• Title/Summary/Keyword: small water system

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Retention Behavior of Organic Compounds on Reversed-Phase Column expected by Van der Waals Volume (Van der Waals Volume을 이용한 역상 컬럼에서의 유기화합물들의 용출거동)

  • Park, Wun-Kyu;Lee, Yong-Moon;Moon, Dong-Cheul;Kang, Jong-Seong
    • Analytical Science and Technology
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    • v.6 no.4
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    • pp.383-390
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    • 1993
  • Retention behaviors of aliphatic and aromatic compounds were investigated with Van der Waals volume which represented the molecular size. The organic solvents, methanol, acetonitrile and tetrahydrofuran, were mixed with water at various ratio, respectively. The selectivity of organic solvents were tested by change of column temperature. The capacity factor was increased linearly according to the enlargement of molecular size. Therefore, Van der Waals volume was useful to predict the elution of organic molecules in reversed-phase column. The order of elution capacity of solvents was methanol

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Obervation of Langmuir Films Using Displacement Current Method and BAM (Brewster-Angle Microscope) (변위전류법과 BAM(BREWSTER-ANGLE MICROSCOPE)를 이용한 LANGMUIR막의 관찰)

  • Song, Kyung-Ho;Park, Tae-Gone;Park, Keun-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.38-42
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    • 2001
  • To observe the Langmuir films, displacement current measuring system(Nippon Laser & Electronics), $\pi-A$ isotherms measuring device, and Brewster Angle Microscope(BAM) were used. As results, for 8A5H, big tilt angle changes of many molecules were detected before liquid expanded phase when the monolayer was compressed and expanded by barrier. Also many small and bright points were detected by BAM when the displacement current radically changed. In $\pi$-A isotherms, surface pressure of 8A5H was radically decreased between 35 and 40[mN/m] and monolayer was assumed to be collapsed in solid condensed phase, since large bright domain was observed without change of displacement current and this bright boundary was not classified part of domain in BAM image. If we observe behaviors of molecules on the water surface in these three measurement at the same time, we can get more precise informations on L films and it could be good data for fabricating LB films.

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Effect of Cool Islands on the Thermal Mitigation in Urban Area -Case Study of Taegu Metropolitan City- (대도시에 있어 냉섬의 유형별 온도완화 효과 -대구광역시의 사례 연구-)

  • 박인환;장갑수;김종용;박종화;서동조
    • Journal of the Korean Institute of Landscape Architecture
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    • v.28 no.1
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    • pp.11-18
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    • 2000
  • Taegu is notorious as hot and dry summer among Korea cities. One of the most important goals of the open space planning is to ameliorate urban climate of the city. The objective of this research is to evaluate the thermal mitigation effect of the cool islands in Taegu metropolitan city. Cool islands of this paper includes parks and rivers surrounded by or adjacent to urbanized areas. Based on the analysis of the thermal band of Landsat TM at May 17, 1997, the thermal mitigation effect of open spaces in the city could be summarized as follows ; Kumho river showed the largest mitigation effect in terms of the width of mitigation zone and temperature difference. Evaporation from wide water surface and evapo-transpiration from riparian grass land could bring into results. Significant mitigation effect of parks covered with forest can be observed. The temperature range of such parks were between 19.05$^{\circ}C$ and 19.44$^{\circ}C$ However, the thermal mitigation effect of Dalsung park and Apsan park was insignificant. The small size and high percentage of hard paving of the former and the relative low density of the residential areas adjacent to the latter could be the main reason. In conclusion, the thermal mitigation effect in urban ope spaces could be detectedby the employment of thermal band data of Landsat TM and GIS buffering technique.

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Design and Implementation of Lamp-Heated LPCVD System (램프 가열 방식 LPCVD 장비의 설계 및 제작)

  • Ha, Yong-Min;Kim, Tae-Sung;Kim, Choong-Ki
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.299-303
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    • 1991
  • A lamp heated LPCVD equipment has been made. Wafer is heated by an array of fifteen tungsten halogen lamps above the front side of a wafer and pyrometer views the back side of the wafer through $CaF_2$ window. Reactor which consisits of a quartz window and a water cooled-stainless steel plate can be evacuated to $5{\times}10^{-3}$ torr with a rotary vane pump. By pyrolysis of $SiH_4$ at about $600^{\circ}C$, polysilicon has been formed on the silicon dioxide film. The measured results show that thickness nonuniformity is 15% and temperature nonuniformity is 1.1%. Because activation energy of pyrolysis of $SiH_4$ is very high, about 1.8eV, small temperature variation will induce large thickness nonuniformity. The main cause of temperature nonuniformity is unsymmetry of lamp power and an unbalanced cooling structure. Charls & Evans' SIMS result shows that the oxygen content in the deposited polysilicon is comparable to that of silicon substrate but carbon content is ten times higher.

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$S^{35}$(1,2-dichloro vinyl) L-Cysteine의 소에 의(依)한 대사물(代謝物)의 분리(分離)

  • Kim, Jae-Uk
    • Applied Biological Chemistry
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    • v.2
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    • pp.36-39
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    • 1961
  • It has been ascertained that S-(1, 2-dichlorovinyl) L-cysteine (DCVC) is probably the toxic component in the trichloro-ethylene extracted soybean oil meal on the bovine. For the study of the metabolites of DCVC, the components with radioactive $S^{35}$-in the urine of the calf, to which $S^{35}$-DCVC was administrated, were separated using of cellulose powder with propanol-water (70:30 V/V) which is easily removable by evaporation. As the results followings were obtained: Peak 1, which shows fractions containing single $S^{35}$-radioactive components, whose Rf is 0.815 Peak 2, which shows fractions containing jingle $S^{35}$-radioactive component, whose Rf is 0.447 Peak 3, which shows fractions containing both $S^{35}$-radioactive components whose Rfs are 0.090 and 0.171 Peak 4, which shows fractions containing single $S^{35}$-radioactive component, whose Rf is 0.142. Peak 5, which shows fractions containing single $S^{35}$-radioactive component, whose Rf is 0.084. Besides these, two of small peak were obtained. Although, the resolving power of the cellulose powder column is not sufficient, it is applicable for the study of the components of metabolytes of DCVC conveniently with the rest of removable solvent easily. Also the components with radioactive $S^{35}$ in the feces of the calf were separated using citrate buffer gradient system of Moore and stein. As the results; three $S^{35}$-radioactive components were separated.

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A Proposal for Generating Good Assembly Sequences by Tournament Tree

  • Tsuboi, Kenji;Matsumoto, Toshiyuki;Shinoda, Shinji;Niwa, Akira
    • Industrial Engineering and Management Systems
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    • v.10 no.2
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    • pp.161-169
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    • 2011
  • In seeking further efficiency in production preparation, it is common to examine assembly sequences using digital manufacturing. The assembly sequences affect the product evaluation, so it is necessary to test several assembly sequences before actual production. However, because selection and testing of assembly sequences depends on the operator's personal experience and intuition, only a small number of assembly sequences are actually tested. Nevertheless, there is a systematic method for generating assembly sequences using a contact-related figure. However, the larger the number of parts, the larger the number of assembly sequences geometric becomes. The purpose of this study is to establish a systematic method of generating efficient assembly sequences regardless of the number of parts. To generate such assembly sequences selectively, a "Tournament Tree," which shows the structure of an assembly sequence, is formulated. Applying the method to assembly sequences of a water valve, good assembly sequences with the same structure as the Tournament Tree are identified. The structure of such a Tournament Tree tends to have fewer steps than the others. As a test, the structure is then applied for a drum cartridge with 38 parts. In all the assembly sequences generated from the contact-related figures, the best assembly sequence is generated by using the Tournament Tree.

Real-time Flood Forecasting Model Based on the Condition of Soil Moisture in the Watershed (유역토양수분 추적에 의한 실시간 홍수예측모형)

  • 김태철;박승기;문종필
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.37 no.5
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    • pp.81-89
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    • 1995
  • One of the most difficult problem to estimate the flood inflow is how to understand the effective rainfall. The effective rainfall is absolutely influenced by the condition of soil moisture in the watershed just before the storm event. DAWAST model developed to simulate the daily streamflow considering the meteologic and geographic characteristics in the Korean watersheds was applied to understand the soil moisture and estimate the effective rainfall rather accurately through the daily water balance in the watershed. From this soil moisture and effective rainfall, concentration time, dimensionless hydrograph, and addition of baseflow, the rainfall-runoff model for flood flow was developed by converting the concept of long-term runoff into short-term runoff. And, real-time flood forecasting model was also developed to forecast the flood-inflow hydrograph to the river and reservoir, and called RETFLO model. According to the model verification, RETFLO model can be practically applied to the medium and small river and reservoir to forecast the flood hydrograph with peak discharge, peak time, and volume. Consequently, flood forecasting and warning system in the river and the reservoir can be greatly improved by using personal computer.

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A Study for Concrete Crack Minimize Methods in Large Section Tunnel Lining (라이닝 시공특성을 고려한 대단면 4차로 터널 균열최소화 방안에 대한 연구)

  • Choo, Seok-Yeon;Lee, Jae-Sung;Koh, Sung-Yil;Kim, Sang-Whang;Ra, Kyong-Woong;Kim, Tae-Hyok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.621-628
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    • 2005
  • The concrete lining in tunnel performs structural and nonstructural functions. The concrete lining works as a structural member for released load and residual water pressure in NATM tunnel system. Also concrete lining used for finishing the tunnel surface. The initial crack of concrete lining is reported because of difficulties in construction process, which concrete is injected into 30$\sim$40cm narrow gap between lining form and tunnel surface through 500${\times}$600mm small injection holes in the form. In this paper, we research a reason of initial crack occurrence by the case study of 4 lane wide span tunnel, and propose an improved method for crack minimization in construction process. We verify that the proposed method can give qualified concrete lining by carrying out the concrete injection model test and the numerical analysis of concrete flow.

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Cytochrome c Peroxidase: A Model Heme Protein

  • Erman, James E.;Vitello, Lidia B.
    • BMB Reports
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    • v.31 no.4
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    • pp.307-327
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    • 1998
  • Cytochrome c peroxidase (CcP) is a yeast mitochondrial enzyme which catalyzes the reduction of hydrogen peroxide to water using two equivalents of ferrocytochrome c. The CcP/cytochrome c system has many features which make it a very useful model for detailed investigation of heme protein structure/function relationships including activation of hydrogen peroxide, protein-protein interactions, and long-range electron transfer. Both CcP and cytochrome c are single heme, single subunit proteins of modest size. High-resolution crystallographic structures of both proteins, of one-to-one complexes of the two proteins, and a number of active-site mutants are available. Site-directed mutagenesis studies indicate that the distal histidine in CcP is primarily responsible for rapid utilization of hydrogen peroxide implying significantly different properties of the distal histidine in the peroxidases compared to the globins. CcP and cytochrome c bind to form a dynamic one-to-one complex. The binding is largely electrostatic in nature with a small, unfavorable enthalpy of binding and a large positive entropy change upon complex formation. The cytochrome c-binding site on CcP has been mapped in solution by measuring the binding affinities between cytochrome c and a number of CcP surface mutations. The binding site for cytochrome c in solution is consistent with the crystallographic structure of the one-to-one complex. Evidence for the involvement of a second, low-affinity cytochrome c-binding site on CcP in long-range electron transfer between the two proteins is reviewed.

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Chemical Imprints of the Upwelled Waters off the Coast of the Southern East Sea of Korea

  • Lee, Tong-Sup;Kim, Il-Nam
    • Journal of the korean society of oceanography
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    • v.38 no.3
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    • pp.101-110
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    • 2003
  • We made intensive observations on the coastal upwelling off the coast of the southern East Sea from June to August in 2001. The upwelling exhibited a weekly waxing and waning. The coastal upwelling of the year 2001 was characterized by abrupt outbreaks and the small local scale. Upwelling occurred more frequently off the coast of Ulsan and Gampo as reported by the earlier observers. The spread of freshly upwelled colder water was varied by each upwelling event. Generally cold waters were carried away northeastward off Pohang province. The upwelled cold waters were saltier than the resident surface waters. The pH and salinity-normalized alkalinity support the idea that the upwelled waters originate from the interior of the East Sea. The extraordinarily high concentration of dissolved oxygen suggests that the upwelled waters are closely connected to the southward flowing North Korea Cold Current. Although a lower primary productivity was reported for the upwelling region, underway surface fluorescence measurement revealed that the recently upwelled waters supported up to an order of magnitude higher algal biomass than the ambient waters. Because thermohaline circulation of the East Sea is so vigorous, with an estimated time scale of less than one hundred years, that the coastal upwelling should be considered not as an anomaly but as a regular component of a circulatory system. A quantitative understanding of upwelling seems to be a key to elucidate material cycling and the associated biological production in the East Sea.