• Applied Chemistry for Engineering
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• 제29권1호
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• pp.122-126
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• 2018

Mesoporous molecular sieves were prepared by the reaction of $Na_2SiO_3$ and $H_2SiF_6$ using nonionic micelle templates in an aqueous solution. Well-crystalline mesoporous molecular sieves were obtained after several seconds at atmospheric conditions. Powder samples exhibited d-spacing of 3.8-5.1 nm with the sharpness of the d00l peak, showing well-crystalline mesoporous molecular sieves, pore size distributions of 2.5-3.1 nm and large specific surface areas of $290-1,018m^2/g$, depending on types of surfactants. SEM images of samples showed well-divided spherical particles with an uniform size of ${\sim}0.5{\mu}m$ and TEM images demonstrated uniform pores with a worm hole shape.

• Journal of Korean Society for Atmospheric Environment
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• 제23권5호
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• pp.575-584
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• 2007

The adsorption capability of iron phthalocyanine derivatives were investigated by means of X-ray diffractometor (XRD), IR (infrared) spectroscopy, scanning electron microscopy (SEM) and temperature programmed desorption (TPD). According to TPD results, iron phthalocyanine derivatives showed two desorption peaks at low temperature ($100{\sim}150^{\circ}C$) and high temperature ($350{\sim}400^{\circ}C$) indicating that there were two kinds of acidities. Tetracarboxylic iron phthalocyanine (Fe-TCPC) have a stronger desorption peak (chemical adsorption) at the high temperature and a weaker desorption peak (physical adsorption) at the low temperature than iron phthalocyanine (Fe-PC). The specific surface areas of Fe-TCPC and Fe-PC were $26.46\;m^2/g\;and\;11.77\;m^2/g$, respectively. The pore volumes of Fe-TCPC and Fe-PC were $0.14\;cm^3/g\;and\;0.06\;cm^3/g$, respectively. The adsorption capability of triethyl amine calculated by breakthrough curve at 220 ppm of equilibrium concentration was 29.2 mmoL/g for Fe-TCPC and 0.8 mmoL/g for Fe-PC. The removal efficiency of dimethyl sulfide of Fe-TCPC and Fe-PC in batch experiment of 225 ppm of initial concentration were 44.9% and 28.9%, respectively. The removal efficiency of trimethyl amine of Fe-TCPC and Fe-PC in batch experiment of 118 ppm of initial concentration were approximately 100.0% and 33.9%, respectively.

• Korean Journal of Materials Research
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• 제28권1호
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• pp.12-17
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• 2018

$In_2O_3$ doped $WO_3$ powders were prepared by a polymer solution route and their $NO_2$ gas sensing properties were analyzed. The synthesized powders showed nano-sized particles with specific surface areas of $6.01{\sim}21.5m^2/g$ and the particle size and shape changed according to the content of $In_2O_3$. The gas sensors fabricated with the synthesized powders were tested at operating temperatures of $400{\sim}500^{\circ}C$ and 100~500 ppm concentrations of $NO_2$ atmosphere. The particle size and $In_2O_3$ content affected on the initial sensor resistance in an air atmosphere. The highest sensitivity (8.57 at $500^{\circ}C$), which was 1.77 higher than the sensor consisting of the pure $WO_3$ sample, was measured in the 0.5 mol% $In_2O_3$ doping sample. In addition, the response time and recovery time were improved by the addition of $In_2O_3$.

• Journal of Soil and Groundwater Environment
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• 제15권3호
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• pp.34-43
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• 2010

The fate of hydrophobic organic contaminants (HOCs) in ground water is highly affected by the distribution and property of the carbonaceous materials (CMs) in subsurface sediments. CMs in soils consist of organic matters (e.g., cellulose, fulvic acid, humic acid, humin, etc.) and black carbon such as char, soot, etc. The distribution and property of CMs are governed by source materials and geological evolution (e.g., diagenesis, catagenesis, etc.) of them. In this study, the distribution and property of CMs in subsurface sediments near the Imjin river in the Republic of Korea and HOC sorption property to the subsurface sediments were investigated. The organic carbon contents of sand and clay/silt layers were about 0.35% and 1.37%, respectively. The carbon contents of condensed form of CMs were about 0.13% and 0.45%, respectively. The existence of black carbon was observed using scanning electron microscopes with energy dispersive spectroscopy. The specific surface areas (SSA) of CMs in heavy fraction(HFrCM) measured with N2 were $35-46m^2/g$. However, SSAs of those HFrCM mineral fraction was only $1.6-4.3m^2/g$. The results of thermogravimetric analysis show that the mass loss of HFrCM was significant at $50-200^{\circ}C$ and $350-600^{\circ}C$ due to the degradation of soft form and condensed form of CMs, respectively. The trichloroethylene (TCE) sorption capacities of sand and clay/silt layers were similar to each other, and these values were also similar to oxidzed layer of glacially deposited subsurface sediments of the Chanute Air Force Base (AFB) in Rantoul, Illinois. However, these were 7-8 times lower than TCE sorption capacity of reduced layer of the Chanute AFB sediments. For accurate prediction of the fate of hydrophobic organic contaminants in subsurface sediments, continuous studies on the development of characterization methods for CMs are required.

• Applied Microscopy
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• 제22권2호
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• pp.118-126
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• 1992

The pathway and time course of fucose-containing glycoprotein synthesis and intracellular translocation in osteoclasts of the mice maxillary alveolar bone were investigated by electron microscopic radioautography. Male Balb-C mice weighing 17gm were anesthetized with Nembutal and injected via the external jugular vein with 2.5 mCi of $L-[6-^{3}H]-fucose$ (specific activity 16.8 mCi/mmol) in 0.1 ml of sterile saline solution. At 5, 10, 20, 35 minutes and 8 hours after administration of the $^{3}H-fucose$, animals were killed by intracardiac perfusion of 30ml of 2% glutaraldehyde in a modified Tyroid solution, pH 7.4. The maxillae were then removed and further fixed in Karnovsky fixative for an additional 3-4 hours. After rinsing in 0.1M cacodylate buffer for 10 minutes, the maxillae were demineralized for 2 weeks at $4^{\circ}C$ in ethylene diamine tetra acetate containing 2% glutaraldehyde. The first interdental areas were mesiodistally sectioned into slices of 1mm thickness and postfixed in osmium tetroxide. Tissues were then dehydrated and embedded in Poly Bed. To prepare electron microscopic radioautography, the dipping method of Kopriwa (1973) was employed. Thin sections were coated with a crystalline monolayer of ILford $L_4$ photographic emulsion. After exposure for 4 months at $4^{\circ}C$, the sections were developed Kodak Microdol-X and Phenidon (for compact grains), fixed in 30% sodium thiosulfate, stained with uranyl acetate and lead citrate and examined in the electron microscope (JEOL 1200 EX). At 5, 10 and 20 minutes after injection, $^{3}H-fucose$ was concentrated in Golgi cisternae of the osteoblasts. By 35 minutes the labels were observed over small vesicles in the suprannclear area of osteoclasts. At 8 hours, numerous silver grains were located on the ruffled border and cell membrane of osteoclasts. These results indicate that fucose molecules are added in the Golgi apparatus and small vesicles appear to be responsible for translocation of the glycoproteins to the marginal portion of osteoblasts. The glycoproteins are distributed on the osteoclast cell surface and especially over the ruffled border.

• Journal of the Korean Society of Environmental Restoration Technology
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• 제15권2호
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• pp.137-147
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• 2012

GRS is an effective urban ecology restoration technique that can manage a variety of environmental functions such as ecological restoration, rainwater spill control and island heat effect from a low-impact development standpoint that can be utilized in new construction and retrofits. Recently, quantitative evaluation studies, both domestic and abroad, in the areas related to these functions, including near-earth surface climate phenomenon, heavy rainwater regulation, thermal environment of buildings, have been actively underway, and there is a trend to standardize in the form of technological standards. In particular, centered on the advanced European countries, studies of standardizing the specific insulation capability of buildings with green system that comprehensively includes the green roof, from the perspective of replacing the exterior materials of existing buildings, are in progress. The limitation of related studies in the difficulties associated with deriving results that reflect material characteristics of continuously evolving systems due in part to not having sufficiently considered the main components of green system, mechanisms of vegetation, soils. This study attempts to derive, through EnergyPlus, the effects that the vegetation-related indicators such as vegetation height, FCV, etc. have on building energy load, by interpreting vegetation and soil mechanisms through plant canopy model and using an ecological standard indicator LAI that represent the condition of plant growth. Through this, the interpretations that assume green roof system as simple heat insulation will be complemented and a more practical building energy performance evaluation method that reflects numerical methods for heat fluxes phenomena that occur between ecology restoration systems comprised of plants and soil and the ambient space.

• Applied Chemistry for Engineering
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• 제24권6호
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• pp.645-649
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• 2013

In this study, we investigated the $NH_3$ oxidation reaction characteristic over $W/TiO_2$ catalyst in order to control $NH_3$ generated from a thermoelectric power plant or incinerator. As a result, it was found that the optimal content of tungsten in $W/TiO_2$ catalyst is 10 wt% and $NH_3$ removal efficiency decreased due to decreasing specific surface areas of catalyst with increasing tungsten contents. When $NH_3$ was injected more than 420 ppm, $NH_3$ conversion decreased at the middle temperature range. In addition, $NH_3$ conversion decreased due to the competitive adsorption of moisture and with increasing oxygen concentration, the $NH_3$ conversion increased while the $N_2$ selectivity decreased.

• Korean Chemical Engineering Research
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• 제49권4호
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• pp.456-459
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• 2011

Among the various activated carbons available in the market, an optimum mixing method of two kind activated carbons with different adsorbability was investigated in this study. The representative adsorption behaviors of the activated carbon are the adsorption isotherm plots obtained by the BET-Analysis which suggests also basic information of adsorption filter design. So we have tested three cases with certifications, the one was the extreme case of coal cokes based activated carbon with highest BET-model and coconut-shell based activated carbon with the lowest Langmuir-model, the other middle and cross case were applied this method to two kinds of activated carbons with higher and lower specific surface areas which are not available but supplied as research samples by an authority of an Korean Research Institute.

• Geomechanics and Engineering
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• 제21권2호
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• pp.95-102
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• 2020

Population concentration in urban areas has led traffic management a central issue. To mitigate traffic congestions, the government has planned to construct large-cross-section tunnels deep underground. This study focuses on estimating the damage caused to frame structures owing to tunnel excavation. When constructing a tunnel network deep underground, it is necessary to divide the main tunnel and connect the divergence tunnel to the ground surface. Ground settlement is caused by excavation of the adjacent divergence tunnel. Therefore, predicting ground settlement using diverse variables is necessary before performing damage estimation. We used the volume loss and cover-tunnel diameter ratio as the variables in this study. Applying the ground settlement values to the settlement induction device, we measured the extent of damage to frame structures due to displacement at specific points. The vertical and horizontal displacements that occur at these points were measured using preattached LVDT (Linear variable differential transformer), and the lateral strain and angular distortion were calculated using these displacements. The lateral strain and angular distortion are key parameters for structural damage estimation. A damage assessment chart comprises the "Negligible", "Very Slight Damage", "Slight Damage", "Moderate to Severe Damage", and "Severe to Very Severe Damage" categories was developed. This table was applied to steel frame and concrete frame structures for comparison.

• Journal of the Optical Society of Korea
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• 제14권3호
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• pp.204-208
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• 2010

A scanning imaging spectrograph system was used in this study to retrieve readings of the 2-D distribution of $SO_2$ and BrO around the crater of the Sakurajima volcano in Japan. The measurement was carried out during the daytime on November 2, 2005. Measurements were made at the surface of the site, located 5 km from the Sakurajima crater. One hundred horizontal scans were performed. Each column scanned by the system consists of 64 vertical pixels in order to retrieve the spatial distributions of BrO and $SO_2$ in the plume in terms of slant column densities (SCDs). Measured spectra were analyzed to identify and quantify $SO_2$ and BrO in the volcanic plume utilizing the plume's specific absorption features in the ultra violet region. Two-dimensional BrO and $SO_2$ distributions in SCD were retrieved horizontally covering the upwind, crater and downwind areas, and vertically, including the plume in the center of the scanned image. Both horizontal and vertical dispersions of $SO_2$ SCD from the crater were successfully measured to be from $10^{17}$ to $4.5{\times}10^{18}$ molecules $cm^{-2}$. However, BrO was measured below $10^{15}$ molecules $cm^{-2}$, which is considered its background level.