• Title/Summary/Keyword: soda process

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Chemical and Mechanical Properties of Yellow Poplar Pulp Produced by Formic Acid- Hydrogen Peroxide Pulping (개미산-과산화수소 펄핑에 의하여 생산된 백합나무 펄프의 화학적 및 역학적 특성 분석)

  • Sim, Jaehoon;Kim, Jeong-Ho;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.6-12
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    • 2013
  • TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

Fabrication of a robust, transparent, and superhydrophobic soda-lime glass

  • Rahmawan, Yudi;Kwak, Moon-Kyu;Moon, Myoung-Woon;Lee, Kwang-Ryeol;Suh, Kahp-Yang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.86-86
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    • 2010
  • Micro- and nanoscale texturing and control of surface energy have been considered for superhydrophobicity on polymer and silicon. However these surfaces have been reported to be difficult to meet the robustness and transparency requirements for further applications, from self cleaning windows to biochip technology. Here we provided a novel method to fabricate a nearly superhydrophobic soda-lime glass using two-step method. The first step involved wet etching process to fabricate micro-sale patterns on soda-lime glass. The second step involved application of $SiO_x$-incorporated DLC to generate high intrinsic contact angle on the surface using chemical vapor deposition (CVD) process. To investigate the effect of surface roughness, we used both positive and negative micro-scale patterns on soda-limeglass, which is relatively hard for surface texturing in comparison to quartz or Pyrex glasses due to the presence of impurities, but cheaper. For all samples we tested the static wetting angle and transparency before and after 100 cycles of wear test using woolen steel. The surface morphology is observed using optical and scanning electron microscope (SEM). The results shows that negative patterns had a greater wear resistance while the hydrophobicity was best achieved using positive patterns having static contact angle up to 140 deg. with about 80% transparency. The overall experiment shows that positive patterns at etching time of 1 min shows the optimum transparency and hydrophobicity. The optimization of micro-scale pattern to achieve a robust, transparent, superhydrophobic soda-lime glass will be further investigated in the future works.

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Preparation of Foamed Glass Block from Recycled Soda-lime-silicate Glasses by Chemical Composition Control (폐 소다석회 유리의 조성조절에 의한 발포유리블록의 제조)

  • Kim, Jung-Min;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.382-390
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    • 2013
  • Foaming process of waste soda lime glasses by just chemical composition control of vitreous feed materials was investigated to find a novel and efficient recycling process. For the chemical composition control of feed materials, 10 wt. parts of $SiO_2$, 0.5 wt. parts of $Na_2SO_4$, 3.0 wt. parts of $B_2O_3$, and 0.3 wt. parts of carbon black as the foaming agent were mixed with 100 wt. parts of soda-lime vitreous feed powder. Proper conditions for foaming process in tunnel kiln are the foaming temperature of $830{\sim}850^{\circ}C$, the foaming time of 30~35 min, and the vitreous feed powder particle size of -325 mesh. Properties of foamed glass blocks obtained under these foaming conditions showed the density of $0.17{\sim}0.21g/cm^3$, thermal conductivity of $0.06{\pm}0.005kcal/h{\cdot}m{\cdot}^{\circ}C$, moisture absorption of 1.1~1.5%, and compressive strength of $20{\sim}30kgf/mm^2$.

Preparation and Characteristics of Soda Lime for Carbon Dioxide Absorption (이산화탄소 흡수를 위한 소다라임 제조 및 특성)

  • Young-Jin Kim;Seok-Je Kwon;Jun-Hyung Seo;Yang-Soo Kim;Kye-Hong Cho;Jin-Sang Cho
    • Resources Recycling
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    • v.32 no.2
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    • pp.52-58
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    • 2023
  • In this study, soda lime was prepared from slaked lime to expand the scope of limestone use. To evaluate carbon dioxide absorption, an extruder-type and disc-type pelletizers were used to make the soda lime using bentonite as an additive. Regardless of the pelletizing process, the peak of CaCO3 was confirmed in soda lime due to its reaction with carbon dioxide. Furthermore, it was confirmed that both calcite and aragonite were present together. The soda lime prepared using the disc-type pelletizer showed a larger specific surface area than that prepared using the extruder-type pelletizer did, and the specific surface area improved on adding bentonite. The carbon dioxide absorption rate increased under the sample condition with an enhanced specific surface area.

($TruNano^{TM}$ processing of dielectric layers and barrier-rib on soda-lime glass substrate for PDP panel

  • Lee, Michael M.S.;Kim, Nam-Hoon;Cheon, Chae-Il;Cho, Guang-Sup;Kim, Jeong-Seog
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.125-125
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    • 2006
  • We present a low temperature thermal process for the transparent dielectric layer, barrier rib, and white back dielectric layer on the soda-lime glass substrate of the PDP by the $TruNano^{TM}$ processor in combination with a compositional modification to the conventional dielectric pastes. By this method the firing temperature can be lowered by more than $100^{\circ}C$.

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Use and Evaluation of Lignin as Ion Exchangers (이온교환체로서 리그닌의 이용과 평가)

  • Ads, Essam.N.;Nada, A.M.A.;El-Masry, A.M.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.86-91
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    • 2011
  • Modified lignins were prepared. Soda and peroxy lignins were precipitated from black liquor produced from bagasse pulping with soda and peroxyacid pulping process. The precipitated lignins were hydrolyzed using 10% HCl. Different functional groups were also incorporated into lignin by carboxylation and phosphorylation reactions. Moreover crosslinking of these lignins were carried out using epichlorohydrin. Characterization of the modified lignins and lignins derivative were carried out using Infrared spectroscopy. Thermal analysis of these compounds were also carried out using TGA and DTA techniques. Efficiency of sorption of metal ions by the modified lignin was also investigated. It was found that, the peroxylignin and its derivatives show higher efficiency toward metal ions uptake than the soda lignin.

The Effects of Boundary Condition in Cone Crack Formation of Soda-lime Glass by Ball Impact (볼 충격을 받는 유리의 콘크랙형성에 대한 경계조건의 영향)

  • Kim, Moon-Saeng;Heo, Jin;Lee, Hyeon-Chul;Kim, Ho-Jong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.6
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    • pp.981-986
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    • 2003
  • In order to investigate the possibility of processing of brittle material by ball impact, the effects of boundary conditions about impact damage of soda-lime glass by small spheres were evaluated experimentally. It was investigated that crack appearance developed in soda-lime glass with boundary conditions of without sealing, single-sealing and double-sealing by impact velocity. The double-sealing was most effective in the development of perfect cone than other boundary condition. In case of double-sealing condition, PVC and Polyurethane sealing were more effective in producing a perfect cone formation than other sealing materials. The impact velocity range over which perfect cones were formed was influenced by both the contact area and diameter of impact particle.

New 2-methyl Anthraquinone Synthesis Approach and Application in Soda-anthraquinone (AQ) Pulping

  • Shin Soo-Jeong;Francis Raymond C.;Omori Shigetoshi
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.35-40
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    • 2005
  • We tried to synthesize the 2-methyl anthraquinone (2-MAQ) with reaction between phthalic anhydride and toluene instead of using 2-methyl phthalic anhydride and benzene. This process didn't generate significant of amount of 1-methyl anthraquinone (l-MAQ) as byproduct. The other advantage of this pathway is using less toxic toluene instead of benzene known as carcinogen. 2-MAQ synthesized this pathway was as effective as reagent grade from commercial available based on soda-anthraquinone(AQ) pulping results.

CO2 Laser Scribing Process of Soda Lime Glass (소다석회유리의 CO2 레이저 스크라이빙 가공)

  • Kang, Seung-Gu;Shin, Joong-Han
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.5
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    • pp.74-81
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    • 2019
  • This study reports the CW $CO_2$ laser scribing of soda lime glass. In this study, scribing experiments are carried out at different laser powers, scan speeds, and focal positions to investigate the effect of the process parameters on the interaction characteristics between a laser beam and glass. In particular, the interaction characteristics are analyzed and described with the input laser energy per unit length. According to the experimental results, the damage threshold for the glass surface was found to exist between 0.072 and 0.08 J/mm. The input laser energy in this region induced partial melting of the surface and grain-shaped cracks. These cracks tended to increase as the input laser energy increased. At the laser input energy larger than 1 J/mm, a huge crack propagating along the scan direction was produced, and the volume below the scribed area was fully melted. The growth of this crack finally resulted in the complete cutting of the glass at the input laser energy above 8 J/mm. It was found that both the width and depth of the scribed line increased with increasing input laser energy. For the beam focusing at the rear surface, the width of the scribed line varied irregularly. This could be ascribed to the increased asymmetry of the beam intensity distribution when the laser beam was focused at the rear surface. Under this condition, a large burr was only produced on one side of the scribed line.