• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.128-135
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• 2006

Steel slag (divided into electric arc furnace slag and convener slag) is being produced by millions of tons per every year in many industrial countries. About 6.5 million tonnes of steel slag is produced yearly as an industrial by-product in Korea. Generally natural aggregate is relatively stable and does not enter into complex chemical reactions with water. Unfortunately, however. steel slag aggregate contains a small amount of free lime. The hydration of free lime makes steel slag aggregate unstable and liable to expand. In this paper, firstly, several aging methods are used in order to decrease the volume expansion of electric arc furnace slag, that is stabilization. The volume expansion of electric arc furnace slag is formulated from the experiment. From the formula, the residual expansibility is predicted with immersion expansion. Compressive strength of concrete with electric arc furnace slag has relation with the residual expansibility in slag aggregate.

• Journal of Korean Society on Water Environment
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• v.28 no.2
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• pp.277-284
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• 2012

This study developed a new ceramics in which natural zeolite was mixed and calcined with industrial by-product such as converter slag, red mud, and fly ash and evaluated the feasibility of the ceramics for removal of heavy metals in acid wastewater. The removal rate of heavy metal by ceramics increased in the order of ZS (zeolite and slag) > ZR (zeolite and red mud) > ZF (zeolite and fly ash) ceramics. The alkalinity increment and coherence of ceramics were increased in the order of ZS > ZR > ZF ceramics. The mixing ratio of natural zeolite to industrial by-product for maximum removal efficiency of heavy metal was 1:1 for ZS ceramics and 1:3 for ZR and ZF ceramics. The order of removal efficiency of heavy metal was observed to be ZS > ZR > ZF ceramics under the mixing ratio of 1:1 for ZS ceramics and 1:3 for ZR and ZF ceramics. The removal efficiency of heavy metal by ZS ceramics with 1:1 mixing ratio was Al 100%, Cd 54.6%, Cr 99.9%, Cu 98.7%, Fe 99.9%, Mn 42.2%, Ni 59.9%, Pb 99.8%, Zn 87.6%, respectively. In addition, the removal capacity of heavy metal by ZS ceramics was observed to be Al 2.01 mM/g, Cd 0.27 mM/g, Cr 1.02 mM/g, Cu 0.83 mM/g, Fe 0.95 mM/g, Mn 0.41 mM/g, Ni 0.55 mM/g, Pb 0.25 mM/g, Zn 0.70 mM/g, respectively. The comparative evaluation in the light of removal capacity, alkalinity increment, and coherence of ceramics showed the ZS ceramics had higher feasibility as a media than others for removal of heavy metals in acid wastewater.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.93-94
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• 2018

This study investigated the compressive strength and drying shrinkage properties of mortar using ferronickel slag powder by the kinds of industrial by-product to estimate the applicability of ferronickel slag powder for cement replacement materials.

• Journal of Soil and Groundwater Environment
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• v.21 no.2
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• pp.1-7
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• 2016

Ferrous slag is a by-product from steel making process and waste concrete is generated from construction activities. Large part of ferrous slag and waste concrete are recycled as construction materials. However, Ca²⁺ leaching out of ferrous slag and waste concrete in the water-contacting environment can cause a strength change. Strength can be reduced due to the dissolution of solid form of CaO which is one of the main contents of ferrous slag and waste concrete. On the other hand, strength can be enhanced due to the pozzolanic reaction of cementitious components with water. In this study, steelmaking slag, blast furnace slag, and waste concrete were aged by exposure to raining events, and the change of their compaction and shear strength characteristics was investigated. Optimum moisture content of all materials used in this study increased with aging period while maximum dry unit weight slightly decreased, implying that the relative contents of fine particles increased as the CaO solid particles were dissolved. Internal friction angle and shear strength of recycled materials also increased with aging period, indicating that the materials became denser by the decrease of void ratio attributed to the fine particles generated during the weathering process and the development of cementitious compounds increasing the bonding and interlocking forces between the particles. The results of this study demonstrated that mechanical strength of recycled materials used as construction materials has little chance to be deteriorated during their service life.

• Computers and Concrete
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• v.31 no.4
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• pp.327-335
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• 2023

The most popular building material, concrete, is intrinsically linked to the advancement of humanity. Due to the ever-increasing complexity of cementitious systems, concrete formulation for desired qualities remains a difficult undertaking despite conceptual and methodological advancement in the field of concrete science. Recognising the significant pollution caused by the traditional cement industry, construction of civil engineering structures has been carried out successfully using Geopolymer Concrete (GPC), also known as High Performance Concrete (HPC). These are concretes formed by the reaction of inorganic materials with a high content of Silicon and Aluminium (Pozzolans) with alkalis to achieve cementitious properties. These supplementary cementitious materials include Ground Granulated Blast Furnace Slag (GGBFS), a waste material generated in the steel manufacturing industry; Fly Ash, which is a fine waste product produced by coal-fired power stations and Silica Fume, a by-product of producing silicon metal or ferrosilicon alloys. This result demonstrated that GPC/HPC can be utilised as a substitute for traditional Portland cement-based concrete, resulting in improvements in concrete properties in addition to environmental and economic benefits. This study explores utilising experimental data to train artificial neural networks, which are then used to determine the effect of supplementary cementitious material replacement, namely fly ash, Ground Granulated Blast Furnace Slag (GGBFS) and silica fume, on the compressive strength, tensile strength, and modulus of elasticity of concrete and to predict these values accordingly.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.526-531
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• 2001

LD slag, that is, a by-product of steel making process, has been mainly used as land construction materials. Recently, the seashore application of LD slag was tried in Japan and Korea tut the reaction between LD slag and seawater was not studied yet. We tried to clarify the leaching reaction and/or mechanism of LD slag and the reaction between seawater and LD slag. We tried to apply these results to the decarbonization of seawater for seawater magnesia process. At first, LD slag was milled and classified into 5 grades, that is, (ⅰ)45${\mu}{\textrm}{m}$ under, (ⅱ)0.25~0.5mm (ⅲ)0.5~1mm(ⅳ)1~2mm, (ⅴ)2.36~3.35mm. These slags were leached in the distilled water. In case of 45${\mu}{\textrm}{m}$ under, the pH of the leached solution was over 12. The chemical analysis of leached solution showed that the $Ca^{+}$$^2$was main component and the S $i^{+}$$^4$was very low. On the other hand, the content of S $i^{+}$$^4$in leached solution was decreased with the increase of pH of this solution. The nearly pure calcium solution was made and the ultra high purity MgO could be made with this calcium solution. The leaching behavior of LD slag was different between the fine particle and coarse particle. The calcium was leached by bulk dissolution in the coarse particle and by surface controlled reaction in fine particle. The leaching rate was slow in coarse particle and fast in fine particle. Therefore, the high pH solution, that is, over 12, was obtained in fine particle.cle.e.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.477-482
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• 2007

The effect of the mixing ratio of compounds in a slag-OPC-Gypsum system on the physical properties of Slag cement is investigated in this study. $Na_2SO_4$ was used as an alkali activator. Blast furnace slag cement was prepared from a mixture of blast furnace slag, ordinary Portland cement and anhydride gypsum. The fluidity and the compressive strength according to the ratio of each mixture were analyzed in statistical analyses in order to discover the parameters influencing the fluidity and compressive strength. The results showed that the hydration of blast furnace slag took place with the addition of $Na_2SO_4$ and that column-crystalline ettringite was created as the main hydration product of the blast furnace slag. In addition, it was found that the compressive strength of blast furnace slag cement tends to increase when the ordinary Portland cement content is higher up to three days. However, it is known that the compressive strength tends to increase as the blast furnace slag content becomes higher with increases in the level of OPC after 28 days. As a result of this analysis, it is believed that the ordinary Portland cement content influences the initial compressive strength of blast furnace slag cement, and that in later days this is highly influenced by the slag content.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.364-371
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• 2015

For the cost down of polymer concrete, It is very important to reduce the use amount of polymer binder, which occupies most of the production cost of polymer concrete. Fly ash and atomizing reduction steel slag are spherical materials obtained from industrial by-products. Spherical atomizing reduction steel slag was manufactured using steel slag from reduction process of ladle furnace by atomizing technology. To investigate the physical properties of polymer concrete, polymer concrete specimens were prepared with the various proportions of polymer binder and replacement ratios of atomizing steel slag. Results showed that compressive and flexural strengths of the specimens were remarkably increased with the addition amount of polymer binder and the replacement ratios of atomizing steel slag. In the hot water resistance test, compressive strength, flexural strength, bulk density and average pore diameter decreased but total pore volume and pore diameter increased. We found that polymer concrete developed in this study reduced the amount of polymer binder by 18.2% compared to the conventional product because of the remarkable improvement of workability of polymer concrete using spherical fly ash and atomizing reduction steel slag instead of calcium carbonate (filler) and river sand (fine aggregate).

• Korean Journal of Materials Research
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• v.26 no.5
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• pp.266-270
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• 2016

Glass-ceramics were developed many years ago and have been applied in many fields such as electronics, chemistry, optics, etc. Much is already known about glass-ceramic technology, but many challenges in glass-ceramic research are still unresolved. Recently, large amounts of slag have steadily increased in the steel industry as by-products. To promote recycling of industrial waste, including steel industry slags, many studies have been performed on the fabrication of basalt-based high-strength glass-ceramics. In this study, we have fabricated such ceramics using various slags to replace high performance cast-basalt, which is currently imported. Glass-ceramic material was prepared in similar chemical compositions with commercial cast-basalt through a pyro process using slags and power plant by-product (Fe-Ni slag, converter slag, dephosphorization slag, Fly ash). The properties of the glass-ceramic material were characterized using DTA, XRD, and FE-SEM; measurements of compressive strength, Vicker's hardness, and abrasion were carefully performed. It is found that the prepared glass-ceramic material showed better performance than that of commercial cast-basalt.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.319-324
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• 2001

Recently new practical use way of industry product is required. In this study, to find flowing property of slump, unit weight, the air amount, compressive strength etc. Compressive strength 240, 270kgf/$cm^{2}$, slump 8$\pm$2.5(I), 152$\pm$.5(II)cm, mixing ratio of copper smelting slag decided by 0, 25, 50, 75, 100% gradually, The result of this study was follows ; 1. Unit weight increased 2.2%~4.4% according as mixing ratio of copper smelting slag increases. 2. Slump increased about 2~5% as the mixing ratio increased gradually 3. Compressive strength was increased about 4~28% in copper smelting slag mixing ratio 25~50% and 8~20% decreased more than mixing ratio 75%.