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Research on Afterglow Brightness of Sr4-(x+y+z)Al14O25 : Eux, Dyy, Agz by Solid State Synthesis (고상법으로 합성한 Sr4-(x+y+z)Al14O25 : Eux, Dyy, Agz계 축광성 형광체 장잔광의 연구)

  • Kim, Seung-woo;Kim, Jung-sik
    • Korean Journal of Metals and Materials
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    • v.49 no.4
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    • pp.348-354
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    • 2011
  • Long-lasting brightness $Sr_{4}Al_{14}O_{25}$ : $Eu^{2+}$, $Dy^{3+}$, $Ag^{+}$ phosphor was synthesized by modified solid state reaction and its photoluminescence was investigated. $Sr(NO_3)_{2}$ and $Al(NO_3)_3{\cdot}9H_{2}O$ as starting materials, and $B_{2}O_{3}$ as a flux were mixed with $Eu_{2}O_{3}$ as an activator, $Dy_{2}O_{3}$ as a coactivator, and $AgNO_{3}$ as a charge compensator. The crystalline of target powder showed a single-phase $Sr_{4}Al_{14}O_{25}$ by the XRD characterization and the average particle size was about 20-30 ${\mu}m$ from the FE-SEM observation. $Ag^{+}$ ion doping effects (0-0.06 mol) on $Sr_{4}Al_{14}O_{25}:Eu^{2+},\;Dy^{3+},\;Ag^{+}$ phosphor were measured by photoluminescence spectrometer and luminescence meter. The of photoluminescence intensity of the $Sr_{3.64}Al_{14}O_{25}:Eu_{0.11},\;Dy_{0.22},\;Ag_{0.03}$ phosphor was higher than other compositions and afterglow brightness was 0.186 $cd/m^{2}$.

Filtration of dispersed nanoparticles using cyclone and ultrasonic atomization (초음파 무화 및 사이클론을 이용한 분산된 나노입자의 여과법)

  • Jung, Jihee;Kim, Moojoon;Kim, Jungsoon
    • The Journal of the Acoustical Society of Korea
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    • v.41 no.1
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    • pp.9-15
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    • 2022
  • In order to overcome the limitation of conventional nanoparticle dispersion methods such as sonicator or homogenizer, a filtration method using an ultrasonic atomization effect and cyclones was proposed in this study. A 0.5 wt% suspension was made with Al2O3 powder with an average diameter of 250 nm. The suspension was filtered by the proposed method after pre-dispersing using a sonicator and a homogenizer, respectively. As the result, in the case of the suspension after pre-dispersing with a sonicator, the particle size distribution of the filtered suspension started showing up a single normal distribution indicating the mode of the average diameter only after the 3rd cyclone process. On the other hand, in the case of the suspension with the homogenizer pre-dispersion, similar results appeared from the 2nd cyclone process. Filtration of various types of nanoparticles is expected to be possible by adjusting ultrasonic atomization frequency and manipulating the design of the cyclone.

The comparison between NBD test results and SCB test results using experimental test and numerical simulation

  • Fu, Jinwei;Sarfarazi, Vahab;Haeri, Hadi;Naderi, K.;Fatehi Marji, Mohammad;Guo, Mengdi
    • Advances in concrete construction
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    • v.13 no.1
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    • pp.83-99
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    • 2022
  • The two, NBD and SCB tests using gypsum circular discs each containing a single notch have been experimentally accomplished in a rock mechanics laboratory. These specimens have also been numerically modelled by a two-dimensional particle flow which is based on Discrete Element Method (DEM). Each testing specimen had a thickness of 5 cm with 10 cm in diameter. The specimens' lengths varied as 2, 3, and 4 cm; and the specimens' notch angles varied as 0°, 45° and 90°. Similar semi-circular gypsum specimens were also prepared each contained one edge notch with angles 0° or 45°. The uniaxial testing machine was used to perform the experimental tests for both NBD and SCB gypsum specimens. At the same time, the numerical simulation of these tests were performed by PFC2D. The experimental results showed that the failure mechanism of rocks is mainly affected by the orientations of joints with respect to the loading directions. The failure mechanism and fracturing patterns of the gypsum specimens are directly related to the final failure loading. It has been shown that the number of induced tensile cracks showing the specimens' tensile behavior, and increases by decreasing the length and angle of joints. It should be noted that the fracture toughness of rocks' specimens obtained by NBD tests was higher than that of the SCB tests. The fracture toughness of rocks usually increases with the increasing of joints' angles but increasing the joints' lengths do not change the fracture toughness. The numerical solutions and the experimental results for both NDB and SCB tests give nearly similar fracture patterns during the loading process.

Material and Manufacturing Properties of Bracket Mural Paintings of Daeungjeon Hall in Gaeamsa Temple, Buan

  • Lee, Hwa Soo;Yu, Yeong Gyeong;Han, Kyeong-Soon
    • Journal of Conservation Science
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    • v.38 no.1
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    • pp.45-54
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    • 2022
  • This study examined the production technique of bracket murals in Daeungjeon Hall, Gaeamsa Temple by conducting a analysis of their wall structure, material characteristics, and painting layers. Wall was a single-branch structure with support layer, middle layer, finishing layer, and painting layer. The support layer, middle layer and finishing layer, were produced by mixing sand (quartz, feldspars etc.), and loess. The ratio of above medium sand to below fine sand was approximately 0.7 : 9.3 in the support layer, 4 : 6 in the middle layer and 6 : 4 in the finishing layer, which had a more percentage of above medium sand than the support layer. The analysis of the painting layer showed that natural soil pigment was used to establish a relatively ground layer of up to 50 ㎛, and pigments such as Lead sulfate, atacamite and mercury sulfide were painted on top of the layer. This study's results confirmed that the bracket mural paintings in Gaeamsa Temple are within the category of the production style of murals during the Joseon period. However, the points that the middle layer was formed several times, the significant difference in particle size distribution between the wall, and the absence of chopped straw in the support layer are a feature of bracket mural paintings in Gaeamsa Temple. These properties of murals as material and structure may be viewed for correlation with the degree of damage to wall structure of mural painting and would serve as an important reference to diagnosis the conservation conditions of murals or prepare conservation treatments.

A Study on the Optimization of Offsite Consequence Analysis by Plume Segmentation and Multi-Threading (플룸분할 및 멀티스레딩을 통한 소외사고영향 분석시간 최적화 연구)

  • Seunghwan, Kim;Sung-yeop, Kim
    • Journal of the Korean Society of Safety
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    • v.37 no.6
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    • pp.166-173
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    • 2022
  • A variety of input parameters are taken into consideration while performing a Level 3 PSA. Some parameters related to plume segments, spatial grids, and particle size distribution have flexible input formats. Fine modeling performed by splitting a number of segments or grids may enhance the accuracy of analysis but is time-consuming. Analysis speed is highly important because a considerably large number of calculations is required to handle Level 2 PSA scenarios for a single-unit or multi-unit Level 3 PSA. This study developed a sensitivity analysis supporting interface called MACCSsense to compare the results of the trials of plume segmentation with the results of the base case to determine its impact (in terms of time and accuracy) and to support the development of a modeling approach, which saves calculation time and improves accuracy. MACCSense is an automation tool that uses a large amount of plume segmentation analysis results obtained from MUST Converter and Mr. Manager developed by KAERI to generate a sensitivity report that includes impact (time and accuracy) by comparing them with the base-case result. In this study, various plume segmentation approaches were investigated, and both the accuracy and speed of offsite consequence analysis were evaluated using MACCS as a consequence analysis tool. A simultaneous evaluation revealed that execution time can be reduced using multi-threading. In addition, this study can serve as a framework for the development of a modeling strategy for plume segmentation in order to perform accurate and fast offsite consequence analyses.

Synthesis of Nickel Oxide (NiO) nanoparticles using nickel(II) nitrate hexahydrate as a precursor (Nickel(II) nitrate hexahydrate를 전구체로 사용한 산화니켈(NiO) 나노입자의 합성)

  • Soo-Jong Kim
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.3
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    • pp.593-599
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    • 2023
  • Nickel oxide (NiO) nanoparticles were successfully synthesized by a simple liquid phase process for producing ceramics powder using a precursor impregnated with a nickel(II) nitrate hexahydrate aqueous solution in an industrial pulp. The microfibrile structure of the precursor impregnated with nickel nitrate hexahydrate aqueous solution was confirmed by scanning electron microscope (SEM), and the crystal structure and particle size of nickel oxide (NiO) particles produced as the heat treatment temperature of the precursor were analyzed by X-ray diffraction (XRD) and SEM. As a result, it was confirmed through XRD and SEM analysis that the temperature at which the organic material of the precursor is completely thermally decomposed was 495-500℃, and the size and crystallinity of the nickel oxide particles produced increased as the heat treatment temperature increased. The size of the nickel oxide particles obtained by heat treatment at 500-800℃ for 1 hour was 50-200 nm. It was confirmed by XRD and SEM analysis that a NiO crystal phase was formed at a heat treatment temperature of 380℃, only a single NiO phase existed until 800℃.

Thermoelectric properties of hot pressed polycrystalline $Bi_2Te_3-Bi_2Se_3$ (가압소결된 다결정 $Bi_2Te_3-Bi_2Se_3$ 열전재료의 열전특성)

  • Hwang, C.W.;Hong, I.G.;Paik, D.K.;Choi, S.C.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.4
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    • pp.363-369
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    • 1994
  • Bimuth telluride base thermoelectrics are prepared by AC current applied hot pressing method. It is possible to minimize the defects arising from the vaporization of Te, thanks to the very short processing time compared to the single crystal growing method. The optimum conditions for the AC applied hot pressing of 95 mol% $Bi_2Te_3-5 mol% Bi_2Se_3$ thermoelectrics are sintering at $400^{\circ}C$, for 2 minutes, under 1500 kgf/$\textrm{cm}^2$, with the particle size of $125 to 250 {\mu}m$, range of powder. The resultant Z value (figure of merit) was $2.2{\times}10^{-3}/K$.

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Synthesis of CuO nanoparticles by liquid phase precursor process (액상프리커서법에 의한 산화구리(CuO) 나노 입자의 합성)

  • Seong-Whan Shinn
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.6
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    • pp.855-859
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    • 2023
  • Copper oxide (CuO) nanoparticles were successfully synthesized using a precursor in which industrial starch was impregnated with an aqueous solution of copper (II) nitrate trihydrate. The microstructure of the precursor impregnated with an aqueous solution of copper nitrate trihydrate was confirmed with a scanning electron microscope (SEM), and the particle size and the crystal structure of the copper oxide particles produced as the temperature of the heat treatment of the precursor increased was analyzed by X-ray diffraction (XRD) and the scanning electron microscope (SEM). As a result of the analysis, it was confirmed that the temperature at which the organic matter of the precursor is completely thermally decomposed is 450-490℃, and that the size and crystallinity of the copper oxide particles increased as the heat treatment temperature increased. The size of the copper oxide particles obtained through heat treatment at 500-800℃ during 1 hour was 100nm~2㎛. It was confirmed that the copper oxide crystalline phase is formed at a heat treatment temperature of 400℃, and only the copper oxide single phase existed up to 800℃. And it was also confirmed that the size of particles produced increased as the calcination temperature increased.

A Study on Development of Acoustic Tweezer System Using Standing Waves and Very High Frequency Focused Beams (정상파와 초고주파 집속 빔을 이용한 음향집게시스템의 개발에 관한 연구)

  • Yang, Jeong-Won;Ha, Kang-Lyeol;Kim, Moo-Joon;Lee, Jung-Woo;Shung, K.K.
    • The Journal of the Acoustical Society of Korea
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    • v.27 no.7
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    • pp.357-364
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    • 2008
  • For the purpose of possibility study on development of an acoustic tweezer using standing waves and very high frequency ultrasound focused beams, a system which can manipulate the position of particles in water has been constructed. It can move the particles to near focal point of a focused beam by the radiation force of standing waves, and then the particles would be trapped by the radiating force of the focused beam. The results show that micro sphere particles were trapped well at nodes of the standing waves and their position can be easily manipulated by frequency control. And, even though the radiation force by single focused beam pushes a particle away from the transducer, two focused confronted beams can trap it at near center.

A Case Study of the Forecasting Volcanic Ash Dispersion Using Korea Integrated Model-based HYSPLIT (한국형 수치예보모델 기반의 화산재 확산 예측시스템 구축 및 사례검증)

  • Woojeong Lee;Misun Kang;Seungsook Shin;Hyun-Suk Kang
    • Atmosphere
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    • v.34 no.2
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    • pp.217-231
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    • 2024
  • The Korea Integrated Model (KIM)-based real-time volcanic ash dispersion prediction system, which employs the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model, has been developed to quantitatively predict volcanic ash dispersion in East Asia and the Northwest Pacific airspace. This system, known as KIM-HYSPLIT, automatically generates forecasts for the vertical and horizontal spread of volcanic ash up to 72 hours. These forecasts are initiated upon the receipt of a Volcanic Ash Advisory (VAA) from the Tokyo Volcanic Ash Advisory Center by the server at the Korea Meteorological Administration (KMA). This system equips KMA forecasters with diverse volcanic ash prediction information, complemented by the Unified Model (UM)-based HYSPLIT (UM-HYSPLIT) system. Extensive experiments have been conducted using KIM-HYSPLIT across 128 different volcanic scenarios, along with qualitative comparisons with UM-HYSPLIT. The results indicate that the ash direction predictions from KIM-HYSPLIT are consistent with those from UM-HYSPLIT. However, there are slight differences in the horizontal extent and movement speed of the volcanic ash. Additionally, quantitative verifications of the KIM-HYSPLIT forecasts have been performed, including threat score evaluations, based on recent eruption cases. On average, the KIMHYSPLIT forecasts for 6 and 12 hours show better quantitative alignment with the VAA forecasts compared to UM-HYSPLIT. Nevertheless, both models tend to predict a broader horizontal spread of the ash cloud than indicated in the VAA forecasts, particularly noticeable in the 6-hour forecast period.