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Origin of Multiple Conductance Peaks in Single-Molecule Junction Experiments

  • Park, Min Kyu;Kim, Hu Sung;Kim, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.654-654
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    • 2013
  • One of the most important yet unresolved problems in molecular electronics is the controversy over the number and nature of multiple conductance peaks in single-molecule junctions. Currently, there are three competing explanations of this observation: (1) manifestation of different molecule-electrode contact geometries, (2) formation of gauche defects within the molecular core, (3) involvement of different electrode surface orientations [1]. However, the exact origin of multiple conductance peaks is not yet fully understood, which indicates our incomplete understanding of the scientifically as well as techno-logically important organic-metal contacts. To theoretically resolve this problem, we previously applied a multiscale computational approach that combines force fields molecular dynamics (FF MD), density functional theory (DFT), and matrix Green's function (MGF) calculations [2] to a thermally fluctuating haxanedithiol (C6DT) molecule stretched between flat Au(111) electrodes, but could observe only a single conductance peak [3]. In this presentation, using DFT geometry optimizations and MGF calculations, we consider molecular junctions with more realistic molecule-metal contact conformations and Au(111) electrode surface directions. We also conduct DFT-based molecular dynamics for the highly stretched junction models to confirm our conclusion. We conclude that the S-Au coordination number should be the more dominant factor than the electrode surface orientation.

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Brushless DC Motor Electromagnetic Torque Estimation with Single-Phase Current Sensing

  • Cham, Chin-Long;Samad, Zahurin Bin
    • Journal of Electrical Engineering and Technology
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    • v.9 no.3
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    • pp.866-872
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    • 2014
  • The purpose of this paper was to find an effective method for measuring electromagnetic torque produced by a brushless DC motor with single-phase current sensing in real-time. A torque equation is derived from the theory of brushless DC motor. This equation is then validated experimentally with a motor dynamometer. A computer algorithm is also proposed to implement the electromagnetic torque estimation equation in real-time. Electromagnetic torque is a linear function of phase current. Estimating the electromagnetic torque in real-time using single-phase current is not appropriate with existing equations, however, because of the rectangular alternating-pulse nature of the excitation current. With some mathematical manipulation to the existing equations, the equation derived in this paper overcame this limitation. The equation developed is simple and so it is computationally efficient, and it takes only motor torque constant and single-phase current to evaluate the electromagnetic torque; no other parameters such as winding resistances, inductances are needed. The equation derived is limited to the three-phase brushless DC motor. It can, however, easily be extended to the multiphase brushless DC motor with the technique described in this paper.

Misunderstandings of Korean Beauty: Comparative Studies of the Theses of Ryoo Jong-yeol, Ko You-seup, and Yoon Hee-soon (한국적 미에 대한 오해 -류종열, 고유섭, 윤희순의 논고 비교분석-)

  • Oh, Beung-Ouk
    • The Journal of Art Theory & Practice
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    • no.1
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    • pp.23-48
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    • 2003
  • Art theorists support art productions by, introducing them to the public, explaining their meanings, and playing a crucial part in the development of art. These tasks seem like their opus. Because the principles of art production and the artistic languages are quite different from the ordinaries, we need 'interpreters' who can mediate us and the artists. Art works need interpretation. And the interpretation includes not only the characteristics of the given art work, but the customs, history, and the unique qualities of the race that produced the art work. The former director of the Korean National Museum, Choi Soon-woo wrote on the characteristics of Korean art as those that stem from the poised, arbitrary, and non-elaborate state of mind. The statement of the former Director of the National Museum has its weight far greater than just a personal opinion. In fact, we encounter the same resonance of this statement over and over reproduced in the mass media. The problem lies on that it deals with not only a single art work, but the entire Korean art. And going further, this kind of remarks are already infused into every sector of our thought on art appreciation. In this paper, I argue for a re-reading of the characteristics of Korean beauty based on two reasons. First, the characteristic of art work is contemporary, thus we cannot define the characteristics of entire Korean art in a few words without the context of the period of its making. Second, Director Choi defined the characteristics that I pointed out above as 'natural' and 'nature-friendly.' Nature or being natural is not an usual word that defines the characteristics of art work, which stands for the opposite side of the nature in the binary opposition of nature/culture. To delve into these misunderstandings of Korean beauty in the popular notions of Korean art, I suggest the re-reading of three major articles on Korean art: Ryoo Jong-yeol's "Korean race and its art," Ko You-seup's reiteration of Ryoo's thesis called "Discourses in Korean Art History and Aesthetics," and Yoon Hee-soon's antithesis of Ryoo Jong-yeol titiled "Studies on Korean Art History."

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Nature-based Tourism in Small Islands Adjacent to Jakarta City, Indonesia: A case study from Seribu Islands

  • Hakim, Luchman;Hong, Sun-Kee;Kim, Jae-Eun;Nakagoshi, Nobukazu
    • Journal of Wetlands Research
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    • v.9 no.1
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    • pp.31-46
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    • 2007
  • In this paper, the nature-based tourism is described as one of the tools to achieve sustainable development in small islands. The study was carried out at Ayer, Bidadari and Onrust Islands of Kepulauan Seribu chains at Jakarta Bay, Indonesia. While the historical records show that previous uses of such islands have started at sixteen century, tourism uses was started at the beginning of 1970s. Among nature-based tourism destination in Kepulauan Seribu chains, these islands are the famous destinations and received a lot of tourists. Tourism growth at these islands has stimulated development of numerous tourism facilities and infrastructure to meet visitor satisfaction. It is observed in this study that island's site-plan destination design has contributed to the successful and sustainability of tourism in small island. The key success lies on the successful integration and implementation of three substantial perspectives into practices, namely economic, ecosystem and social perspectives. First, in order to enhance economic benefits, a site-plan design allowing floating cottages establishment to extent room availability, to build strong images as tropical paradise islands, and to enhance tourist satisfaction with the objectives of improving income and sustaining tourist loyalty to the destination. This design is also reducing land risk from tourism impact and it becomes the significant key of second perspective, the ecosystem perspective. Moreover, the ecosystem perspective has been implemented through native vegetation preservation that led island's wildlife conservation and became potential tourism attraction. The design also develops effective mechanism to manage and regulate visitor flows by establishing visitor track corridors. In implementation, such corridor plays an important role to reduce tourist density in single places and therefore become instrument to reduce severe visitor impact to wildlife, vegetation and heritages of islands. Third, the social aspect of development allowing heritages to conserve and furthermore serve numerous benefits for education, socio-political, culture, and historical studies. Through this study, it is clear that the success of these islands to continuous tourism growth lies on the island's vision to integrate economic, ecosystem and social perspectives on tourism development.

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Assessment of Co-benefit and Trade-off Effects of Nature-based Solutions on Carbon Storage Capacity and Biodiversity (자연기반해법의 탄소저장과 생물다양성의 공동·상쇄 효과 평가)

  • Kim, Da-seul;Lee, Dong-kun;Hwang, Heymee;Heo, Su-jeong;Yun, Seok-hwan;Kim, Eun-sub
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.27 no.1
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    • pp.45-54
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    • 2024
  • This study developed a model to evaluate the co-benefits and trade-off effects between biodiversity and carbon storage capacity based on the implementation locations of nature-based solutions. The model aims to propose optimal implementation locations by using the conceptual idea of edge effects for carbon storage and connectivity for biodiversity. The co-benefits were considered by simultaneously taking into account two effects rather than a single effect. Trade-off effects were observed among optimal plans through a comparison of benefits. The NSGA-II multi-objective optimization algorithm was utilized, confirming the identification of Pareto-optimal solutions. The implementation patterns of Pareto-optimal solutions for green areas were examined. This study holds significance in proposing optimal locations by evaluating various co-benefits and trade-off effects of nature-based solutions. By advancing models based on this evaluation framework, it is anticipated that the assessment of co-benefits and trade-off effects among various benefits of nature-based solutions, such as climate change mitigation, enhancement of biodiversity, and provision of ecosystem services, can be accomplished.

Hula-twist, a Supramolecular Photoisomerization Reaction Mechanism in Reactions of Photosensitive Biopigments

  • Liu, Robert S.H.
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.1-4
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    • 2002
  • Hula-twist is a volume-conserving photoisomerization reaction mechanism postulated in 1985 to account for the rapid photoisomerization of the retinyl chromophore in rhodopsin. The requisite stereochemical consequence of simultaneous isomerization of a double bond and an adjacent single bond has recently been demonstrated in isomerization of pre-vitamin D in an organic glass and by many other examples of organic systems already reported in the literature This paper reports the consequence in applying the mechanism to the primary photochemical process of several photosensitive biopigments: bilirubin, photoactive yellow protein, bacteriorhodopsin and rhodopsin. It is shown that the anchored nature of the chromophores must first be taken into consideration.

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Efficient Task Execution Methods in Multi-Agent Systems (멀티 에이전트 시스템에서의 효율적인 작업 수행 방법)

  • 박정훈;최중민
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.511-514
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    • 1998
  • This paper proposes efficient methods that integrate and execute local plan rules of task agents in a multi-agent environment. In these methods, each agent's plan rules are represented in a network structure, and these networks are then collected by a single task agent to build a integrated domain network, which is exploited to achieve the goal. Agent problem solving by using the domain network enables a concurrent execution of plan rules that are sequential in nature.

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Design and Test of an Experimental Optical Cross-Connect

  • Lee, Sung-Un;Seo, Wan-Seok
    • Journal of Electrical Engineering and information Science
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    • v.3 no.3
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    • pp.336-341
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    • 1998
  • We describe the architecture of an optical cross-connect (OXC) which is modular in structure and is able to be upgraded to a virtual wavelength path by adding wavelength converters. The additional feature of the OXC is the all-optical nature. It can be implemented with commercial components including mechanical optical switches. As a result of the test on the experimental OXC, it has been shown that 2.5 Gb/s signal can be transmitted via the OXC through 100 km length o an ordinary single mode fiber with 3 dB penalty.

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Wind Tunnel Investigation of Fluctuating Pressure inside Building (풍하중에 의한 건물내부 압력의 동적변화에 관한 연구)

  • Kyoung-Hoon Rhee
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1990.10a
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    • pp.63-68
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    • 1990
  • The nature of fluctuating air pressure inside building was studied by testing a building model in a wind tunnel. The model has a single room and a sin81e window opening. Various opening conditions were tested in both laminar uniform wind and turbulent boundary-layer wind. The RMS and the spectra of the fluctuating internal pressure were measured. The test results support a recent theory which predicts the behavior of internal pressure under high wind based on aerodynamic analysis.

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DERIVATION OF THE GRAVITATIONAL MULTI-LENS EQUATION FROM THE LINEAR APPROXIMATION OF EINSTEIN FIELD EQUATION

  • KANG SANGJUN
    • Journal of The Korean Astronomical Society
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    • v.36 no.3
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    • pp.75-80
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    • 2003
  • When a bright astronomical object (source) is gravitationally lensed by a foreground mass (lens), its image appears to be located at different positions. The lens equation describes the relations between the locations of the lens, source, and images. The lens equation used for the description of the lensing behavior caused by a lens system composed of multiple masses has a form with a linear combination of the individual single lens equations. In this paper, we examine the validity of the linear nature of the multi-lens equation based on the general relativistic point of view.