이로신 잔기의 약 40% 미만이 단백질 표면에 노출되어 있었으나 85% 아세틸화 glycinin에 있어서는 70% 이상이 표면에 노출되어 용매에 대해 접근이 용이하게 되었다. 이와 같은 현상은 second derivative spectroscopy에 의해 서로 동일하게 나타났으며, 따라서 아세틸화에 의해 타이로신과 같은 소수성 아미노산이 단백질 표면으로 이동하여 단백질 구조가 변형되었음을 알 수 있었다. 한편 near UV circular dichriosim의 결과 자연상태의 glycinin과 아세틸화가 일어난 glycinin 모두 유사한 모양의 spectra를 나타내었으나 95% 아세틸화 glycinin의 경우에는 tryptophan의 영향이 두드러졌다. Specific viscosity의 경우 아세틸화가 일어날수록 급격히 증가하였는데 이는 아세틸화에 의해 구형의 glycinin이 변형되어 분자의 부피가 커졌을 뿐 아니라 subunit의 분리에 의해 입자수가 증가했기 때문이다.

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배합중 카본블랙 혼입속도에 천연고무 점도가 미치는 영향 (The Effect of Viscosity of Natural Rubber on Incorporation Rate of Carbon Black in The Mixing)

  • 강용구;한신;이계정;류동완;박찬영
    • 한국산업융합학회 논문집
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    • 제2권1호
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    • pp.97-103
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    • 1999
  • The power curve during rubber mixing presents useful information for the understanding of rubber mixing process, because the power curve is determined the mixing state of rubber at the point. The time to the second peak on the power curve is known as carbon black incorporation time, BIT. This study gets the quantity relationship of BIT and viscosity of natural rubber, so by determining the mixing time of the compound on the ground of viscosity of the raw rubber. The mixing with natural rubber and carbon black is examined for various grade natural rubbers, encompassing a wide range of Mooney viscosity. Alter smoothing the mixing power curve using a polynomial, the carbon black incorporation time, BIT, was determined time to second power peak on the curve, The BIT's versus specific values on Mooney viscometer test curve show a linear relation, Especially, the peak of initial maximum torque on Mooney viscometer curve, PMT, is most relevant property relating to the BIT. PMT is useful index for determined optimum mixing time, To apply this results at the mixing, we effectively control the natural rubber mixing but can also know the grading of natural rubber upon processability.

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정수 슬러지의 탈수성 개선을 위한 고분자 응집제 조합주입 고찰 (Determination of Organic Polyelectrolyte Addition Method to Improve Dewaterbility of Alum Sludge)

  • 유태종;안균환;박상준;현미
    • 상하수도학회지
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    • 제18권5호
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    • pp.608-618
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    • 2004
  • Since polyelectrolytes have been used as conditioners, conventionally only a single polyelectrolyte has been added for sludge conditioning. However, the amount of polyelectrolyte needed for optimal conditioning of sludge is very critical. Overdosing reduces the sludge dewaterbility. In this experimental study, sludge conditioning with single or dual polyelectrolyte was conducted to avoid problems associated with overdosing. Single polyelectrolyte conditioning was conducted by one of cationic, nonionic, and anionic polyelectrolytes. The dual polyelectrolyte conditioning was performed by adding one polyelectrolyte and another one in sequence. The dewaterbility of sludges were measured by SRF(specific resistance to filtration), TTF(time to filter), CST(capillary suction time) respectively. Additionally, parameters such as turbidity, zeta potential, viscosity of conditioned sludges or supematant were measured to evaluate the changed characteristics of sludge by addition of polyelectrolytes. From the experiment results, it was concluded that single polyelectrolyte conditioning had a high probability of overdosing, whereas dual polyelectrolyte conditioning resulted in a better dewaterbility and less chance of overdosing. But, it was also found that dosing sequence in dual conditioning was very important according to the characteristics of sludge. Parameters such as viscosity, turbidity, zeta potential were found to be useful as a means of evaluating sludge dewaterbility.

아연-공기 전지용 전해질의 Gelling Agent 분자량에 따른 자가 방전 억제 효과 (Effect of Gelling Agent Molecular Weight on Self-Discharge Behavior for Zinc-Air Batteries)

  • 박정은;조용남
    • 한국재료학회지
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    • 제29권12호
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    • pp.812-817
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    • 2019
  • A zinc-air battery is one of most promising advanced batteries due to its high specific energy density, low cost, and environmental friendliness. However, zinc anodes in zinc-air batteries lead to several issues including self-discharge, corrosion reaction, and hydrogen evolution reaction (HER). In this paper, viscosity of electrolyte has been controlled to suppress the corrosion reaction, HER, and self-discharge behavior. Various viscosity average molecular weights of poly(acrylic acid) (PAA) are adopted to prepare the electrolyte. The evaporation of electrolytes is proportional to the increase in molecular weight. In addition, enhanced self-discharge behavior is obtained when the gelling agent with high molecular weight is used. In addition, the zinc-air cell assembled with lower viscosity average molecular weight of PAA (Mv ~ 450,000) delivers 510.85 mAh/g and 489.30 mAh/g of discharge capacity without storage and with 6 hr storage, respectively. Also, highest capacity retention (95.78 %) is obtained among studied materials.

A Study on the Optimum Mix Proportion of the Stabilizing Liquid Used for Excavation of the Deep and Massive Slurry Wall

  • Kwon Yeong-Ho
    • KCI Concrete Journal
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    • 제14권4호
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    • pp.151-159
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    • 2002
  • This study investigates experimentally the optimum mix proportion and design factors of the stabilizing liquid used for excavation of the massive and deep slurry wall in LNG in-ground tank before pouring concrete. Considering those site conditions, the stabilizing liquid used for excavation of slurry wall has to be satisfied with some requirements including specific gravity, fluid loss, cake thickness, funnel viscosity and sand content in order to construct the safe and qualified slurry wall. For this purpose, we select materials including bentonite, polymer and dispersion agent. After performing many tests for materials and mix design process, we propose the optimum mix proportion that the upper limit ratio of bentonite is $2.0\%$, polymer is $0.1\%$ considering the funnel viscosity and dispersion agent is $0.05\%$considering the fluid loss of the stabilizing liquid. Also, we select all materials which are consisted of GTC4 as bentonite, KSTP as polymer and Bentocryl 86 as dispersion agent. Based on the results of this study, the optimum mix proportion of the stabilizing liquid is applicable to excavate the deep and massive slurry wall in LNG in-ground tank successfully.

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머시응고에 대한 속도감쇠 기법이 정상상태 머시영역에 미치는 영향 (Effect of the Velocity Suppression Techniques for a Mushy Solidification on Steady-state Mushy Region)

  • 김우승;김덕수
    • 대한기계학회논문집B
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    • 제22권12호
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    • pp.1657-1668
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    • 1998
  • In the analysis of a mushy solidification system with natural convection using a fixed grid method, the enthalpy method has been used to account for the release of latent heat. The variable viscosity, Darcy source, and hybrid methods have been employed for the velocity suppression in a mushy region. The choice of the values of solid viscosity and permeability constant in conjunction with the Darcy source term plays an important role in forming the location and shape of the phase boundaries. In this work the effects of these major parameters related to steady-state behavior in the system of mushy solidification are investigated through a simple test problem. The effective specific heat based on the spatial gradients of the enthalpy and temperature is adopted for the treatment of the release of latent heat. The effects of the Prandtl and Rayleigh numbers on the shape of mushy region are examined using the hybrid method.

벤젠의 점성도에 대한 온도와 압력의 영향 (Effect of Temperature and Pressure on the Viscosity of Benzene)

  • 김정림;경진범;유미현
    • 대한화학회지
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    • 제37권12호
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    • pp.1003-1009
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    • 1993
  • 여러 온도와 압력에서 벤젠의 점성도를 결정하여, 액체 벤젠의 점성도에 미치는 온도와 압력의 영향에 대하여 연구하였다. 여러 온도와 압력으로 유지되고 있는 일정한 밀도의 벤젠 속에서 공 낙하 시간을 측정함으로써 벤젠의 점성도를 산출할 수 있었다. 그 결과로부터 벤젠의 비부피에 미치는 온도와 압력의 영향, 자유부피에 미치는 온도와 압력의 영향에 대해서 알아보았으며, 결론적으로 벤젠의 점성도에 대한 온도와 압력의 영향을 온도와 압력의 변화에 따르는 자유부피의 변화에 의하여 고찰하였다.

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Physical Characteristics and Antioxidative Capacity of Major Seaweeds

  • Han, Kyung-Hee;Lee, Eun-Joo;Sung, Mi-kyung
    • Preventive Nutrition and Food Science
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    • 제4권3호
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    • pp.180-183
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    • 1999
  • Seaweeds is a rich sources of dietary fibers exerting a number of physiological properties. However, the reported dietary fiber contents of seaweeds are not consistent and vary widely. Also. a limited number of studies on the biological effects of specific seaweeds have been reported. In this study, water-holding capacity, viscosity and antixidantive activity of major dietary seaweeds were measured to assess their physiological effects. Results showed that total dietary fiber contents ranged from 28 to 51% of dried weight, and large proportions of dietary fiber were insoluble fibers. Water-holding capacity was highest in sea mustard being 1310% , while laver, sea tangle, and green laver exhibited 943, 854 and 815%, respectively. The viscosity of seaweed samples was 20 to 40 cP in sea mustard and sea tangle, while laver and green laver possessed much lower values. All seaweed samples revealed a weak, albeit significant electron donating ability. Also, lipid peroxidation was reduced by 7 to 18%. However, there was no difference in antioxidative activity among seaweeds and sample concernations used. These results imply that most commonly used seaweeds possibly exert parts of their physiological effects through their water-holding, gel-forming , and/or antioxidative activities.

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쌀 품종별 당화액 첨가에 따른 증편의 품질특성 (Quality Characteristics of Jeung-pyun Added with Rice Mash of Various Cultivars)

  • 정인경;정현숙
    • 한국식생활문화학회지
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    • 제37권6호
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    • pp.510-518
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    • 2022
  • This study compares the quality characteristics of Jeung-pyun prepared by supplementing with rice mash of various cultivars. Results showed high contents of crude protein and crude ash in Saeilmi. The highest and lowest amylose contents were obtained in Goami4 and Baekjinju, respectively. Saeilmi had the highest water absorption index (WAI) of rice flour, whereas the highest water-soluble index (WSI) was obtained in Baekokchal. Maximum viscosity, minimum viscosity, and breakdown were high in Baekjinju, and high cooling viscosity and setback levels were determined in Goami4. The sugar content, total free sugar, and pH of the rice mash were highest in Baekjinju. The highest volume of Jeung-pyun was obtained with Saeilmi supplementation, whereas the specific volume was highest in Baekokchal. Evaluation of L, a, and b color values of Jeung-pyun revealed the maximum L value in Saeilmi, a value in Goami4, and b value in Baekjinju. The physical properties of Jeung-pyun were lower in all supplemented groups compared to the control group for hardness, adhesiveness, and chewiness. The lowest chewiness was obtained in Baekokchal-supplemented Jeung-pyun. We conclude that supplementation with different varieties of rice affects the quality characteristics of Jeung-pyun, which are important factors for manufacturing processed foods.