• Title/Summary/Keyword: slurry coating

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Joint Displacement Resistance Evaluation of Waterproofing Material in Railroad Bridge Deck (철도교량상판 방수재료 선정을 위한 균열거동저항 성능평가)

  • Bae, Young-Min;Oh, Dong-Cheon;Park, Yong-Gul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.683-692
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    • 2020
  • A joint displacement resistance evaluation method for selecting waterproofing materials in railway bridge decks is proposed. The displacement range for an evaluation is determined by finite element method (FEM) analysis of a load case based on an existing high-speed PSC Girder Box railroad bridge structure. The FEM analysis results were used to calculate the minimum joint displacement range to be applied during testing (approximately 1.5 mm). For the evaluation, four commonly used waterproofing membrane types, cementitious slurry coating (CSC), polyurethane coating system (PCS), self-adhesive asphalt sheet (SAS), and composite asphalt sheet (CAS), were tested, with five specimens of each membrane type. The joint displacement width range conditions, including the minimum displacement range obtained from FEM analysis, were set to be the incrementing interval, from 1.5, 3.0, 4.5, and 6.0 mm. The proposal for the evaluation criteria and the specimen test results demonstrated how the evaluation method is important for the sustainability of high-speed railway bridges.

Study on The Effect of Electrode Drying Temperature on The Silicon Electrode Characteristics of Lithium Secondary Batteries (전극 건조 온도가 리튬이차전지의 실리콘 전극 특성에 미치는 영향 연구)

  • Dong-Wan Ham;Myeong-Hui Jeong;Jeong-Tae Kim;Beom-Hui Lee;Hyeon-Mo Moon;Sun-Yul Ryou
    • Journal of the Korean Electrochemical Society
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    • v.27 no.3
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    • pp.97-104
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    • 2024
  • The electrodes of commercialized lithium secondary batteries are manufactured through a wet coating process, and the drying process (DC) is a very important factor as to electrode production speed and process cost. In this study, silicon anodes were manufactured under high-temperature (180 ℃) and low-temperature (50 ℃) DC to investigate the quality and the electrochemical performance of Si-electrodes according to DC. High-temperature DC can quickly evaporate the solvent in the Si-electrode slurry, improving the electrode production rate. However, this also causes the electrode composite to peel off from the current collector. As a result, the Si-electrode's adhesion weakened, and the electrode coating's quality deteriorated. In addition, the Si-electrode manufactured under high-temperature was found to have a thicker composite material than the Si-electrode manufactured under low-temperature. Si-electrodes manufactured under high-temperature had higher sheet resistance and lower electrical conductivity than those manufactured under low-temperature. Consequently, the Si-electrode manufactured under low-temperature showed 152.5% superior cycle performance compared to the Si-electrode manufactured under high-temperature. (Discharge capacities of Si-electrodes manufactured under high-temperature and low-temperature DC were 844 and 1287 mAh g-1, respectively, after 300 cycles). Establishing the DC of Si-electrodes can easily provide new perspectives to improve the quality and stability of Si-electrodes.

Silver Coating on the Porous Pellets from Porphyry Rock and Application to an Antibacterial Media (반암(맥반석)으로 제조한 다공성 펠렛의 Ag 담지 및 항균 메디아로서의 적용)

  • Han, Yo-Sep;Kim, Hyun-Jung;Shin, Young-Seop;Park, Jai-Koo;Ko, Jae-Churl
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.16-23
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    • 2009
  • The porous pellets were prepared from porphyry by slurry foaming method. The effect of sintering temperatures on pore structure of porous porphyry pellets with different extension ratio ($E_R$) was investigated by specific surface area, water absorption and porosity, which changed with sintering temperatures. When the sintering temperatures increased from $975^{\circ}C$ to $1075^{\circ}C$, specific surface area and water absorption of the all samples decreased. In case of the sample with an equal sintering temperature, $E_R=3.0$ pellets had little influence on pore structure compared to the $E_R=2.0$ pellets. As a results, it was shown by SEM that facilitated formation of micro pores at $E_R=2.0$ pellets shrunk increasingly after sintering process. At $E_R=3.0$ and sintering temperature at $1025^{\circ}C$, optimum conditions of the porous porphyry porous pellets was found. Also, Escherichia coli removal efficiency of the silver-containing porphoyry porous pellets was measured for the feasibility as a antibacterial media. The antibacterial activity of prepared silver-containing sample was maintained above 90% for 40 days.

Characterization of Ag Nanowire Transparent Electrode Fabricated on PVDF Film (PVDF 필름 위에 제작된 고전도도 Ag 나노와이어 투명전극 특성 연구)

  • Ra, Yong-Ho;Park, Hyelim;An, Soyeon;Kim, Jin-Ho;Jeon, Dae-Woo;Kim, SunWoog;Lee, Mijai;Hwang, Jonghee;Lim, Tae Young;Lee, YoungJin
    • Journal of Sensor Science and Technology
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    • v.28 no.6
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    • pp.366-370
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    • 2019
  • In this study, we have successfully fabricated a highly conductive transparent electrode using Ag nanowires, based on piezoelectric polyvinylidene difluoride (PVDF) film, that can be applied as transparent and flexible speakers. The structural morphology of the Ag nanowires was confirmed by a detailed scanning electron microscopy. Ultraviolet-visible spectroscopy demonstrated that the transparent electrode fabricated by the Ag nanowires exhibited a transmittance of above 70%. The transparent electrode also showed very low sheet resistance with high flexibility. We have further developed an anti-oxidation coating layer by using a tetraethyl orthosilicate-poly trimethyloxyphenylsilane (TEOS-PTMS) slurry technique. It was confirmed that the transmittance and sheet resistance of the antioxidant film depends critically on the humidity of the film surface. We believe such Ag nanowire electrodes are a very promising next-generation transparent electrode technology that can be used in future flexible and transparent devices.

Photocatalytic Cell Disruption of Giardia lamblia in a $UV/TiO_2$ Immobilized Optical-Fiber Reactor

  • YU , MI-JIN;KIM, BYUNG-WOO
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1105-1113
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    • 2004
  • Disinfection of a waterborne pathogenic protozoa, Giardia lamblia, by the conventional chlorine method has been known to be difficult. An alternative disinfection has been carried out by using a UV -light illuminating optical­fiber photoreactor. Light intensity diffused from one piece of a clad-removed optical-fiber was $1- 1.5{\mu}Em^{-2}s^{-1}$. Disinfection capability in a UV -light irradiated optical-fiber reactor suspended with 0.01 g $TiO_{2}\;dm^{-3}$ was 1.4 times that in the same reactor without $TiO_{2}$ photocatalysts. To resolve the absorption and scattering of UV light by the particles themselves as well as the difficulty of recycling particles in the slurry­type reactor, $TiO_{2}$ which was obtained by a hydrothermal method, was immobilized on clad-removed optical fibers. Such pretreatment of fiber surface resulted in an excellent transparency, which enhanced the UV light to diffuse laterally from a fiber surface. Coating time of the prepared solution by the hydrothermal method was not effective after more than two times. Disinfection capability in the $TiO_{2}$-immobilized optical-fiber reactor was $83\%$ in 1 h at $40^{\circ}C$, which was slightly higher than $76\%$ at $22^{\circ}C$ and $68\%$ at $10^{\circ}C$. Disinfection capability at $22^{\circ}C$ increased from $74\%$ at an initial pH of 3.4, through $76\%$ at pH 6.5, to $87\%$ at an initial pH of 10. Oxygen supply with air-flow rate of 5 $cm^3\;min^{-1}$ did not seem to increase the disinfection capability with UV /immobilized $TiO_2$.

Decolorization of a Rhodamine B Using Photoelectrocatalytic and Electrolytic/UV Process (광전기촉매 공정과 전기/UV 공정을 이용한 Rhodamine B의 색 제거)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.17 no.9
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    • pp.1023-1032
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    • 2008
  • The feasibility study of the application of the photoelectrocatalytic and electrolytic/UV decolorization of Rhodamine B (RhB) was investigated in the photoelectrocatalytic and electrolytic/UV process with $TiO_2$ photoelectrode and DSA (dimensionally stable anode) electrode. Three types of $TiO_2$ photoelectrode were used. Thermal oxidation electrode (Th-$TiO_2$) was made by oxidation of titanium metal sheet; sol-gel electrode (5G-$TiO_2$) and powder electrode (P-$TiO_2$) were made by coating and then heating a layer of titania sol-gel and slurry $TiO_2$ on titanium sheet. DSA electrodes were Ti and Ru/Ti electrode. The relative performance for RhB decolorization of each of the photoelecoodes and DSA electrodes is: Ru/Ti > Ti > SG-$TiO_2$ > Th-$TiO_2$. It was observed that photoelectrocatalytic decolorization of RhB is similar to the sum of the photocatalytic and electrolytic decolorization. Therefore the synergetic effect was not showed in pthotoelectrocatalytic reaction. $Na_{2}SO_{4}$ and NaCl showed different decolorization effect between pthotoelectrocatalytic and electrolytic/UV reaction. In the presence of the NaCl, RhB decolorization of Ru/Ti DSA electrode was higher than that of the other photoelectrode and Ti electrode. Optimum current, NaCl dosage and UV lamp power of the electrolytic/UV process (using Ru/Ti electrode) were 0.75 A, 0.5 g/L and 16 W, respectively.

Development of Investment Casting Technique using R/P Master Model (R/P 마스터모델을 활용한 정밀주조 공정기술의 개발)

  • Im, Yong-Gwan;Chung, Sung-Il;Jeong, Hae-Do
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.6
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    • pp.52-57
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    • 1999
  • Funtional metal prototypes are often required in numerous industrial applications. These components are typically needed in the early stage of a project to determine form, fit and function. Recent R/P(Rapid Prototyping) part are made of soft materials such as plastics, wax, paper, these master models cannot be employed durable test in real harsh working environment. Parts by direct metal rapid tooling method, such as laser sintering, by now are hard to get net shape, pores of the green parts of powder casting method must be infiltrated to get proper strength as tool, and new type of 3D direct tooling system combining fabrication welding arc and cutting process is reported by song etc. But a system which can build directly 3D parts of high performance functional material as metal part would need long period of system development, massive investment and other serious obstacles, such as patent. In this paper, through the rapid tooling process as silicon rubber molding using R/P master model, and fabricate wax pattern in that silicon rubber mold using vacuum casting method, then we tranlsated the wax patterns to numerous metal prototypes by new investment casting process combined conventional investment casting with rapid pototyping & rapid tooling process. with this wax-injection-mold-free investment casting, we developed new investment casting process of fabricating numerous functional metal prototypes from one master model, combined 3-D CAD, R/P and conventional investment casting and tried to expect net shape measuring total dimension shrinkage from R/P part to metal part.

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The contamination prevention of diamond conditioner by anti-contamination film coating (오염방지막 코팅을 통한 Diamond Conditioner의 표면오염 방지)

  • Son, Il-Ryong;Kang, Young-Jae;Kim, In-Kwon;Kim, In-Gon;Jeon, Jeong-Bin;Kim, Tae-Jin;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.114-114
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    • 2008
  • 반도체 device의 성능을 향상시키기 위하여 패턴은 더욱 더 고 집적화 되고 배선 또한 다층배선 구조를 가지게 되었으며 요구되는 선폭 또한 더욱 미세화 되어 CMP 공정이 도입되게 되었다. 이러한 CMP 공정에 사용되는 소모품으로는 크게 세 가지의 중요한 부분으로 나눌 수 있다. 그것은 slurry와 pad, conditioner이다. 그중에 pad conditioning 공정은 CMP 공정시 pad의 마모에 따라 감소하는 removal rate(RR)값을 회복시키기 위한 공정으로 마모된 pad의 표면을 활성화 시켜주는 중요한 공정이다. 하지만 pad conditioning 공정을 장시간 진행하게 되면 conditioner 표면에 오염물이 발생하게 되며, 오염물로 인하여 wafer표면에 scratch 및 defect을 발생시키는 원인이 될 수 있다. 이러한 문제점을 보완하기 위하여 conditioner의 표면을 변화시켜 공정중의 오염이 발생하지 않도록 하는 것이 중요하다. 본 논문에서는 oxide CMP 실험을 통하여 conditioner표면에 오염물이 발생함을 확인하였으며 energy dispersive spectroscopy(EDS) 분석을 통하여 주오염물의 성분이 oxide slurry중 silica임을 확인하였다. Conditioner의 표면을 소수성으로 만들기 위하여 self assembled monolayer(SAM) 방법을 이용하여 표면에 코팅을 하였으며, 소수성 박막이 코팅된 conditioner와 코팅되지 않은 conditioner의 비교 실험을 통하여 오염 정도를 비교하였다.

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The Effects of Surface Insulation Layer on the Magnetic Properties of Nanocrystalline Alloy Ribbons (표면 절연층이 나노결정립 합금 리본의 자기적 특성에 미치는 영향)

  • Oh, Young-Woo
    • Journal of the Korean Magnetics Society
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    • v.17 no.6
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    • pp.226-231
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    • 2007
  • High frequency loss property of nanocrystalline amorphous ribbon with a high resistivity insulation layer of $TiO_2$ and $SiO_2$ was studied. The insulation layer was fabricated by sol-gel method using dip-coating. The optimum composition ratio of metal alkoxide and slurry for fabrication of insulation layer was established and insulation layer with high adhesion was coated on the nanocrystalline amorphous ribbon. Frequency loss of magnetic core material manufactured on nanocrystalline amorphous ribbon with the surface insulation layer decreased over 40 % compared with that of magnetic core material without surface insulation layer. The insertion loss of an inductive coupler, which was prepared by using magnetic core material coated insulation layer, decreased due to reduction of frequency loss for magnetic core material and insertion loss decreased in proportion to frequency.

Optimization for Ammonia Decomposition over Ruthenium Alumina Catalyst Coated on Metallic Monolith Using Response Surface Methodology (반응표면분석법을 이용한 루테늄 알루미나 메탈모노리스 코팅촉매의 암모니아 분해 최적화)

  • Choi, Jae Hyung;Lee, Sung-Chan;Lee, Junhyeok;Kim, Gyeong-Min;Lim, Dong-Ha
    • Clean Technology
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    • v.28 no.3
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    • pp.218-226
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    • 2022
  • As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO2) emissions are being focused on. Among them, ammonia (NH3) is an economical hydrogen carrier that can easily produce hydrogen (H2). In this study, Ru/Al2O3 catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al2O3 catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R2) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.