• 분석과학
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• 제5권2호
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• pp.223-228
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• 1992

초산염(acetate)을 출발원료로 하여 $Bi_2Sr_2Ca_2Cu_3Oy$계 단일상 고온초전도체를 합성하려 하였으며 그 초전도상의 형성과정을 초전도전이온도 $T_c$ 및 전하나르게 농도와의 상관관계로부터 설명하고자 하였다. 초전도전이온도 $T_c$는 전기저항밀도 및 자화율을 측정하여 결정하였다. 시료로는 상기의 초전도체 출발조성물의 하소분말에 대해 $850^{\circ}C$, $860^{\circ}C$, 그리고 $870^{\circ}C$에서 40시간 동안 공기 중 열처리한 것을 이용하였다. 전하나르게농도는 홀계수를 측정하여 구하였다. 열처리과정 중의 초전도체 형성과정을 세라믹벌크내에 형성된 초전도체의 양 및 전하나르게농도 분포의 상관관계로부터 설명하였다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.269-271
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• 2009

We investigated on the sintering behaviors and electrical properties of photo-sensitive aluminum (Al) electrode materials in plasma display panels. General characteristics of Al electrodes was totally different to that of conventional Ag materials; resistivity was decreased with the increasing of metal particle sizes and the amount of frit content and there is almost no width difference between developed and fired electrodes layers. Microstructures of fired electrodes revealed that Al electrodes had different mechanism on necking between metal particles and making electrical conducting path. Chemical durability (especially, antialkalinity) and adhesion of Al electrodes must be carefully controlled. Nevertheless there are difficulties of processing Al electrodes, we developed and optimized photo-sensitive Al materials as address electrodes without any changes of existing patterning equipment and sintering conditions.

• 한국표면공학회지
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• 제50권5호
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• pp.301-307
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• 2017

The purpose of this study is to investigate the electrical properties of thick-film resistor (TFR) prepared from $CaO-ZnO-B_2O_3-Al_2O_3-SiO_2$ (CZBAS) glass containing $RuO_2$ particles. $RuO_2$-glass composite powder was made by mixing and melting oxide powders of constituents. For comparison, $RuO_2$ powder was simply mixed with glass powder. $RuO_2$-40wt% glass composite and mixture were dispersed in an organic binder to obtain printable resistor paste and then thick-film was formed by screen printing, followed by sintering at the range between $750^{\circ}C$ and $900^{\circ}C$ for 10 min with a heating rate of $50^{\circ}C/min$ in an ambient atmosphere. $RuO_2$-glass composite sample showed much higher resistance compared to the simple mixed sample. This could be attributed to the difference in conducting mechanism. After sintering at $850^{\circ}C$, temperature coefficient of resistance of composite sample was lower than that of simple-mixed sample. TFR with dense and homogeneous microstructure could be obtained by using $RuO_2$-glass composite powder.

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1832-1836
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• 2014

A deep understanding of the metallic silver catalysts formation process on oxide support and the formation mechanism is of great scientific and practical meaning for exploring better catalyst preparing procedures. Herein the thermal decomposition process of supported silver catalyst with silver oxalate as the silver precursor in the presence of ethylenediamine and ethanolamine is carefully investigated by employing a variety of characterization techniques including thermal analysis, in situ diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy, and X-ray diffraction. The formation mechanism of supported silver particles was revealed. Results showed that formation of metallic silver begins at about $100^{\circ}C$ and activation process is essentially complete below $145^{\circ}C$. Formation of silver was accompanied by decomposition of oxalate group and removal of organic amines. Catalytic performance tests using the epoxidation of ethylene as a probe reaction showed that rapid activation (for 5 minutes) at a relatively low temperature ($170^{\circ}C$) afforded materials with optimum catalytic performance, since higher activation temperatures and/or longer activation times resulted in sintering of the silver particles.

• 한국안광학회지
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• 제11권2호
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• pp.85-89
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• 2006

렌즈 절삭공구의 기계적 특성을 향상시키는 기구에 관한 연구를 하기 위해, 탄화규소와 탄화티타늄을 주재료로 사용되었다. 또한, 소결첨가제로 알루미나와 이트리아를 첨가하였다. 첨가제 조성비는 알루미나와 이트리아비를 1:1로 유지하였다. 이를 $1810^{\circ}C$에서 1시간 일축가압 소결 후 $1860^{\circ}C$에서 3, 6 그리고 12시간 동안 열처리하였다. 열처리 시간이 길어질수록 입자크기는 점점 증가하였다. 미세구조는 주사전자현미경으로 관찰하였으며 이미지프로그램(Image-Pro Plus, Media Cybernetics, Maryland, U.S.A.)으로 상분석 하였다. 파괴기구는 주로 길게 자란 탄화규소 입자에 의한 균열회절에서 일어나고 있음을 알 수 있다. 균열회절기구에 영향을 미친 SiC입자들은 대부분 두께가 $2.3{\mu}m$ 이하였고, 장경비는 2.5 이상이었다. 균열가교도 일부 파괴인성 증진기구에 기여함을 알 수 있다.

• 한국재료학회지
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• 제14권8호
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• pp.595-599
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• 2004

We investigated the structural, electrical and magnetic properties of Mn-doped $CuAlO_2$ delafossite ceramics ($CuAl_{1-x}Mn_{x}O_2,\;0\le\;x\;\le0.05$), synthesized by solid-state reaction method in an air atmosphere at a sintering temperature of $1150^{\circ}C$. The solubility limit of Mn ions in delafossite $CuAlO_2$ was found to be as low as about 3 $mol\%$. Positive Hall coefficient and the temperature dependence of conductivity established that non-doped $CuAlO_2$ ceramic is a variable-range hopping p-type semiconductor. It was found that the Mn-doping in $CuAlO_2$ rapidly reduced the hole concentration and conductivity, indicating compensation of free holes. The analysis of the magnetization data provided an evidence that antiferromagnetic superexchange interaction is the dominant mechanism of the exchange coupling between Mn ions in $CuAl_{1-x}Mn_{x}O$ alloy, leading to an almost paramagnetic behavior in this alloy.

• 한국재료학회지
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• 제15권4호
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• pp.224-232
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• 2005

Dry sliding wear behavior of electro-pressure sintered Fe-Ni and Co-Fe-Ni compacts was investigated. Pin-on-disk wear tests were performed on the sintered Fe-Ni, Co-Fe-Ni disk specimens against alumina $(Al_2O_3)$ and silica $(SiO_2)$ ball counterparts at various loads ranging from 3N to 12N. A constant sliding speed of 0.1m/sec was employed. Wear rate was calculated by dividing the weight loss measured after the test by specific gravity and sliding distance. Worn surfaces and cross sections of them were examined by a scanning electron microscopy, and wear mechanism of the compacts was investigated. Wear characteristics of the compacts were discussed as a function of composition of the compacts. Relationship between the wear rate and mechancial properties of the compact was explored, and effects of the oxide layer that was formed on wearing surface of the compacts on the wear were also studied.

• 한국세라믹학회지
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• 제44권2호
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• pp.116-123
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• 2007

Electrical properties of AlN ceramics sintered with 1 wt% $Y_2O_3$ have been investigated. From the impedance spectroscopy, electrical conductivity of grain boundary was found to be much lower than that of grain. DC conductivity measurement showed the electrode polarization effects caused by blocking electrode. The heat-treatment at $1700^{\circ}C$ of the specimen sintered at $1850^{\circ}C$ transformed continuous pain boundary phases along triple boundary junctions into isolated particles in grain comers. The heat-treatment induced decreases both in grain and grain boundary conductivity, and in DC electrical conductivities. From the analysis on the transference number, ionic conductivity was shown to be more dominant than electron conductivity, which was due to ion compensation mechanism during oxygen incorporation into grain.

• 한국재료학회지
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• 제10권9호
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• pp.612-618
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• 2000

WC-Co와 WC-Co 초경합금중 WC/WC 입계의 구조와 입계 편석상태를 알아볼 목적으로 HRTEM과 EDS를 이용하여 연구하였다. 일부의 입계들은 액상에 의하여 분리된 상태로 관찰되었으나, 상당수는 원자적 상태의 연소계면이었다. 또 연속계면 중 WC-Co 합금에서는 Co 상이 편석되어 있었으며, WC-VC-Co 합금에서는 Co와 V이 동시에 편석되어 있음을 알 수 있었다. 그 편석의 폭은 약6nm이었다. 연속 계면 중 V의 편석은 소결 또는 열처리 시에 일어나는 입계 이동을 억제하는 데 효과적인 역할을 할 것으로 여겨졌다. 동시에 이것은 WC-Co 초경합금에서 VC 첨가에 의한 입성상 억제기구를 설명할 수 있는 것으로 사료되었다.

• 한국결정성장학회지
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• 제5권3호
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• pp.269-277
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• 1995

초고온(5000K 이상)의 고주파 유도 플라즈마(ICP)를 열원으로 사용하여 $AlCl_3$와 $Al_2(SO_4)_3$로부터 $Al_2O_3$ 초미세분말을 합성하였다. 각각 합성된 $Al_2O_3$ 미분말의 결정상은 모두${\alpha} - group({\alpha}, {wdelta}, {\theta})$의 상이었으며, 평균입경 20 nm 내외의 좁은 입도 분포를 가지는 미분말이 형성되었다. ICP tail flame 중간부(X = 500 mm)에서 MgO polycrystal plate위에 부착된 응집플록, whisker 및 판형의 형태를 통 해 기상-고상반응에 의한 성장과 입자간 소결현상을 제안 할 수 있었다. 그리고 위의 결과들로부터 spray-ICP 반응기 내에서의 $Al_2O_3$미 분말 형성과정을 제안하였다.