• Journal of Korean Society on Water Environment
• /
• v.32 no.3
• /
• pp.303-309
• /
• 2016

This study aimed to assay the biological removal of TDS (total dissolved solids) from RO (reverse osmosis) rejected water. Following bio-sorption of TDS with AGS (aerobic granular sludge), the effects of TDS on biological nitrogen removal were examined. The bio-sorption of TDS after AGS treatment was confirmed by checking for TDS removal efficiency and surface analysis of microorganisms with SEM and EDS. Then, the effects of TDS on biological nitrogen removal and the denitrification efficiency were evaluated using the MBR reactor. According to the results, the bio-sorption of TDS with AGS was 0.1 mg TDS/mg AGS, and we confirmed that the microorganism surfaces had adsorbed the TDS. Biological nitrogen removal efficiency was measured at inhibiting denitrification at 4,000 mg/L of TDS-injected material. Based on this study, it is necessary to pretreat TDS-containing RO rejected water and to maintain TDS concentration lower than a specific value (≤4,000 mg/L), when considering biological nitrogen removal.

• Journal of Microbiology and Biotechnology
• /
• v.12 no.5
• /
• pp.849-853
• /
• 2002

Metal ions have an adverse effect on anaerobic digestion. In an acetate degradation test of upflow of anaerobic sludge blanket granules with $Cu^{2+}$, not all of the acetate that disappeared was stoichiometrically converted to methane. In the presence of 400 mg/g-VSS (volatile suspended solids) $Cu^{2+}$, only 26% of the acetate consumed was converted to methane. To study acetate conversion by other anaerobic microorganisms, sulfate and nitrate reductions were investigated in the presence of $Cu^{2+}$ Sulfate and nitrate reductions exhibited more resistance to $Cu^{2+}$than methanogenesis, and the granules reduced 2.2 mM and 5.4 mM of nitrate and sulfate, respectively, in the presence of 400 mg/g-VSS copper ion. However, the acetate degraded by sulfate and nitrate reductions was only 24% of the missing acetate that could have been stoichiometrically converted to $CO_2$. Accordingly, 76% of the acetate consumed appeared to have been converted to other unknown compounds.

• Journal of Korean Society of Water and Wastewater
• /
• v.27 no.6
• /
• pp.815-826
• /
• 2013

Using a developed mathematical model and calibrated kinetic constants, numerical experiments for a aerobic digestion of wastewater sludge by SBR aerobic digestion process combined with ultrasonication (USSBR) were performed in this study. It simulated well the phenomena of the decomposition of particulate organics and the release of organic nitrogen and transformation. To achieve 40 % of particulate organics removal, USSBR process requires only 6 days of SRT and 14 W/L of ultrasonic power whereas SBR aerobic digestion process requires 12 days of SRT. Based on the model simulation results, an empirical equation was presented here. This equation will be used to predict digestion efficiency for the given variables of SRT and ultrasonic power dose. USSBR aerobic digestion process can reduce the nitrogen concentration. The optimal operation strategy for the simultaneous removal of solids and soluble nitrogen in this process is estimated to 7 days of SRT with 14 W/L of ultrasonic power dose while anoxic period was 6 hours out of 24 hours of cycle time. In this condition, 40 % of particulate organics as well as 36 % of total nitrogen will be removed and the soluble nitrogen concentration of the centrate will be lower less then 40 mg/L.

• Environmental Engineering Research
• /
• v.9 no.5
• /
• pp.238-247
• /
• 2004

The objective of this study was to develop kinetic model for the MBR and investigate kinetic characteristics of the gravitational flow transverse direction MBR system. Kinetic model was derived by mass balance of substratc and biomass combined with empirical membranc filtration rerm for the MBR. To find kinctic values, permeale flux and COD removal were analyzed through the laboratory, MBR operation as different solids retention times. Permeate flux was ranged 2.5-5.0 LMH (L/m$^2$/hr) as sludge characteristics in each run. Although the soluble COD in the bioreactor was changed, the effluent COD was stable as average 99% removal rate during the experimental periods. Y$_g$ of this MBR system was higher than those of cross-flow MBR processes. The kinetics of this MBR showed that smaller k, larger b, and larger K$_s$ values than the conventional activated sludge process. These results indicated that substrate was used for cell maintenance rather than growth in this MBR system.

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.8
• /
• pp.561-569
• /
• 2014

This study was carried out to get the characteristics of anaerobic digestion for chemical/biological sludge produced from municipal sewage treatment plant for phosphorus. Anaerobic mesophilic batch tests showed that the ultimate biodegradability of waste activated sludge showed 31%, PACl sludge 24%, Alum sludge 26%, respectively. At the S/I 1.0, 75% of total biodegradable volatile solids (TBVS) of waste activated sludge was degraded with an initial rapid decay coefficient, k1 of $0.1129day^{-1}$ and 74% of TBVS of PACl sludge with k1 of $0.0998day^{-1}$, and 76% of TBVS of Alum sludge with k1 of $0.1091day^{-1}$ for 20 days. During the operation of SCFMRs, the 3 reactor (Control, PACl, Alum) pH maintained 6.7~7.0 and the reactor alkalinity maintained 1,800~ 2,200 mg/L as $CaCO_3$. The average biogas production rates of SCFMRs fed with PACl sludge and Alum sludge were 0.089 v/v-d and 0.091 v/v-d, respectively, which was 27~28% lower than that of the control (0.124 v/v-d) at an HRT (hydraulic retention times) of 20 days. And the methane content during the operation ranged 70~76% in 3 reactor. The average TVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 19.6% and 19.9%, respectively, at an HRT of 20 days, which showed 4% lower than that of the control (23.8%). The average BVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 25.8% and 26.9%, respectively, at an HRT of 20 days, which was 8~9% lower than that of the control (34.5%).

• Applied Chemistry for Engineering
• /
• v.17 no.5
• /
• pp.521-526
• /
• 2006

A membrane bioreactor (MBR) is an effective tool for wastewater treatment with recycling. MBR process has several advantages over conventional activated sludge process (ASP); reliability, compactness, and quality of treated water. The resulting high-quality and disinfected effluents suggest that MBR process can be suitable for the reused and recycling of wastewater. An anoxic/oxic (A/O) type MBR was applied to simultaneous removal of organics and nutrients in sewage. At first, the efficiency of submerged MBR process was investigated using a hollow fiber microfiltration membrane with a constant flux of $10.2L/m^2{\cdot}h$ at each solids retention time (SRT). Results showed that protein/carbohydrate (P/C) ratio increased and total extracellular polymeric substances (EPS) remained constant with SRT increased. Secondly, A/O type MBR with a reverse osmosis (RO) membrane was employed to treat the municipal wastewater. The performance of A/O type MBR-RO process is better for the treatment of organics and nutrients than ASP-MF-RO process in terms of consistent effluents quality.

• Korean Journal of Environmental Biology
• /
• v.17 no.2
• /
• pp.183-190
• /
• 1999

The bioleaching of heavy metals from fly ash was performed by Thiobacillus thiooxidans MET isolated from the enrichment culture of an anaerobically digested sludge. The effect of solid concentrations on the efficiency of metal leaching was studied in shaken flasks. In the range of solid concentrations 20 g.L­$^1$to 100 g.L­$^1$T. thiooxidans MET oxidized S$^{0}$ to sulfate without any lag period. The final pH of slurry solution was decreased to below pH 1, and the final oxide-redox potential (ORP) was increased to over 420 mV in the solid concentrations below 100 g.L­$^1$. However, the initial lag period of 4 to 8 days was required to obtain the pH reduction and ORP increase of the slurry solutions in the range of solid concentrations 150 g.L­$^1$to 300 g.L­$^1$. The sulfur oxidation rate of T. thiooxidans MET in 20~100 g.L­$^1$solid concentrations was 0.70~0.75 g-S.L­$^1$ㆍ d­$^1$, but its sulfur oxidation activity was remarkably inhibited with increasing solid concentration over 150 g.L­$^1$. Increasing fly ash solids concentration in the range of solids concentration 20 g.L­$^1$ to 200 g.L­$^1$decreased the removal efficiency of Zn, Cu, Mn, Cr and Pb. The solubilization of heavy metals from fly ash was strongly correlated with the pH value of slurry solution. When the pH of slurry solution was reduced to 3, the solubilization process of Zn, Cu and Mn started, and their solubilization efficiency of Zn, Cu and Mn was progressively increased below pH 2. However, the solubilization process of Cr and Pb started at pH 2.5 and 2.0, respectively.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.27 no.2
• /
• pp.13-18
• /
• 2019

Sewage sludge treatment is increasing every year due to improvement of living and urbanization. However, interest in anaerobic digestion which is one of the recycling technology. There is anaerobic digestion of increasing due to limitations of ocean dumping and final disposal. But, the limit of anaerobic digestion efficiency due to the advanced treatment of sewage has been limited, and studies for solubilization technology have been actively conducted. Therefore, in this study, we aimed to investigate the variation of generation of scum and the solubilization efficiency in the application of pre-treatment of ozone reaction and the change of properties of digested sludge with wet milling. There are results of VS/TS increased by 4.4% and $SCOD_{cr}/TCOD_{cr}$ increased by 9.4% by wet milling alone. In addition, the increase of the specific surface area due to which the reduction of the particle size of the solid content of the sludge in the ozone reaction caused by wet milling decreased the generation rate of scum at 14.3% and increased VS/TS at 2.1%, compared with the ozone reaction alone. From these results, it is expected that the application of wet milling can be increased the contact efficiency with solids in the sludge during ozone reaction with suppress scum and increase the efficiency of the subsequent process in anaerobic digestion.

• Journal of Korean Society on Water Environment
• /
• v.16 no.4
• /
• pp.501-512
• /
• 2000

This study was carried out to develop the new process for RBC process which is capable of nutrient removal and to obtain its design parameters for Sludge Settling Type Rotating Biological Contactors by comparing RBC with RBC combined with HBR (Hanmee Bio-Reactor). To achieve more than 90% of organic removal efficiency, organic loading rate less than $6.0g\;BOD/m^2/d$ is recommended. Nitrification rate was about 90% at $6.0g\;BOD/m^2/d$. TN removal efficiency of RBC+HBR was higher than those of RBC1 and RBC2. TN removal efficiency at condition of $5.0g\;BOD/m^2/d$ was about 60% in RBC1. When BOD loading rate was $6.0g\;BOD/m^2/d$. TN removal efficiencies in RBC2 and RBC+HBR were about 70%, 80%, respectively. TP removal efficiency was more than about 67% for RBC1, about 63% for RBC2 and about 71 % for RBC+HBR at the same loading rate. From the blank experiment to observe removal efficiency in the first stage, it can be known that COD removal efficiency was about 30% and suspend solids settling rate was about 45%. It was proved that RBC+HBR is much better in sludge dewatering than RBC.

• Proceedings of the Korean Institute of Intelligent Systems Conference
• /
• 2000.11a
• /
• pp.452-455
• /
• 2000

There are increasingly important financial incentives and environmental consideration to improve the effluent quality of wastewater from domestic and industrial users. The activated sludge process is a widely used biological wastewater treatment process. The activated sludge process is complicated due to the many factors such as the variation of influent flowrate and concentration, the complexity of biological reactions and the various operation conditions. Nowadays, not only suspended solids and residual carbon, but also nitrogen and phosphorous concentration of the effluent water must be taken into account for the design and operation of wastewater treatment plants. Also, the effluent quality to be met are more stringent. Therefore, an intelligent control approach is required in order to successful biological nitrogen removal. In this paper, the strategies for dosage of extra carbon in the anoxic zone and DO concentration in the aerobic zone are presented and evaluated through the simulation using the denitrification layout of the IWA simulation benchmark implemented by Matlab$\^$/5.3/Simulink$\^$/3.0. The control strategy to achieve sufficient denitrification rates in an anoxic zone. Methanol is used as an external extra carbon source. The external extra carbon source is required for the nitrogen removal process because nitrogen and organic concentration are fluctuated in the influent flowrate. The dissolved oxygen is calculated by So concentration in the activated sludge model NO.1. The air flowrate of each aerobic reactor is intelligently controlled to achieve the predefined setpoints. Air flowrate is adjusted by the fuzzy logic controller that includes two inputs and one output. The objective function for the optimization procedure is designed to improve effluent quality and reduce the operating cost.