• Title/Summary/Keyword: sodium potassium

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Aromatization of 1,3,5-Trisubstituted of 4,5-Dihydro-1H-Pyrazoles by In-Situ Generation of I+ from Hydrogen Peroxide/Acids/Iodide Potassium or Sodium Systems

  • Maleki, Behrooz;Veisi, Hojat
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4366-4370
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    • 2011
  • A simple, green and cost-effective protocol was used for the aromatization of 1,3,5-trisubstituted-2-pyrazolines to the corresponding pyrazoles by in situ generation of iodine ($I^+$) from $H_2O_2$/AcOH or SSA or oxalic acid /KI or NaI system under thermal condition with moderate to good yields.

A Simple and One-pot Oxidative Conversion of Alcohols or Aldehydes to the Nitriles using NaIO4/KI in Aqueous NH3

  • Zolfigol, Mohammad Ali;Hajjami, Maryam;Ghorbani-Choghamarani, Arash
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4191-4194
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    • 2011
  • Sodium periodate ($NaIO_4$) and potassium iodide (KI) in aqueous ammonia has been used for the one-pot synthesis of nitriles from the corresponding aldehydes and alcohols in moderate to good yield. This transformation, proceeds via an in situ oxidation- imination-aldimine oxidation sequence.

Effect of a Reductant on Production and Characteristics of Tantalum Powder (탄탈륨 분말제조시 분말특성에 미치는 환원제의 영향)

  • Yun, Jae-Sik;Park, Hyeong-Ho;Bae, In-Seong;Lee, Sang-Baek;Yun, Dong-Ju;Kim, Byeong-Il
    • Korean Journal of Materials Research
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    • v.11 no.12
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    • pp.1047-1051
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    • 2001
  • Purity tantalum powder has been produced by sodium reduction of potassium tantalum fluoride($K_2TaF_7$)in a stainless steel bomb. The influence of experimental variable, such as excess of reductant and temperature of reduction on the yield and quality of the Ta powder has been studied. The excesses of reductant were varied from -20%, -10%, 0%, 5%, 10%, 20%. When -20% excess of sodium was used, the un-reacted sodium remained in the reacted product. The yield of 81% of Ta powder has been achieved by reducing 50g of$K_TaF_7$with 5% sodium in excess of stoichiometric amount in presence of 16.8g of sodium chloride in the charge at a reduction temperature of$905{\circ}C$. The proportion of fine fraction(~325mesh) decreased appreciably with the increase of sodium excess, and the yield of tantalum powder improved from 65% to 94%. The average particle size of Ta Powder is improved from 3 microns to 4 microns in the 5% excess sodium.

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Effect of Phosphates on Lytic Activity of Bacteriophages Infected in Lactobacilus Cells (유산간균 Bacteriophage의 증식억제물질)

  • 강국희;박기문
    • Microbiology and Biotechnology Letters
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    • v.10 no.4
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    • pp.253-258
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    • 1982
  • Lactobacillus casei YIT 9018 was infected with phage J1 and subjected to grow in $Ca^{++}$ -free MRT (spell out) medium under the presence of four different types of phosphates, sodium-metaphosphate,-pyrophos-phate,-dibasic phosphate, and potassium-phosphate. Among the phosphates tested, sodium pyrophosphate showed sufficient inhibition on the lytic activity of the phage at 0.1% level whereas other phosphate needed more than 0.2% for the same effect. When the concentration of sodium pyrophosphate increased to 0.17%, the bacteria could be protected from lysis until the second succeeding transfer.

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The Effect of Reducing Agent on the Production of Niobium Powder by Metallothermic Reduction (금속열환원법에 의한 니오븀 분말제조시 환원제의 영향)

  • Hwang, Sun-Ho;Yoon, Jae-Sik;Kim, Byung-Il
    • Journal of the Korean institute of surface engineering
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    • v.42 no.4
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    • pp.186-189
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    • 2009
  • In this study, niobium powder was made from potassium heptafluoroniobite($K_2NbF_7$) using sodium(Na) as a reductant and KCl, KF as a diluent based on the hunter metallothermic reduction method. The excesses of reductant were varied from 0%, 3%, 5% and 7%. When 7% excess of sodium was used, the un-reacted sodium remained in the reacted product. The niobium powder has been achieved by reducing 50 g of $K_2NbF_7$ with 5% sodium excess in a charge at a reduction temperature of $850^{\circ}C$. The proportion of fine fraction decreased appreciably and the yield of niobium powder improved from 65% to 85% with the increase of sodium excess. The average particle size of niobium powder is improved from 0.2 microns to 0.3 microns in the 5% excess sodium.

Acute Changes of R-A-A system following Lasix Administration in Normal Korean and Subjects with Low Sodium Intake (정상 한국인 및 저식염식인에서 본 이뇨제투여후의 Renin-Angiotensin-Aldosterone 계)

  • Sung, Ho-Kyung;Koh, Joo-Hwan
    • The Korean Journal of Physiology
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    • v.8 no.1
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    • pp.7-14
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    • 1974
  • This study was carried out to investigate the acute changes in R-A-A system following lasix administration, and to evaluate the materials in plasma R-A-A system and electrolytic excretion every 30 minutes for 2 hours after lasix administration with normal high sodium Korean food, moderate sodium restriction, and severe sodium restriction, and it was concluded as followed; 1. Plasma renin activity, angiotensin II concentration, and aldosterone concentration elevated in course of time after lasix administration with high sodium Korean food, but the R-A-A system takes insignificant part because of the increasing rate was so slight. 2. Although the increasing rate of plasma renin activity reached lower levels, angiotensin II and aldosterone concentration were significantly increased after lasix administration with moderate sodium restriction. 3. It was observed that higher rise in aldosterone concentration following lasix administration during severe sodium restriction than when moderate sodium restriction. 4. Urinary sodium and potassium excretion during two hours after lasix administration showed decrease as little as the amount of sodium intake, but K/Na excretion ratio showed increase with small amount of sodium intake because of the decreasing rate of potassium was low value. 5. Sodium excretion after lasix administration reached more than 1.5 times of sodium intake, even though R-A-A reaction showed significantly. 6. As our results showed, R-A-A reaction following acute diuresis was insignificant with high sodium Intake, the increasing ratio of aldosterone concentration showed high rise compare with of plasma renin activity as little as the amount of sodium intake, and the participated rate in sodium reabsorption of R-A-A system was increased.

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Survey on Sodium and Potassium Content of School Meals as well as Sodium and Potassium Intake by Students in the Daejeon and Chungcheong Area (대전.충청 지역 초.중학교 급식의 나트륨, 칼륨 함량 및 섭취량 조사)

  • Lee, Eun-Mi;Park, You-Gyoung;Jung, Woo-Young;Kim, Mi-Ra;Seo, Eun-Chae;Jung, Rae-Seok;Na, Mi-Ae;Lee, Jin-Ha;Heo, Ok-Soon
    • Journal of the East Asian Society of Dietary Life
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    • v.20 no.6
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    • pp.853-862
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    • 2010
  • This study was conducted as a nationwide project in order to obtain data on the content and intake of sodium in school meals. For this purpose, we selected two elementary and two middle schools in Daejeon as well as four elementary schools in the Chungcheong area. We measured the sodium and potassium contents of 842 dishes as well as their intake levels over 154 days. Sodium content was analyzed using an AAS (Atomic Absorption Spectrometer). The average meal intakes of second and fifth grade elementary school students were 244 g/meal and 304 g/meal, respectively. The meal intake of middle school students was 401 g/meal. Boys tended to eat slightly more than did girls, and students tended to eat more in the spring than in the summer. The average sodium intake per meal was 642 mg (570 mg by elementary school students, 1068 mg by middle school students), which was 32.1% of the UL (Tolerable Upper Intake Level, 2,000 mg per day) according to the KDRIs (Dietary Reference Intakes for Koreans). The sodium intake per meal was not significantly differ between boys and girls or between spring and summer (p>0.05). This study provides fundamental data that can be used to establishment a nutrition policy concerning the adequate content of sodium in school meals.

The effect of salt usage behavior on sodium intake and excretion among Korean women

  • Lee, Jeung-Yun;Cho, Dong-Sook;Kim, Hyun-Ju
    • Nutrition Research and Practice
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    • v.6 no.3
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    • pp.232-237
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    • 2012
  • This study was done to explore the effect of Korean women's salt usage behavior on their sodium intake and excretion according to aging. Dietary sodium intake and salt usage behavior were analyzed to compare the difference between young and middle-aged women. One hundred fifty six young women and 77 middle-aged women without hypertension or any current medication were recruited. Body mass index, waist hip ratio, blood pressure were measured from each subject. Salt usage behaviors were surveyed with questionnaire, sodium intake with 24-hr recall method, and sodium excretion with spot urine. Middle-aged women were more obese than young women according to body mass index and waist hip ratio. Blood pressure was significantly higher for the middle-aged. Young women consumed more fats and middle-aged women more carbohydrates. Middle-aged women consumed more sodium and potassium, and excreted more sodium. Among questionnaire items, kimchi, soup or pot stew, or salted vegetables were found to be related with high sodium diet. Salted vegetables and salted nuts and potato chips were significantly correlated with young women's high sodium diet, while soy sauce on fried food, kimchi, salted vegetables accounted for middle-aged women's high sodium diet. With these results, we concluded that middle-aged women consumed more carbohydrates, less fat, and more sodium and potassium than young women. Middle-aged women frequently choose kimchi, soup or pot stew, or salted vegetables, and they contribute to high sodium intake. We recommend to choose low-salt kimchi, less soup or pot stew, and more fresh vegetables for lower sodium diet.

Effect of Salinity on Growth and Osmoregulation of Sweetfish, Plecoglossus altivelis (은어, Plecoglossus altivelis의 성장과 삼투압 조절에 미치는 염분의 영향)

  • 전민지;강경호;장영진;이종관
    • Journal of Aquaculture
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    • v.12 no.2
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    • pp.123-135
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    • 1999
  • In order to investigate the effect of salinity on growth and osmoregulation of the sweetfish, Plecoglossus altivelis, the fish (post-larva, juvenile, adult) reared in seawater were directly transferred into the experimental rearing water of the different salinities (post-larva : $0\textperthousand$, $5\textperthousand$, $10\textperthousand$, $15\textperthousand$, $20\textperthousand$, $30\textperthousand$. juvenile : $0\textperthousand$, $\10textperthousand$, $20\textperthousand$, $30\textperthousand$. adult : $0\textperthousand$, $15\textperthousand$, $35\textperthousand$, respectively). Fish samples were taken in time courses after transfer for blood and body fluid collection. The changes of sodium, potassium concentration and osmolality of the body fluid and plasma, muscle water content, gonadosomatic index (GSI) and hepatosomatic index (HSI) in the experimental fish were observed in time courses. Growth rate of the post-larva in $\5~25\textperthousand$ were faster than in $0\textperthousand$ (P<0.05). Survival rate was very low in $0\textperthousand$ (P<0.05). No fish survived more than 50 days after transferred into $0\textperthousand$. The concentration of sodium, potassium and osmolality in body fluid of the juvenile sweetfish were slightly decreased at 0.25 day after the beginning of the maintainable level of sodium, potassium and osmolality were $36.4\pm6.2 mM/\ell, 47.5\pm0.7 mM/\ell, 366.3\pm19.1 mOsm/kg, respectively. Except potassium concetration, fish in $0\textperthousand$ and $10\textperthousand$ displayed the pattern of hypoosmotic regulation. Growth rate and survival rate of juveniles of $30\textperthousand$ are significantly low than other groups (P<0.05). The concentration of sodium, potassium and osmolality in plasma of adult sweetfish were slightly decreased at 1 day after the beginning of the maintainable level of sodium, potassium and osmolality were $159.0\pm2.5 mM/\ell, 5.8\pm0.9 mM/\ell, 338.1$\pm13.3 mOsm/kg respectively. Compared with these values, fish in $0\textperthousand$ and $15\textperthousand$ displayed hypoosmotic regultion. Growth and survival rate of adult in $35\textperthousand$ are significantly low than other experimental groups. GSI was the highest in $15\textperthousand$ after 60 days. HSI was the lowest in $35\textperthousand$. With decreased salinities, oxygen consumption was found to be decreased in the other experimental groups compared to the more than $30\textperthousand$.

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Effect of Dietary Zinc Levels on Calcium, Magnesium, Sodium, and Potassium Contents in Rats (아연의 섭취 수준이 흰쥐의 칼슘, 마그네슘, 나트륨, 칼륨 함량에 미치는 영향)

  • Kim, Hyun-Sook;Kang, Mun-Hui;Sung, Chung-Ja
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.8
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    • pp.1037-1041
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    • 2009
  • The effect of dietary zinc levels on macro mineral contents was investigated in rats. Rats were divided into three groups by zinc levels, such as low (50% of requirement, Zn/L), adequate (100%, Zn/A) and high (200%, Zn/H) levels of dietary zinc. The calcium, magnesium, sodium and potassium contents in serum and organs were measured. The food intake was significantly higher in Zn/L group compared to that of Zn/H group. The body weight gain in Zn/H group was significantly lower than that of other two groups. There were no significant differences in liver, kidney and spleen weights. Also, serum calcium, magnesium, sodium and potassium concentrations were not significantly changed by the zinc diet at any level. In the low zinc diet group, liver calcium content was significantly lower, but the magnesium and potassium contents in spleen were significantly higher than that in other groups. The calcium, magnesium, sodium and potassium contents of kidney were not significantly different for any level of zinc. In conclusion, the macro mineral contents of liver and spleen in the normal rats were changed by zinc levels. Based on this study, the interaction between micro and macro minerals remains to be further studied.