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Size-controlled Chevrel Mo6S8 as Cathode Material for Mg Rechargeable Battery

  • Ryu, Anna;Park, Min-Sik;Cho, Woosuk;Kim, Jeom-Soo;Kim, Young-Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3033-3038
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    • 2013
  • Nanoscale Chevrel $Mo_6S_8$ powders are synthesized by molten salt synthesis. Synthesized $Mo_6S_8$ powders have different mean particle sizes which are dependent on a ratio of salt to precursor. The particle sizes of $Mo_6S_8$ powders changes along with the ratio increase. $Mo_6S_8$ (6:1) demonstrates the best electrochemical characteristics among the synthesized $Mo_6S_8$ powders although the $Mo_6S_8$ (4:1) has the smallest particle size. $Mo_6S_8$ (6:1) shows a reversible capacity of 83.9 $mAhg^{-1}$, which is 27.5% and 33% improved value over $Mo_6S_8$ (2:1) and $Mo_6S_8$ (4:1) at a current density of 0.2C, respectively. The superior electrochemical properties of $Mo_6S_8$ (6:1) are attributed to the balanced particle size which provides proper contact area with electrolyte and the shortened $Mg^{2+}$ diffusion length. The $Mo_6S_8$ (4:1) has the smallest particle size but further reduction of particle size from $Mo_6S_8$ (6:1) is not advantageous.

Population Dynamics of Arisaema robustum (넓은잎천남성 (Arisaema robustum) 개체군의 동태)

  • 민병미;유진숙
    • The Korean Journal of Ecology
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    • v.21 no.1
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    • pp.27-33
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    • 1998
  • Arisaema robustum, which has the ability to change sex, was studied in a temperate broadleaf forest of Sanseong-ri, Joongbu-myeon, Gwangju-gun, Kyonggi Province, Korea. \ulcornerThe study, carried out from 1993 to 1997, focused on population dynamics energy budget among organs, size distribution, mortality, the relationships between sex and size, seed production and germination rate. In terms of energy budget among the organs, the ratio of aboveground to belowground biomass was 36.6 : 63.4 in non-female plants, and 81.4 : 18.6 in female plants. Also, in female plants, the ration of leaf to sexual organ biomass was 39.5 : 41.9. Therefore, the belowground ratio of female plants was lower than that of non-female plants. Plants were classified into 8 levels relative to the amount of leaf area by $100cm^2$. The rates of the smallest and the largest classes were 49% and 1%, respectively, and population distribution by size was relatively stable. The mortality averaged 13.1% per year and decreased in inverse proportion to leaf size (6.6% in the smallest and 0.0% in the largest size classes). Leaf areas were $64.1{\pm}48.5cm^2$ in non-flowering plants, $232.1{\pm}123.9cm^2$ in males and $444.8{\pm}153.9cm^2$ in females. The increase rates of leaf area per year varied from 1.9% in plants changing from female tomale, to 152.4% in plants changing from non-flowering to female. But plants which remained female for 2 years showed a decrease of 34.7%. >From this result, it is thought that the female plants invest more energy to reproduction than to vegetative organs. The correlation coefficient (CC) value between plant size and the number of seeds produced (0.55) was larger than the CC value between plant size and total seed weight (0.73). That is, the larger the plant size, the heavier the seed produced. The germination rate increased along with seed weight, and it was 95% in plants which were over 60mg fresh weight/seed.

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Accuracy evaluation of resin complete denture made with glass fiber mesh reinforcement before and after curing (유리섬유 보강재로 제작한 레진의치의 온성 전·후에 따른 정확성 평가)

  • Kim, Dong-Yeon;Jung, Il-Do;Park, Jin-Young;Kang, Seen-Young;Kim, Ji-hwan;Kim, Woong-Chul
    • Journal of Technologic Dentistry
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    • v.39 no.1
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    • pp.25-33
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    • 2017
  • Purpose: The aim of this study was to evaluate accuracy of glass fiber mesh complete denture of before and after curing. Methods: Edentulous model was selected as the master model. Ten study models were made by Type IV stone. Wax complete dentures were produced by the denture base and artificial teeth. CD and GD groups were measured six measurement distance before curing. The wax complete denture was investment after measurement is completed. Using a heat polymerization resin was injected resin. After injecting the resin it was curing. A complete denture was re-measured after curing. The measured data was verified by paired t-test. Results: Overall CD group was larger the value of the measured length. In the CD group, A-D point was larger. The smallest point was the B-D point. However, there was no statistically significant difference only C-D point(p>0.05). In the GD group, A-B point was larger. but B-D point was the smallest. A-D and B-C statistically points showed significant differences(p<0.05). Conclusion: Glass fiber mesh resin complete denture can be clinically applied to the edentulous patient.

Uptake Effects of Two Electrons for Relative Stability and Atomic Structures of Carbon Cluster Isomers of C20: ab initio Methods

  • Lee, Wang-Ro;Lee, Chang-Hoon;Kang, Jin-Hee;Park, Sung-Soo;Hwang, Yong-Gyoo;Lee, Kee-Hag
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.445-448
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    • 2009
  • This study examined the effect of the uptake of one and two electrons on the atomic structure of three isomers of $C_{20}$ clusters, namely the ring, bowl (corannulene like), and cage (the smallest fullerene). Geometry optimizations were performed using the hybrid density functional (B3LYP) methods for neutral, singly and doubly charged $C_{20},\;{C_{20}}^-,and\;{C_{20}}^{2-}$. These results show that the symmetry of the lowest energies for ring and bowl isomers were not changed, whereas the increasing order of energy for the cage (the smallest fullerene) isomers was changed from $D_{2h}\;<\;C_{2h}\;{\leq}\;C_2\;of\;C_{20}\;through\;Ci\;<\;C_{2h}\;<\;C_2\;<\;D_{2h}\;of\;{C_{20}}^-\;to\;Ci\;<\;C_2\;<\;D_{2h}\;<\;C_{2h}\;of\;{C_{20}}^{2-}$. The reduced symmetry isomers of the cage have comparative energy and the ground state symmetry of the neutral and single and double charged $C_{20}$ decreased with increasing number of electrons taken up in the point of energetics. Interestingly, the difference in energy between the ground state and the next higher energy state of ${C_{20}}^{2-}$ was 3.5kcal/mol, which is the largest energy gap of the neutral, single anion and double anion of the cage isomers examined.

The Study on Workload Reducing Effects of Multi-Elastic Insoles (다탄성 Insole의 Workload 감소 효과에 관한 연구)

  • Lee, Chang-Min;Lee, Kyun-Deuk;Oh, Yeon-Ju;Kim, Jin-Hoon
    • Journal of the Ergonomics Society of Korea
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    • v.26 no.2
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    • pp.157-165
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    • 2007
  • The Work-Related Musculoskeletal Disorders (WMSDs) can be occurred by various factors such as repetition, forceful exertions and awkward postures. Especially, occurrences of the WMSDs on the waist and lower limb are reported in workplaces, demanded standing postures for a long time, in service and manufacturing industry. The static and standing postures without movement for a long time increase work loads to the lower limb and the waist. Accordingly, anti-fatigue mat or anti-fatigue insole is used as a preventing device of the WMSDs. However anti-fatigue mats are limited in space and movement. In this study, multi-elastic insoles are designed and shown the effects of the workload reduction for a long time under the standing work. The foot pressures and EMG (Electromyography) are measured at 0 hour and after 2 hours by 6 health students in their twenties. The 6 prototype insoles are designed with three elastic (Low, Medium and High). These insoles are compared with no insole (insole type 7) as control group. The EMG measurement was conducted to waist (erector spinae muscle), thigh (vastus lateralis muscle) and calf (gastrocnemius muscle). The foot pressure is analyzed by mean pressure value and the EMG analysis is investigated through MF (Median Frequency), MPF (Mean Power Frequency) and ZCR (Zero Crossing Rate). The results of the foot pressure show that the multi-elastic insoles had smaller foot pressure value than that of no-insole. Moreover, Insole 2 and Insole 3 have the smallest increasing rate in foot pressure. The EMG results show that the multi-elastic insoles had smaller EMG shift value than that of no-insole in 2 hour, and then shift value shows the smallest value in Insole 2. Therefore, this study presents that the multi-elastic insoles have reducing effects of the work load for a long time standing work in both side of foot pressure and EMG.

COMPARISONS OF PARALLEL PRECONDITIONERS FOR THE COMPUTATION OF SMALLEST GENERALIZED EIGENVALUE

  • Ma, Sang-Back;Jang, Ho-Jong;Cho, Jae-Young
    • Journal of applied mathematics & informatics
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    • v.11 no.1_2
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    • pp.305-316
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    • 2003
  • Recently, an iterative algorithm for finding the interior eigenvalues of a definite matrix by CG-type method has been proposed. This method compares to the inverse power method. The given matrices A, and B are assumed to be large and sparse, and SPD( Symmetric Positive Definite) The CG scheme for the optimization of the Rayleigh quotient has been proven a very attractive and promising technique for large sparse eigenproblems for smallest eigenvalue. Also, it is very amenable to parallel computations, like the CG method for the linear systems. A proper choice of the preconditioner significantly improves the convergence of the CG scheme. But for parallel computations we need to find an efficient parallel preconditioner. Our candidates we ILU(0) in the wave-front order, ILU(0) in the multi-coloring order, Point-SSOR(Symmetric Successive Overrelaxation), and Multi-Color Block SSOR preconditioner. Wavefront order is a simple way to increase parallelism in the natural order, and Multi-coloring realizes a parallelism of order(N), where N is the order of the matrix. Another choice is the Multi-Color Block SSOR(Symmetric Successive OverRelaxation) preconditioning. Block SSOR is a symmetric preconditioner which is expected to minimize the interprocessor communication due to the blocking. We implemented the results on the CRAY-T3E with 128 nodes. The MPI (Message Passing Interface) library was adopted for the interprocessor communications. The test problem was drawn from the discretizations of partial differential equations by finite difference methods. The results show that for small number of processors Multi-Color ILU(0) has the best performance, while for large number of processors Multi-Color Block SSOR performs the best.

Types of perception on the body shape of old-old aged women

  • Cha, Su-Joung
    • Journal of the Korea Society of Computer and Information
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    • v.23 no.4
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    • pp.121-129
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    • 2018
  • The purpose of this study is to provide a basic data of clothing development which can improve the satisfaction of the body shape by examining the subjective evaluation and type characteristics of the old-old women themselves. Q methodology was used for the study of subjectivity. The types of the body shape of the old-old women were analyzed as five types: bent body with protruding abdomen, backward bent body with slender legs, inverted triangle, swollen cylinder, triangle. The bent body with protruding abdomen had a bent back and waist. They were recognized that the bust and shoulders were sagging and abdomen was protruding. The backward bent body with slender legs was the smallest of the five types with a BMI index and shoulders and bust were sagging. And knee and waist were bent and legs were thin. The inverted triangular shape showed the highest BMI index among the 5 types, indicating that it is obese. They thought that the upper body was developed and the lower body and legs were slender. The swollen cylinder shape was analyzed to be the smallest and the most fat body. The triangle shape had developed lower body and bent back and waist. It is considered that a design consideration is needed to cover the disadvantages of the body shape in consideration of not only wearing feeling but also aesthetic part when making clothes. By making ergonomic garments considering the characteristics of body shape, it can be expected to change the body shape due to the wearing of clothing that is not suitable for body shape and the effect on physical health in a positive direction.

Design of high-speed planing hulls for the improvement of resistance and seakeeping performance

  • Kim, Dong Jin;Kim, Sun Young;You, Young Jun;Rhee, Key Pyo;Kim, Seong Hwan;Kim, Yeon Gyu
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.1
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    • pp.161-177
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    • 2013
  • High-speed vessels require good resistance and seakeeping performance for safe operations in rough seas. The resistance and seakeeping performance of high-speed vessels varies significantly depending on their hull forms. In this study, three planing hulls that have almost the same displacement and principal dimension are designed and the hydrodynamic characteristics of those hulls are estimated by high-speed model tests. All model ships are deep-V type planing hulls. The bows of no.2 and no.3 model ships are designed to be advantageous for wave-piercing in rough water. No.2 and no.3 model ships have concave and straight forebody cross-sections, respectively. And length-to-beam ratios of no.2 and no.3 models are larger than that of no.1 model. In calm water tests, running attitude and resistance of model ships are measured at various speeds. And motion tests in regular waves are performed to measure the heave and pitch motion responses of the model ships. The required power of no.1 (VPS) model is smallest, but its vertical motion amplitudes in waves are the largest. No.2 (VWC) model shows the smallest motion amplitudes in waves, but needs the greatest power at high speed. The resistance and seakeeping performance of no.3 (VWS) model ship are the middle of three model ships, respectively. And in regular waves, no.1 model ship experiences 'fly over' phenomena around its resonant frequency. Vertical accelerations at specific locations such as F.P., center of gravity of model ships are measured at their resonant frequency. It is necessary to measure accelerations by accelerometers or other devices in model tests for the accurate prediction of vertical accelerations in real ships.

A Comparative Study on Lowflow Quantiles Estimation in Han River Basin (한강유역의 확률갈수량 추정기법 비교연구)

  • Kim, Kyung-Duk;Kim, Don-Soo;Heo, Jun-Haeng;Kim, Kyu-Ho
    • Journal of Korea Water Resources Association
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    • v.36 no.2
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    • pp.315-324
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    • 2003
  • Stream flow data was analyzed for determining the lowflow which is the standard for river maintenance flow. Lowflow quantiles were estimated based on the parametric and nonparametric methods and two methods were compared by Monte Carlo simulation study. As the results of the parametric method, three probability distributions such as gamma-2, lognormal-2 and Weibull-2, are selected as appropriate models for stream flow data of 13 stations in Han River Basins. According to simulation results, relative bias (RBIAS) and relative root mean square error (RRMSE) of the lowflow quantiles are the smallest when the applied and population models are the same. The fame statistical properties from the nonparametric models are good within the interpolation range. Among 7 bandwidth selectors used in this study, the RRMSEs of the Park and Marron method (PM) are the smallest while those of the Shoaler and Jones method (SJ) are the largest.

Runoff Analysis due to the Moving Rainstorms on the Nonsymmetric Basin Shapes (비대칭 유역형상에 대한 이동강우의 유출영향분석)

  • Jeon, Min-Woo
    • Journal of Wetlands Research
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    • v.11 no.1
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    • pp.1-13
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    • 2009
  • The influence of moving rainstorms to runoff was analysed for the nonsymmetric shaped basins using kinematic wave theory. The distribution types of moving rainstorms are uniform, advanced, delayed and intermediate type, the nonsymmetric shaped basins are square, oblong and elongated shape. The runoff hydrographs were simulated and the characteristics were compared with the symmetric shaped basins for the rainstorms moving up, down and cross the basins with various velocities. The smallest differences of peak runoff of symmetric and nonsymmetric basins are appeared in the case of elongated basin, and the largest differences are shown at the oblong basin for the downstream direction. The identical results are shown for the upstream direction. The greatest peak runoff differences are shown in the delayed type rainstorm and the smallest differences are in the advanced type rainstorm for the crossstream direction. The oblong shaped basin generates the longest peak time and shortest peak time for the elongated shape basin.

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