• Title/Summary/Keyword: solar cell manufacturing

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Industrial Applications of Si-based Ceramics

  • Eichler, Jens
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.561-565
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    • 2012
  • Due to their unique combination of properties, Si-based ceramics, such as silicon carbide (SiC), silicon nitride ($Si_3N_4$) and silicon oxide ($SiO_2$ as fused silica), have a range of industrial applications in fields such as the chemical industry, aluminum manufacturing, oil and gas production and solar cell production. For each materials group, examples of typical applications from various industry sectors are presented while taking into account the property fingerprint.

Effect of the Concentration of Citrate on the Growth of Aqueous Chemical Bath Deposited ZnO and Application of the Film to Cu(In,Ga)Se2 Solar Cells (Citrate 농도에 따른 수용액 화학조 증착 ZnO 성장 및 ZnO 박막의 Cu(In,Ga)Se2 태양전지 응용)

  • Cho, Kyung Soo;Jang, Hyunjun;Oh, Jae-Young;Kim, Jae Woo;Lee, Jun Su;Choi, Yesol;Hong, Ki-Ha;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.30 no.4
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    • pp.204-210
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    • 2020
  • ZnO thin films are of considerable interest because they can be customized by various coating technologies to have high electrical conductivity and high visible light transmittance. Therefore, ZnO thin films can be applied to various optoelectronic device applications such as transparent conducting thin films, solar cells and displays. In this study, ZnO rod and thin films are fabricated using aqueous chemical bath deposition (CBD), which is a low-cost method at low temperatures, and environmentally friendly. To investigate the structural, electrical and optical properties of ZnO for the presence of citrate ion, which can significantly affect crystal form of ZnO, various amounts of the citrate ion are added to the aqueous CBD ZnO reaction bath. As a result, ZnO crystals show a nanorod form without citrate, but a continuous thin film when citrate is above a certain concentration. In addition, as the citrate concentration increases, the electrical conductivity of the ZnO thin films increases, and is almost unchanged above a certain citrate concentration. Cu(In,Ga)Se2 (CIGS) solar cell substrates are used to evaluate whether aqueous CBD ZnO thin films can be applicable to real devices. The performance of aqueous CBD ZnO thin films shows performance similar to that of a sputter-deposited ZnO:Al thin film as top transparent electrodes of CIGS solar cells.

Effect of annealing temperature on Al2O3 layer for the passivation of crystalline silicon solar cell

  • Nam, Yoon Chung;Lee, Kyung Dong;Kim, JaeEun;Bae, Soohyun;Kim, Soo Min;Park, Hyomin;Kang, Yoonmook;Lee, Hae-Seok;Kim, Donghwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.335.2-335.2
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    • 2016
  • The fixed negative charge of the Al2O3 passivation layer gives excellent passivation performance for both n-type and p-type silicon wafers. For the best passivation quality, annealing is known to be a prerequisite step and a lot of studies concerning annealing effect on the passivation characteristics have been performed. Meanwhile, for manufacturing a crystalline silicon solar cell, firing process is applied to the Al2O3 passivation layer. Therefore, study on not only annealing effect but also on firing effect is necessary. In this work, Al2O3 passivation performance (minority carrier lifetime) for p-type silicon wafer was evaluated with Quasi-Steady-State Photoconductance(QSSPC) measurement after annealing at different temperatures. For the samples which showed different aspects, C-V measurement was performed for the cause - whether it is due to the chemical effect or field-effect. The change in Al2O3 passivation property after firing processes was investigated and the mechanism for the change could be estimated.

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Fabrication and characteristics of the flexible DSSC

  • Choe, Eun-Chang;Choe, Won-Chang;Wi, Jin-Uk;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.400.2-400.2
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    • 2016
  • Dye-sensitized solar cells (DSSCs) have been widely investigated as a next generation solar cell because of their simple structure and low manufacturing cost. To realize a commercially competitive technology of DSSCs, it is imperative to employ a technique to prepare nanocrystlline thin film on the flexible organic substrate, aiming at increasing the flexibility and reducing the weight as well as the overall device thickness of DSSCs. The key operation of glass-to-plastic substrates conversion is to prepare mesoporous TiO2 thin film at low temperature with a high surface area for dye adsorption and a high degree of crystallinity for fast transport of electrons. However, the electron transport in the TiO2 film synthesized at low temperature is very poor. So, in this study, TiO2 films synthesized at high temperature were transferred on the selective substrate. We fabricated DSSCs at low temperature using this method. So, we confirmed that the performance of DSSCs using TiO2 films synthesized at high temperature was improved.

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$CuInSe_2$ thin film is manufactured by the Sputtering and Selenization process (스퍼터링 및 셀렌화 열처리에 의한 $CuInSe_2$ 박막제조)

  • Moon, Dong-Gwan;Ahn, Se-Jin;Yun, Jae-Ho;Gwak, Ji-Hye;Lee, Huy-Dek;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.83-84
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    • 2009
  • Thin film solar cells based on CIGS continue to be a leading candidate for thin film photovoltaic devices due to their appropriate bandgap, long-term stability, and low-cost production. To date, the most successful technique for the deposition of a CIGS absorber layer has been based on the co-evaporation However, the evaporation process is difficult to scale-up for large-area manufacturing the sputtering and Selenizaton process has been a promising method for low-cost and large-scale production of high quality CIGS In this study, we have used Cu and CuIn alloy targets for precursor deposition the precursor deposited by sputtering Cu and CuIn targets and $CuInSe_2$ thin film is manufactured by Selenization process

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Ag nanorod manufacturing using nano-imprint lipography process and application of amorphous thin film solar cells (나노 임프린트 공정을 이용한 Ag 나노로드 제조 및 비정질 박막 태양전지 적용)

  • Jang, JiHoon;Han, Kang-Soo;Cho, Jun-Sik;Lee, Heon;Park, Hai Woong;Song, Jinsoo;Lee, Jeong Chul
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.103.2-103.2
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    • 2011
  • 비정질 실리콘 태양전지의 효율을 증가하기 위하여 많이 사용되는 방법 중 하나는 입사되는 빛의 산란을 증가하여 태양전지의 광흡수를 증가시키는 방법이다. 이를 위하여 양극전극으로 사용되는 TCO층의 일정한 패턴 처리를 통하여 광산란을 증가시키는 방법이 사용되고 있다. 본 연구에서는 나노 임프린트 리소그래피방법을 사용하여 Ag 나노로드를 증착한 기판을 제조하고 이를 비정질 실리콘 태양전지에 적용하였다. 실험결과, 그림과 같이 높이와 너비가 300nm 정도로 일정한 패턴의 Ag 나노로드를 제조하였다. 또한, 그 위에 증착된 Si 박막의 경우, 나노로드 전체를 감싸는 돔 형태로 성장하였다. 이와 같은 나노로드 위에 substrate n-i-p 구조의 비정질 박막 태양전지를 증착하고 그 특성변화를 분석하고자 하였다.

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The Analysis of Optical Characteristics of Glasses for PV Module Application (태양전지모듈적용 투명유리의 광특성 분석)

  • Kim, Kyung-Soo;Kang, Gi-Hwan;Yu, Gwon-Jong
    • 한국태양에너지학회:학술대회논문집
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    • 2008.04a
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    • pp.98-103
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    • 2008
  • The glass for crystalline PV module fabrication should have high thermal and mechanical resistance to environmental also have high transparency. In this paper, we analyze the optical characteristics of glasses for photovoltaic module application. The transmittance of several glasses are measured. The effects of texturing on low iron glass, glass thickness, anti-reflective glass, photocatalyst-treated glass and special glass are compared each other. Then this will give some information to select PV glass for manufacturing. The detailed analysis is described in the following paper.

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Future Prospect of Perovskite Solar Cells for Practical Applications (페로브스카이트 태양전지 안정성 개선을 위한 광활성층 연구 현황과 전망)

  • Song, Jae-Kwan;Kim, Do-Heyoung
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.1-20
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    • 2020
  • Development of efficient methods for clean energy production became a critical issue to improve the quality of human lives. Solar cells is considered as one of the alternative solutions to resolve the issue. Although Si-based solar cells are only popularly utilized for practical applications, high manufacturing cost is considered as a serious drawback for further versatile applications. Thus, different types of are being investigated aiming to replace the Si-based solar cells. Recently, perovskite solar cells (PSC) are considered as a potential replacement for Si-based solar cells due to their low production cost, high power conversion efficiency, light weight and possibility of flexible device fabrication. Thus, we have reviewed the challenges of PSC faced with practical application, particularly on stability.

A comparative study on the characteristics of the dye-sensitized solar cell with different methods of manufacturing the counter electrode (상대전극 제작 방식에 따른 염료감응형 태양전지 특성 비교 연구)

  • Son, Min-Kyu;Seo, Hyun-Woong;Shin, In-Young;Kim, Jin-Kyoung;Hong, Ji-Tae;Chae, Won-Yong;Kim, Hee-Je
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1338_1339
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    • 2009
  • Dye-sensitized solar cell (DSC) consists of photo electrode, counter electrode and electrolyte. Photo electrode has titanium oxide layer with dye molecule to create electrons. And counter electrode is made of one layer that has catalytic ability for redox system such as the iodide/triiodide couple. Most DSC researchers use platinum as catalyst on counter electrode because platinum has good catalytic ability and conductivity. Platinum is doped on fluorine-doped tin oxide glass with different methods such as sputtering method, electrochemical method and so on. In this paper, we deposit platinum on counter electrode glass with two methods. One is the radio frequency (RF) sputtering method and the other is the chemical method with heating treatment. Finally, we compare the photovoltaic characteristics of DSCs that are assembled using two different counter electrodes.

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Study metal-grade silicon manufacturing and slag refining for the production of silicon solar cell (태양전지용 실리콘 생산을 위한 금속급 실리콘 제조와 슬래그 정련 연구)

  • Lee, Sangwook;Kim, Daesuk;Park, Dongho;Moon, Byung Moon;Min, Dong Jun;Yu, Tae U
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.111.2-111.2
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    • 2011
  • 야금학적 방법을 통한 태양전지용 실리콘 제조를 위하여 아크로(Arc furnace)에서 제조된 용융 상태의 금속급 실리콘을 슬래그와 직접 반응시켜 불순물을 제거하는 공정에 관한 연구를 수행하였다. 이를 위해 아크로와 고주파 유도용해로(High-frequency induction furnace)를 이용하여 금속급 실리콘을 제조와 정련 특성 실험을 수행하였다. 본 연구에서 금속급 실리콘을 제조하기 위한 장비로 150kW급-DC 아크로와 300kW급-AC 아크로를 사용하였다. 원재료로 규석, 코크스(Cokes), 숯, 그리고 우드칩(Wood chip)을 실험 비율에 맞춰 아크로 내부에 장입하고, 이를 용융환원 방법을 통해 반응을 시켰다. 이때 생산된 금속급 실리콘의 순도는 약 99.2~99.8% 이었으며, 원재료의 순도, 장입 비율 및 아크로 운전 특성에 따라 편차가 있다. 아크로에서 생산된 금속급 실리콘의 경우 인(phosphorus), 붕소(boron)를 다량 함유하고 있고, 이를 제거하기 위하여 50kW급 고주파 유도용해로 장비를 사용하여 슬래그 정련 실험을 수행하였다. 슬래그 정련시 사용한 성분은 SiO2, CaO 그리고 CaF2 이며, 금속급 실리콘과 슬래그의 질량비 및 반응 시간에 따른 실리콘 불순물 특성을 평가하였다. 실험결과 인과 붕소는 각각 1 ppm 이하, 5 ppm 이하 였으며, 칼슘을 제외한 대부분의 금속 불순물의 경우 0.1~0.2% 임을 확인하였다.

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