• Journal of Environmental Impact Assessment
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• v.16 no.1
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• pp.27-33
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• 2007

Hexavalent chromium-contaminated soils are encounted at many unregulated discharge and improper handling of wastes from electroplating, leather tanning, steelmaking, corrosion control, and wood preservation industries. Contamination of hexavalent chromium in the soil is a major concern because of its toxicity and threat to human life and environment. Current technologies for hexavalent chromium-contaminated soil remediation are usually costly and/or cannot permanently prohibit the toxic element from entering into the biosphere. Thus, as an alternative technique, immobilization is seen as a cost-effective and promising remediation technology that may reduce the leachable potential of hexavalent chromium. The purpose of this paper is to develope an immobilization technique for the formation of the geochemically stabilized hexavalent chromium-contaminated soil from the reactions of labile soil hexavalent chromium forms with the added soluble phosphate and chromium reducing agent. From the liquid phase experiment, reaction order of chromium reducing agent, soluble phosphate, alkali solution shows the best removal efficiency of 95%. In addition, actual soil phase experiment demonstrates up to 97.9% removal efficiency with 1:1 molar ratio of chromium reducing agent and soluble phosphate. These results provide evidence for the potential use of soluble phosphate and chromium reducing agent for the hexavalent chromium-contaminated soil remediation.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.91-96
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• 2001

Restoration of contaminated soils to an environmentally acceptable condition is important. One of the newer techniques in soil remediation is a method based on electrokinetic phenomena in soils. The technology uses electricity to affect chemical concentrations and water flow through the pores of soils. An important advantage of electrokinetic soil remediation over other in-situ processes such as soil flushing is the capability of control over the movement of the contaminants. Because the migration of the contaminants is confined by the electric field, there is little dispersion outside the treatment zone. Furthermore, the process is effective for soils with low and variable permeability. In the present study, the distributions of cadmium in the electrokinetic processing of kaolinite under the condition of constant applied voltage are investigated. Cadmium accumulates near the cathode without reducing the diffusion of hydroxide ion into the soil. In keeping the catholyte pH at neutrality, cadmium migrates toward the cathode without any accumulation of cadmium near the cathode and is successfully removed at the cathode reservoir. It was also found that the progress of electrokinetic processing of cadmium could be gasped to a certain extent by monitoring the local voltage and the current density.

• Journal of Soil and Groundwater Environment
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• v.15 no.2
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• pp.34-39
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• 2010

In this study, the remediation of diesel contaminated soil was attempted with ozone treatment and Fenton reaction. About 10% of initial diesel concentration was removed by the ozone saturated solution. The pseudo-first order decomposition constant of diesel contaminated soil in the presence of 5% of hydrogen peroxide with 1.82, 2.82, 4.82, 6.82, and 11.82% of iron contents was 0.0228, 0.0308, 0.0482, 0.0471, and 0.0592 $min^{-1}$ respectively. The decomposition constant of the diesel was 0.0064 $min^{-1}$ with the addition of ozone saturated solution only. On the addition of ozone saturated solution in the presence of 5% hydrogen peroxide and 5% iron, the decomposition constant of the diesel was 0.0850 $min^{-1}$. These results indicated that the decomposition rate was 190% faster than without the addition of ozone saturated solution. Thus, the application of both ozone and the fenton reaction is promising for the remediation of the diesel contaminated soil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.02a
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• pp.65-78
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• 2003

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.02a
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• pp.61-73
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• 2001

• Environmental Analysis Health and Toxicology
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• v.17 no.4
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• pp.347-355
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• 2002

As concerns on the effects of soil contamination on human health have grown, more efforts have been made to quantify the effects. One of such efforts is the development of risk assessment methodology. The fundamental objectives of this approach is to investigate the alternative options that reduce the risk of hazardous chemicals results from environmental pollution, which will eventually lead to an accomplishment of removement of identified toxicants in polluted environment. The U.S. EPA Risk Assessment guidance for the superfund (RAGS) provides a methods for assessing the health risk of contaminated soils and determining the preliminary remediation goals (PRGs). Using this approach, we assessed the health risk and preliminary remediation goals of petroleum contaminated site in Kyounggi province.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.302-306
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• 2004

Probabilistic approaches are applied to the problem of groundwater remediation design to consider the risk of design and heterogeneity of real condition. Hydraulic conductivity fields are generated by two methods. First, the homogeneous domains which have the hydraulic conductivity with log-normal distribution are constructed by using Latin Hypercube method. Second, random fields with a certain spatial correlation are also generated. The optimal solutions represented by cumulative distribution function (CDF) of relative cost are calculated by three different manners. The one uses the homogeneous domains with the optimal design of base condition. It shows that ver)'wide range of cost and the influences of different penalty values. The other one uses the random field with same design and shows narrow range of cost. These CDF can reflect on the risk of optimal solution in a simple exampie condition and be effective in estimating the cost of groundwater remediation.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.63-66
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• 2002

Developers have, for some time now, recognised the benefits of acquiring "brownfields" sites for future urban development. The term “brownfield” generally refers to sites that have been previously occupied and in most cases this occupation has been for industrial usage. A key issue that developers face when considering the acquisition of a former industrial site is contamination and the costs associated with remediating the land to a level that renders the site suitable for its proposed use. Understanding all of the issues and implications associated with the remediation of contaminated land can be quite daunting. The process of remediation brings together a number of stakeholders that all have some influence on the outcome of the works. The stakeholders include the vendor, the purchaser, the regulatory authorities i.e. EPA and council, the Site Auditor and local residents. Careful planning and negotiation with the above stakeholders should be considered before committing to any remediation project.n project.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.293-296
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• 2004

The objective of this study was to decide the designing factor for remediaton of the contaminated site. The soil and ground-water samples were analyzed and hydro- geological characteristics was assayed for the survey of pollution level. Also air-permeability test and MPN(most probable number) test were conducted for selecting the designing factor. The contaminants were mainly found in north-west part of the site and were expected to move toward the south. Ex-situ technology was expected more useful than in-situ one with the results of air-permeability test saying that air permeability was relatively low. Additional microbes were expected for remediation efficiency because residual microbes were loosely populated. The choosing of the designing factor was requisite for remediation of contaminated site.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.05a
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• pp.121-124
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• 2000

In-situ soil remediation using electrokinetics has been investigated and the attempts for the removal of hydrocarbons have been continued. In this study, the electrokinetic remediation using three different kinds of surfactnats was conducted for the removal of phenanthrene from clay The used surfactnats were APG, Brij30 and SDS. In the solubility test for phenanthrene, the experimental result was APG