• Title/Summary/Keyword: solubility parameter

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Study of Multi-layer Cleansing Oil Using Solubility Parameter (Solubility parameter를 이용한 다층 클렌징 오일에 관한 연구)

  • Park, Chan-Ik;Kim, Bo-Ae;Yang, Jae-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.240-247
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    • 2009
  • The purpose of this study is to develop a method to evaluate solubility parameter interactions of cosmetic ingredients in formulations. This experimentation relates to the fabrication of new multi-layer cleansing oil which can remove make-up products such as lipstick, foundation, mascara, eye shadow, etc., and also can wash away dirt and sebum from the skin just in one stage process. Solubility parameter and specific gravity of various cosmetic ingredients are measured to explain the cleanliness of interface, detergency of make-up cosmetics on the skin surface. The results suggest that it is possible for cosmetic chemists to use solubility parameter of cosmetic materials for fabrication of new formulation of 3-layer cleansing oil.

Prediction of Pervaporation Performance Using Solubility Parameter Calculation

  • John R. Dorgan;Nam, Sang-Yong
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.36-42
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    • 2003
  • A Prediction of pervaporation performance was studied by solubility parameter calculation approach for the benzene/cyclohexane mixture system using rubbery blend membrane with various solubility parameters. The solubility parameter of the rubbery blend membranes were controlled with different blend ratio of the poly(acrylonitrile-co-butadiene), poly(styrene-co-butadiene) and poly(vinyl chloride). Screening of blend formulations was accomplished by simple swelling tests. When the content of NBR is increased, the swelling of both benzene and cyclohexane are decreased. However, the ratio of benzene swelling to swelling by cyclohexane (the swelling selectivity) increases. The same is true for blends in which the PVC content is increased. Adoption of a solubility parameter calculation provides an a priori methodology for seeking the best blend formulation.

A Study About Radionuclides Migration Behavior in Terms of Solubility at Gyeongju Low- and Intermediate-Level Radioactive Waste (LILW) Repository

  • Park, Sang June;Byon, Jihyang;Lee, Jun-Yeop;Ahn, Seokyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.1
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    • pp.113-121
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    • 2021
  • A safety assessment of radioactive waste repositories is a mandatory requirement process because there are possible radiological hazards owing to radionuclide migration from radioactive waste to the biosphere. For a reliable safety assessment, it is important to establish a parameter database that reflects the site-specific characteristics of the disposal facility and repository site. From this perspective, solubility, a major geochemical parameter, has been chosen as an important parameter for modeling the migration behavior of radionuclides. The solubilities were derived for Am, Ni, Tc, and U, which were major radionuclides in this study, and on-site groundwater data reflecting the operational conditions of the Gyeongju low and intermediate level radioactive waste (LILW) repository were applied to reflect the site-specific characteristics. The radiation dose was derived by applying the solubility and radionuclide inventory data to the RESRAD-OFFSITE code, and sensitivity analysis of the dose according to the solubility variation was performed. As a result, owing to the low amount of radionuclide inventory, the dose variation was insignificant. The derived solubility can be used as the main input data for the safety assessment of the Gyeongju LILW repository in the future.

Prediction of Affinity between Membrane and Esters Using Solubility Parameter (용해도 파라미터에 의한 막과 esters 간의 친화도 예측)

  • Song, Kun-Ho;Lee, Kwang-Rae
    • Membrane Journal
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    • v.24 no.6
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    • pp.484-490
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    • 2014
  • To find out the feasibility of the separating/enriching esters from aqueous solution using FASs (Fluoloalkyl-silanes-coupling agent)-surface modified hydrophobic membrane, the solubility parameter of FASs was obtained and compared with those of esters and water. The value of the solubility parameter of FASs (${\delta}_t=16.9$) was almost same with those of esters (ethyl acetate ${\delta}_t=18.1$, propyl acetate ${\delta}_t=18.0$, ethyl propionate ${\delta}_t=17.9$, butyl acetate ${\delta}_t=17.4$, ethyl butyrate ${\delta}_t=17.0$). However, the calculated value of the solubility parameter of water was ${\delta}_t=47.8$, which was far from the value of the solubility parameter of FASs (${\delta}_t=16.9$). This means that the FASs-modified membrane has a much higher affinity to esters than water. The experimental results of permeation flux of esters used in this study showed that the order of permeation flux predicted by the solubility parameter was almost coincide with experimental results. It might be concluded that the solubility parameter may be applicable for a separating/enriching flavors from aqueous natural-flavor solution, in which esters are main components of natural flavors.

Effect of Solubility Parameter Mismatch in Holographic PDLCs

  • Jung, Ju-Ai;Kim, Eun-Hee;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1216-1219
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    • 2004
  • LC and polymer miscibility in HPDLC has been studied in terms of solubility parameter. It was found that better grating formation and diffraction efficiency were obtained when the difference in solubility parameters between polymer and LC is greater.

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Effect of Physicochemical Properties of Solvents on Microstructure of Conducting Polymer Film for Non-Volatile Polymer Memory

  • Paik, Un-Gyu;Lee, Sang-Kyu;Park, Jea-Gun
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.8 no.1
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    • pp.46-50
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    • 2008
  • The effect of physicochemical properties of solvents on the microstructure of polyvinyl carbazole (PVK) film for non-volatile polymer memory was investigated. For the solubilization of PVK molecules and the preparation of PVK films, four solvents with different physicochemical properties of the Hildebrand solubility parameter and vapor pressure were considered: chloroform, tetrahydrofuran (THF), 1,1,2,2-tetrachloroethane (TCE), and N,N-dimehtylformamide (DMF). The solubility of PVK molecules in the solvents was observed by ultravioletvisible spectroscopy. PVK molecules were observed to be more soluble in chloroform, with a low Hildebrand solubility parameter, than solvents with higher values. The aggregated size and micro-/nano-topographical properties of PVK films were characterized using optical and atomic force microscopes. The PVK film cast from chloroform exhibited enhanced surface roughness compared to that from TCE and DMF. It was also confirmed that the microstructure of PVK film has an effect on the performance of non-volatile polymer memory.

A New Solubility Parameter for Retention Behavior in Liquid Chromatography (액체크로마토그래피에서 머무름거동에 대한 새로운 용해도파라미터)

  • Dae Sub Oh;Sun Haing Lee;Soo Han Kim;Sang Tae Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.458-463
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    • 1988
  • The solubility parameter theory for retention behaviors of phenols in a reversed phase liquid chromatography can be applied to limited ranges of the aqueous solvent system. The many examples of the exception to this theory were found to show no agreement with the retention behavior of phenols. Therefore, a new solute-solvent interaction parameter, ${\delta}_{im}$ is added to the Schoenmakers equation of the solubility parameter theory in LC to approach the equation to the real one. The new solute-solvent interaction pararneter, ${\delta}_{im}$ depends on the kinds of solvent, the solvent composition and the structure of solutes. The parameter, ${\delta}_{im}$ has the linear relationship with the solubility parameter of mobile phase, ${\delta}_{im}$. The prediction of retention behavior by this modified equation turns out to be greater than the previous one.

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Solubility Study of Graphene-oxide with Various Solvents (산화그래핀(Graphene oxide)의 솔벤트(solvent)별 Solubility에 대한 연구)

  • Jung, Su-Yeon;Choi, Sung-Woong
    • Composites Research
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    • v.35 no.1
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    • pp.18-22
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    • 2022
  • Dispersion is one of the most important factors in the manufacture of composite materials. In the manufacture of composite materials, solvents are used to better disperse the reinforcement, nano-filler in the matrix. Since dispersion is affected with solvents, it is necessary to study which solvent is adopted to get good dispersion. In this study, the dispersion behavior and solubility of graphene oxide(GO) were examined under various solvents (DMF, NMP, ethylene glycol, Acetone, DI water) to identify dispersion. As a result of UV-Vis spectroscopy absorbance measurement, it was found that DMF and ethylene glycol had the best dispersibility, whereas DI water showed the lowest dispersibility. In addition, as a result of visually observing the dispersion according to the surface tension and time, it was found that the dispersibility was excellent in the order of DI water, ethylene glycol, NMP, DMF, and acetone, which was consistent with the Hansen solubility parameter value.