• 제목/요약/키워드: solid bed

검색결과 303건 처리시간 0.025초

Effect of process parameters on the recovery of thorium tetrafluoride prepared by hydrofluorination of thorium oxide, and their optimization

  • Kumar, Raj;Gupta, Sonal;Wajhal, Sourabh;Satpati, S.K.;Sahu, M.L.
    • Nuclear Engineering and Technology
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    • 제54권5호
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    • pp.1560-1569
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    • 2022
  • Liquid fueled molten salt reactors (MSRs) have seen renewed interest because of their inherent safety features, higher thermal efficiency and potential for efficient thorium utilisation for power generation. Thorium fluoride is one of the salts used in liquid fueled MSRs employing Th-U cycle. In the present study, ThF4 was prepared by hydro-fluorination of ThO2 using anhydrous HF gas. Process parameters viz. bed depth, hydrofluorination time and hydrofluorination temperature, were optimized for the preparation of ThF4 in a static bed reactor setup. The products were characterized with X-Ray diffraction and experimental conditions for complete conversion to ThF4 were established which also corroborated with the yield values. Hydrofluorination of ThO2 at 450 ℃ for half an hour at a bed depth of 6 mm gave the best result, with a yield of about 99.36% ThF4. No unconverted oxide or any other impurity was observed. Rietveld refinement was performed on the XRD data of this ThF4, and Chi2 value of 3.54 indicated good agreement between observed and calculated profiles.

혐기성 유동층 생물 반응기와 새로운 모델의 AFPBBR에서 유기성폐수 처리시 Biogas 생성과 반응상수에 관한 연구 (A Study on the Kinetics and the Biogas Formation for Organic Wastewater Treatment in Anaerobic Fluidized-Bed Bioreactor and New Model AFPBBR)

  • 김재우;장인용
    • 한국환경보건학회지
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    • 제19권2호
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    • pp.23-33
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    • 1993
  • The anaerobic digestion of organic synthetic wastewater in anaerobic fluidized bed bioreactor (AFBBR) and anaerobic fluidized packed bed bioreactor (AFPBBR) was studied. This study was conducted to evaluate efficiency and reliability of two reactor. Experiment was performed to find the effect of upflow rate with AFBBR and the height of packed bed with AFPBBR. As a result, this program obtained several conclusion. These are given as follows: As applied the upflow rate increased in AFBBR the produced volume of biogas increased, while the gas production and COD removal decreased at above 0.3 m$^3$/h. When a upflow rate is 0.4 m$^3$/h in AFBBR the volatile suspended solid (VSS) became significantly increased. At an organic loading rate from 0.1 to 0.4 of upflow rate in AFBBR, the methane yield was 1.5584 m$^3$CH$_4$/kgCOD removed, and the observed cell yield coefficient was 0.0933 gVSS/gCOD. In case of AFPBBR, the results showed also that 20 cm of height of packed bed was superior to other in the aspect ot biogas production, the content of methane and COD removal. At 20 cm of height, the profile of microorganisms was stable, while at 30 cm the VSS of effluent became higher than AFBBR. Though COD removal of AFPBBR increased with packed bed, COD removal deteriorate with over packing because the loss of pressure became higher in the reactor. At an organic loading rate from 20 to 40 cm of packed bed in-AFPBBR, the methane yield was 2.5649 m$^3$CH$_4$/kgCOD removed, and the observed cell yield coefficient was 0.0506 gVSS/gCOD. Based upon the results obtained, it is suggested that AFBBR and AFPBBR is the most effective conditions at 0.3 m3/h of upflow rate, the 20cm of packed bed, respectively. The rate constant are summarized as follow:

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다양한 종류의 연소로 형식에서 고체 연료 특성이 연소과정에 미치는 영향 (Effects of solid fuel combustion characteristics in various combustor types)

  • 최진환;양원;이상득;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2001년도 제23회 KOSCO SYMPOSIUM 논문집
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    • pp.142-152
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    • 2001
  • Three Lab-scale combustors of different types were made to observe some basic phenomena of fuel combustion in the combustors ; grate type combustor, rotary kiln and FBC. The aims were to introduce how to simulate the combustion behaviors in the real plants by utilizing the reduced apparatuses and characterize the combustors relating to some important parameters such as fuel size, water contents, bed temperature, rotating speed of kiln, flow rate. The mean carbon conversion time and the flame propagation rate were adopted for the quantitative analysis.

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유동상 소각로에서 하수 슬러지 연료 특성 (Fuel Characteristics of Sewage Sludge in a Fluidized Bed Incinerator)

  • 최진환;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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    • pp.81-91
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    • 1999
  • Fuel characteristics of sewage sludge as required for the fluidized bed incinerators have been evaluated. Sewage sludge is basically a solid fuel with high percentage of moisture. Moisture content of the fuel directly affects the heating value of the fuel and the exhaust gas composition. When the sludge of transported into the incinerator, sludge cake is subject to the mixing, break-up and heat-up. Fluidization process would enhance these physical processes. The sludge fuel could then undergo the moisture evaporation and devolatilization process. Subsequent oxidation of volatiles as well as the remaining char would then follow. Sludge samples are characterized with high percentage of volatiles out of total combustibles. Quantitative understanding of above listed subprocesses would certainly help in the utilization of fluidized bed incinerators. A limited set of fuel characterization tests including calorimetric analysis, proximate analysis, elemental analysis and thermogravimetric analysis were conducted for the selected sludge samples. The measurement reasults of sludge samples were reported along with some published data. Limited experience in the actual incinerator plant is also presented.

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입자 순환식 열교환기의 상승관 설계방법 (Riser Design Approach for Particle-Circulation-Type Heat Exchangers)

  • 전용두
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2002년도 학술대회지
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    • pp.311-312
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    • 2002
  • In this paper a systematic design approach to determine the optimum size (height) of circulating fluidized bed heat exchanger for exhaust gas heat recovery is prososed. Unlike the convensional heat exchangers where the length of the heat exchanger section is not very much emphasized, the vertical length of heat exchanger tube in the case of fluidized bed heat exchangers is important because this length determines the time interval during which particles reside and transfer heat in the heat exchanger section. For particles initial conditions are nearly stationary, accelerating particles motion should be considered rather than simply assuming fully developed condition. A way to estimate optimum tube length at different fluid velocity and particle sizes is suggested based on the required conditioning time for heat transfer from the flue gas to solid particles.

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충진층 현열 축열조의 성태해소에 관한 연구 (A Study on the Performance for the Cylindrical Packed Bed Sensible Heat Storage Unit)

  • 권순석;김시범;구본영
    • 한국해양공학회지
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    • 제4권2호
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    • pp.85-93
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    • 1990
  • A numerical study on the cylindrical packed bed sensible heat storage unit was accomplished by finite difference method. Relation between the heat storage rate and the mechanical pumping energy and the characteristics of the heat storage were investigated for various in let velocities and porosities. In this study, the numerical results are as follows: 1) The temperature distributions of solid and fluid rapidly reached the steady state as the heat capacity ratio was increased. 2) The efficiency of the heat storage was increased as the heat capacity ratio was decreased. For constant heat capacity ratio, however, the efficiency of the heat storage was increased at lower porosity. 3) It is very profitable to design the heat storage system such that the porosity is larger for the large flow rate and samller for small flow rate.

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충진층 현열 축열조의 성태해소에 관한 연구 (A Study on the Performance for the Cylindrical Packed Bed Sensible Heat Storage Unit)

  • 권순석;김시범;구본영
    • 한국해양공학회지
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    • 제4권2호
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    • pp.235-235
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    • 1990
  • A numerical study on the cylindrical packed bed sensible heat storage unit was accomplished by finite difference method. Relation between the heat storage rate and the mechanical pumping energy and the characteristics of the heat storage were investigated for various in let velocities and porosities. In this study, the numerical results are as follows: 1) The temperature distributions of solid and fluid rapidly reached the steady state as the heat capacity ratio was increased. 2) The efficiency of the heat storage was increased as the heat capacity ratio was decreased. For constant heat capacity ratio, however, the efficiency of the heat storage was increased at lower porosity. 3) It is very profitable to design the heat storage system such that the porosity is larger for the large flow rate and samller for small flow rate.

RESEARCH PAPERS : REMOVAL EFFICIENCY OF THE POLLUTANTS BY MULTILAYERED METAL TREATED CARBON FILTER

  • Oh, Won-Chun;Lee, Ho-Jin;Bae, Jang-Soon
    • Environmental Engineering Research
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    • 제9권5호
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    • pp.193-200
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    • 2004
  • A study of the treatment of piggery wastes using a multilayered metal-activated carbon system followed by carbon bed filtration was carried out at bench scale. From the physicochemical properties obtained from samples treated with aqueous solutions containing metallic ions such as Ag$^+$, Cu$^{2+}$, Na$^{-}$, K$^+$ and Mn$^{2+}$, main inspections are subjected to isothem shape, pore distribution with micropore, SEM and EDX. Multilayered metal-activated carbons were contacted to waste water to inwestigate the simultaneous catalytic effect for the COD, BOD, T-N and T-P removal. From these removal performance was achieved. The high efficiency of the multilayered metal-activated carbon bed, satisfactory removal performance was achieved. The high efficiency of the multilayered metal-activated carbon bed was derermined by the properties of this material for trapping, catalytic effect and adsorption of organic solid particles.

유동층형(流動層形) 핀관(管) 열교환기(熱交換器)의 열전달특성(熱傳達特性)에 관(關)한 기초적(基礎的) 연구(硏究) (A Basic Study on Fluidized Bed Heat Exchanger with Finned Tube)

  • 이석우;유지오;양한주;서정윤
    • 설비공학논문집
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    • 제3권3호
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    • pp.168-175
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    • 1991
  • Experiments have been conducted to measure the overall heat transfer coefficient for gas-solid fluidized double pipe heat exchanger with finned tube. The average particle diameters of alumina are used in 0.4, 0.5, 0.6 and 0.9mm. And the effects of average particle diameter, static bed height and flow velocity on overall heat transfer coefficient have been investigated. Also the heat transfer effect of fluidized bed was compared with that of single phase forced convection and that of heat exchanger with smooth tube.

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페블 베드 타입 고온 가스 냉각 원자로 내부 유동장 측정 (Measurement of Flow Field in the Pebble Bed Type High Temperature Gas-cooled Reactor)

  • 이사야;이재영
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2088-2093
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    • 2008
  • In this study, flow field measurement of the Pebble Bed Reactor(PBR) for the High Temperature Gas-cooled Reactor(HTGR) was performed. Large number of pebbles in the core of PBR provides complicated flow channel. Due to the complicated geometries, numerical analysis has been intensively made rather than experimental observation. However, the justification of computational simulation by the experimental study is crucial to develop solid analysis of design method. In the present study, a wind tunnel installed with pebbles stacked was constructed and equipped with the Particle Image Velocimetry(PIV). We designed the system scaled up to realize the room temperature condition according to the similarity. The PIV observation gave us stagnation points, low speed region so that the suspected high temperature region can be identified. With the further supplementary experimental works, the present system may produce valuable data to justify the Computational Fluid Dynamics(CFD) simulation method.

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