• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.381-381
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• 2011

The influence of the water vapor on the growth of single-walled carbon nanotubes (SWCNTs) was investigated. SWCNTs were synthesized by catalytic chemical vapor deposition of acetylene over Fe-Mo/MgO catalyst with injection of water vapor. The morphologies and structures of the water-assisted SWCNTs were investigated according to the growth conditions such as water vapor concentrations, flow rate of the gas, furnace temperature, and growth time. Water-assisted SWCNTs exhibited large bundle morphological features with well-alignment of each CNT, while SWCNTs synthesized in the absence of water vapor showed entangled CNT with the random orientation. We also found that the diameter of the SWCNT bundle could be controlled by the growth condition. In our optimal growth condition, the product yield and the purity were 300 wt. % and 75%, which were 7.5 and 2.5 times higher than those of SWCNTs synthesized without water vapor, respectively. More detail discussion will be offered at the poster presentation.

• Carbon letters
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• v.17 no.1
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• pp.29-32
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• 2016

This paper addresses the effect of dopants on the electronic properties of zigzag (8, 0) semiconducting single walled carbon nanotubes (SWCNTs), using extended Hückel theory combined with nonequilibrium Green’s function formalism. Through appropriate dopant concentrations, the electronic properties of SWCNTs can be modified. Within this context, we present our ongoing investigation on (8, 0) SWCNTs doped with nitrogen. Quantum confinement effects on the electronic properties of the SWCNTs have also been investigated. The obtained results reveal that the electronic properties of SWCNTs are strongly dependent on the dopant concentration and modification of electronic structures by hydrogen confinement.

• Bulletin of the Korean Chemical Society
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• v.30 no.9
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• pp.2071-2076
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• 2009

The single-walled carbon nanotubes (SWCNTs) produced by chemical vapor deposition (CVD) were directly fluorinated with fluorine ($F_2$) gas in a temperature range 20 ~ 400 ${^{\circ}C}$. The surface properties and morphology of the SWCNTs were investigated in terms of fluorination temperature. As a result, Raman spectra showed a pair of bands at 1340 and 1590 $cm^{-1}$ peculiar to disordered $sp^2$-carbons. These results indicated that C-F bonds were formed on the rear surfaces of the nanotubes by fluorination, while the external surfaces as well as the layers between the internal and external surfaces retained their $sp^2$-hybridization. XPS analysis exhibited that fluorine atoms were bonded to carbon atoms on internal surfaces (rear surfaces) of the nanotubes and the amount of fluorine attached on the nanotubes was increased with increasing the fluorination temperature. Consequently, the direct fluorination of carbon nanotubes led to functionalization and modification of pristine nanotubes with respect to surface and morphological properties.

• Computers and Concrete
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• v.32 no.3
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• pp.303-311
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• 2023

An analysis of the Poisson's ratios influence of single walled carbon nanotubes (SWCNTs) based on Sander's shell theory is carried out. The effect of Poisson's ratio, boundary conditions and different armchairs SWCNTs is discussed and studied. The Galerkin's method is applied to get the eigen values in matrix form. The obtained results shows that, the decrease in ratios of Poisson, the frequency increases. Poisson's ratio directly measures the deformation in the material. A high Poisson's ratio denotes that the material exhibits large elastic deformation. Due to these deformation frequencies of carbon nanotubes increases. The frequency value increases with the increase of indices of single walled carbon nanotubes. The prescribe boundary conditions used are simply supported and clamped simply supported. The Timoshenko beam model is used to compare the results. The present method should serve as bench mark results for agreeing the results of other models, with slightly different value of the natural frequencies.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.5
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• pp.402-410
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• 2008

Single-walled carbon nanotubes (SWCNTs) were currently produced together with some contaminants such as a metallic catalyst, amorphous carbon, and graphitic nanoparticles, which should be sometimes purified for their applications. This study aimed to develop efficient, scalable purification processes but less harmful to SWCNTs. We designed three-step purification processes: acidic treatment, surface functionalization and soxhlet extraction, and heat treatment. During the soxhlet extraction using tetrahydrofuran, specifically, carbon impurities could be easily expelled through a glass thimble filter without any significant loss of CNTs. Finally, SWCNTs were left as a bulky paper on the filter through membrane filtration. Vertically aligned SWCNTs on one side of bulky paper were well developed in a speparation from the filter paper, which were formed by being sucked through the filter pores during the pressurized filtration. The bucky paper showed a very high peak current density of field emission up to $200\;mA/cm^2$ and uniform field emission images on phosphor, which seems very promising to be applied to vacuum microelectronics such as microwave power amplifiers and x-ray sources.

• Carbon letters
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• v.13 no.4
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• pp.248-253
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• 2012

Dielectrophoretic filtering and alignment of single-walled carbon nanotubes (SWCNTs) were tested using deuterium oxide as a solvent. A solution of deuterium oxide-SWCNTs was dropped on top of a silicon chip and an ac electric field was applied between pre-defined electrodes. Deuterium oxide was found to be a better solvent than hydrogen oxide for the dielectrophoresis process with higher efficiency of filtering. This was demonstrated by comparing Raman spectra measured on the initial solution with those measured on the filtered solution. We found that the aligned nanotubes along the electric field were not deposited on the substrate but suspended in solution, forming chain-like structures along the field lines. This so-called pearl chain formation of CNTs was verified by electrical measurements through the aligned tubes. The solution was frozen in liquid nitrogen prior to the electrical measurements to maintain the chain formation. The current-voltage characteristics for the sample demonstrate the existence of conduction channels in the solution, which are associated with the SWCNT chain structures.

• Carbon letters
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• v.28
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• pp.60-65
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• 2018

Linear carbon chains (LCCs) encapsulated inside the hollow cores of carbon nanotubes (CNTs) have been experimentally synthesized and structurally characterized by Raman spectroscopy and transmission electron microscopy. However, in terms of electronic conductivity, their transportation mechanism has not been investigated theoretically or experimentally. In this study, the density of states and quantum conductance spectra were simulated through density functional theory combined with the non-equilibrium Green function method. The encapsulated LCCs inside (5,5), (6,4), and (9,0) single-walled carbon nanotubes (SWCNTs) exhibited a drastic change from metallic to semiconducting or from semiconducting to metallic due to the strong charge transfer between them. On the other hand, the electronic change in the conductance value of LCCs encapsulated inside the (7,4) SWCNT were in good agreement with the superposition of the individual SWCNTs and the isolated LCCs owing to the weak charge transfer.

• Advances in nano research
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• v.9 no.2
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• pp.83-90
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• 2020

This research investigates the effect of single walled carbon nanotubes (SWCNTs) dimensions in terms of diameter on the mechanical properties (longitudinal and transverse Young's modulus) of the simulated nanocomposites by molecular dynamics (MDs) method. MDs utilized to create nanocomposite models consisting of five case studies of SWCNTs with different chiralities (5, 0), (10, 0), (15, 0), (20, 0) and (25, 0) as the reinforcement and using polymethyl methacrylate (PMMA) as the common matrix. The results show that with increasing of SWCNTs diameter, the mechanical and physical properties increase. It is important that with the increasing of SWCNTs diameter, density, longitudinal and transverse Young's modulus, shear modulus, poisson's ratio, and bulk modulus of simulated nanocomposite from (5, 0) to (25, 0) approximately becomes 1.54, 3, 2, 1.43, 1.11 and 1.75 times more than (5, 0), respectively. Then to validate the results, the stiffness matrix is obtained by Materials studio software.

• Advances in materials Research
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• v.11 no.1
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• pp.1-22
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• 2022

In this paper, the nonlocal integral Timoshenko beam model is employed to study the free vibration characteristics of singled walled carbon nanotubes (SWCNTs) including the thermal effect. Based on the nonlocal continuum theory, the governing equations of motion are formulated by considering thermal effect. The influences of small scale parameter, the chirality of SWCNTs, the vibrational mode number, the aspect ratio of SWCNTs and temperature changes on the thermal vibration properties of single-walled nanotubes are examined and discussed. Results indicate significant dependence of natural frequencies on the nonlocal parameter, the temperature change, the aspect ratio and the chirality of SWCNTs. This work should be useful reference for the application and the design of nanoelectronics and nanoelectromechanical devices that make use of the thermal vibration properties of SWCNTs.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.153-153
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• 2008

Practical application of single-walled carbon nanotubes (SWCNTs) qualified as a promising material has been limited by either poor dispersion or their insolubility in aqueous or organic media due to formation of bundling by relatively high surface energy. Thus, major attention to overcome this issue has been paid at surface modification of CNTs by functionalization, but this introduces defects to the sidewall of CNTs, consequently perturbing the inherent electronic and optical properties. Therefore, using surfactants is a general approach to disperse SWCNTs with lower damages by which bundled nanotubes could be dispersed up to the level of individuals or small bundles. Here, we have investigated various surfactants for their efficiency in dissolving purified SWCNTs produced by arc discharge in deionized water. To compare the surfactants respectively, we have determined the least amount of each surfactant to suspend the nanotubes under optimized experimental conditions(CNT amount, sonication power, and centrifugation speed, etc.) set on the basis of the most common surfactant (sodium dodecyl sulfate, SDS) and discussed the qualitative and quantitative characterization of SWCNT dispersions by UV-Vis absorption spectroscopy. Quantitative aspect about nanotube dispersion was that in particular N-methyl-2-pyrrolidone (NMP) and sodium dodecylbenzene sulfonate (NaDDBS) were found to be effective in dispersing individual tubes.