• Title/Summary/Keyword: solid fuels

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IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

  • Meyer, M.K.;Gan, J.;Jue, J.F.;Keiser, D.D.;Perez, E.;Robinson, A.;Wachs, D.M.;Woolstenhulme, N.;Hofman, G.L.;Kim, Y.S.
    • Nuclear Engineering and Technology
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    • v.46 no.2
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    • pp.169-182
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    • 2014
  • High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. U-Mo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

Characteristics Test and Model Parameter Determination of Generator/Excitation System of Yeongdong Unit 1 due to Conversion of Renewable Generation Fuel (신재생 발전 연료전환에 따른 영동1호기 발전기/제어계 특성시험 및 모델정수 도출)

  • Mun, Jeong-Min;Lee, Tae-kyu;Shin, Woo-Ju;Kim, Jeong-Uk
    • Journal of IKEEE
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    • v.23 no.2
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    • pp.586-593
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    • 2019
  • In this paper, we introduce the wood pellet electric power generation system, which is an eco - friendly solid fuel processed pure wood, which is one of the largest capacity renewable power fuels in Korea, The Ministry of Commerce, Industry and Energy notified the Ministry of Land, Infrastructure, Transport and Tourism of the Ministry of Land, Transport and Maritime Affairs of the Ministry of Land, Transport and Maritime Affairs. Derived and validated. It is confirmed that the performance of the generator and the voltage control characteristics of excitation system are good even for the change of generator fuel. It can contribute to future reference at the plant that wants to replace fossil fuels with renewable fuels.

Synthesis and Evaluation of Superhydrophobic ODA/PDMS Dip Coating on PET for Liquid-Solid Contact Electrification (액체-고체 접촉대전을 위한 PET 기판 기반 ODA/PDMS 딥 코팅 제조 및 평가)

  • Park, Sunyoung;Kang, Hyungyu;Byun, Doyoung;Cho, Dae-Hyun
    • Tribology and Lubricants
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    • v.37 no.2
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    • pp.71-76
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    • 2021
  • As opposed to using fossil fuels, we need to use eco-friendly resources such as sunlight, raindrops and wind to produce electricity and combat environmental pollution. A triboelectric nanogenerator (TENG) is a device that converts mechanical energy into electricity by inducing repetitive contact and separation of two dissimilar materials. During the contact and separation processes, electron flow occurs owing to a change in electric potential of the contacting surface caused by contact electrification and electrostatic induction mechanisms. A solid-solid contact TENG is widely known, but it is possible to generate electricity via liquid-solid contact. Therefore, by designing a hydrophobic TENG, we can gather electricity from raindrop energy in a feasible manner. To fabricate the superhydrophobic surface of TENGs, we employ a dip coating technique to synthesize an octadecylamine (ODA)- and polydimethylsiloxane (PDMS)-based coating on polyethylene terephthalate (PET). The synthesized coating exhibits superhydrophobicity with a contact angle greater than 150° and generates a current of 2.2 ㎂/L while water droplets fall onto it continuously. Hence, we prepare a box-type TENG, with the ODA/PDMS coating deposited on the inside, and place a 1.5 mL water droplet into it. Resultantly, we confirm that the induced vibration causes continuous impacts between the ODA/PDMS coating and the water, generating approximately 100 pA for each impact.

Development of Reduced Graphene Oxide/Sr0.98Y0.08TiO3-δ Anode for Methane Fuels in Solid Oxide Fuel Cells (메탄연료사용을 위한 고체산화물 연료전지용 Reduced Graphene Oxide/Sr0.98Y0.08TiO3-δ 연료극 개발)

  • Hyung Soon Kim;Jun Ho Kim;Su In Mo;Gwang Seon Park;Jeong Woo Yun
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.296-301
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    • 2023
  • Solid oxide fuel cell has received more attention recently due to the fuel flexibility via internal reforming. Commonly used Ni/YSZ anode, however, can be easily deactivated by carbon coking in hydrocarbon fuels. The carbon deposition problem can minimize by developing alternative perovskite anode. This study is focused on improving conductivity and catalytic activity of the perovskite anode by introducing rGO (reduced graphene oxide). Sr0.92Y0.08TiO3(SYT) anode with perovskite structure was synthesized with 1wt% of rGO. The presence of rGO during anode fabricating process and cell operation is confirmed through XPS and Raman analysis. The maximum power density of rGO/SYT anode improved to 3 times in H2 and 6 times in CH4 comparing to that of SYT anode due to the high electrical conductivity and good catalytic activity for CH4.

Predicting Micro-Thickness of Phase Fronts in Propellants (추진제의 마이크로 스케일 상면 두께 예측)

  • Yoh Jai-Ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.13-21
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    • 2005
  • I consider the structure of steady wave system which is admitted by the continuum equations for materials that undergo phase transformations with exothermic chemical reaction. In particular, the dynamic phase front structures between liquid and gas phases, and solid and liquid phases are computationally investigated. Based on the one-dimensional continuum shock structure analysis, the present approach can estimate the nano-width of waves that are present in combustion. For illustration purpose, n-heptane is used in the evaporation and condensation analysis and HMX is used in the melting and freezing analysis of energetic materials of interest. On-going effort includes extension of this idea to include broad range of liquid and solid fuels, such as rocket propellants.

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Production of Chemical Intermediate Furfural from Renewable Biomass Miscanthus Straw (재생가능한 바이오매스 자원인 억새로부터 화학중간체 푸르프랄의 생산)

  • Jeong, Gwi-Taek
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.492-496
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    • 2014
  • In this work, the possibility of Miscanthus as renewable lignocellulosic biomass was evaluated for production of furfural. Also, to find the reaction conditions of furfural production from Miscanthus straw, the effects of solid-to-liquid ratio, reaction temperature, catalyst amount, and reaction time were investigated. Finally, 5.1 g/L furfural was produced from Miscanthus straw in the condition of solid-to-liquid ratio at 1:10, reaction temperature at $150^{\circ}C$, sulfuric acid at 3%, and reaction time of 60 minutes. This result will provide basic knowledge for converting renewable resources into valuable chemicals substituted for fossil fuels.

An Experimental Study about The Effect of Solid Particle Seeding on Thermal Characteristics of Hydrogen Flame (고체 입자첨가가 수소화염의 열특성에 미치는 영향에 관한 실험적 연구)

  • Kim, Jung-Ju;Baek, Seung-Wook;Kim, Han-Seok;Choi, Joon-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.11
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    • pp.1503-1512
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    • 2002
  • From the view of the environmental protection against the use of fossil fuels, a great of efforts have been exerted to find an alternative energy source. Hydrogen may become an alternative However the product species of the hydrogen flame is only $H_2O$, which emits only non-luminous radiation so the radiation from it is much smaller than that for a hydrocarbon flame. In this study, the authors designed and fabricated a laboratory scale test furnace to study thermal characteristics of hydrogen-air diffusion flame. In addition. the effects of addition of reacting as welt as non-reacting solid particles were experimentally investigated. Among the total heat flux to the wall, about 75 % was occupied by radiation while 25% by convection. When the aluminum oxide (Al$_2$O$_3$) particles were added, the radiative heat flux was reduced due to heat blockage effects. On the other hand, the total as well as the radiative heat flux was increased when the carbon particles were seeded, since the overall temperature increased. The effects of swirl and excess air ratio were also examined.

A Study on the Suppression of Carbon Deposition in Solid Oxide Fuel Cells Through Methane Internal Reforming (메탄 내부개질 반응을 통한 고체산화물 연료전지의 탄소침적 억제에 관한 연구)

  • Kang, Yun-Hyeok;Lim, Sung-Kwang;Yoo, Yung-Sung;Park, Jin-Woo;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.5
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    • pp.473-481
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    • 2007
  • Compared to other types of fuel cells, SOFC has advantages like a wide output range and the direct use of hydrocarbon fuel without the process of external reforming. Particularly because the direct use of fuel without reforming reaction is closely linked to overall system efficiency, it is a very attractive advantage. We tried the operation with methane. However, although methane has a small number of carbons compared to other hydrocarbon fuels, our experiment found the deposition of carbon on the surface of the SOFC electrode. To overcome the problem, we tried the operation through activating internal reforming. The reason that internal reforming was possible was that SOFC runs at high temperature compared to other fuel cells and its electrode is made of Ni, which functions as a catalyst favorable for steam reforming.

Electrochemical Ceramic Membrane Reactors (이온전도성 세라믹 기반 고온 전기화학 멤브레인 반응기 응용기술)

  • Uhm, Sunghyun;Park, Jae Layng;Seo, Minhye
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.337-343
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    • 2013
  • Membrane reactors have been showing a promising future and attracted increasing attention in the scientific community as they possess advantages in terms of enhanced catalytic activity and selectivity, combination of processes (reaction and separation), simplicity in process design, and safety in operation. In particular, solid electrolyte membrane reactor principles are realized in fuel cells, electrolyzers and reactors for hydrogenation of carbon dioxide and other economically viable reactions. In this review, as a young generation of ion conducting materials, high temperature proton conductors are discussed in terms of the current status of material development and their various applications.

Review of the Inlet Air Temperature Effect on the Ramjet Performance Efficiency (램제트 성능에 미치는 흡입 공기 온도에 대한 고찰)

  • Lee, Tae-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.271-274
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    • 2007
  • In the fuel of the solid fuel ramjet there are metal particles in order to improve the Isp like as solid rocket propellants. Because of the short combustion residence time these metallized fuels have low combustion efficiencies. Therefore it is necessary to increase the combustion efficiency and the inlet air temperature does an important role to this. The main factors to affect the inlet air temperature is the free stream temperature and the flight Mach number. Also the flow velocity in the combustor does an important role, therefore entire range of the air flow; from the stagnation to the sonic velocity in the ramjet combustor is considered.

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