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ZnO Nanostructure Characteristics by VLS Synthesis (VLS 합성법을 이용한 ZnO 나노구조의 특성)

  • Choi, Yuri;Jung, Il Hyun
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.617-621
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    • 2009
  • Zinc oxide (ZnO) nanorods were grown on the pre-oxidized silicon substrate with the assistance of Au and the fluorine-doped tin oxide (FTO) based on the catalysts by vapor-liquid-solid (VLS) synthesis. Two types of ZnO powder particle size, 20nm, $20{\mu}m$, were used as a source material, respectively The properties of the nanorods such as morphological characteristics, chemical composition and crystalline properties were examined by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX) and field-emission scanning electron microscope (FE-SEM). The particle size of ZnO source strongly affected the growth of ZnO nanostructures as well as the crystallographic structure. All the ZnO nanostructures are hexagonal and single crystal in nature. It is found that $1030^{\circ}C$ is a suitable optimum growth temperature and 20 nm is a optimum ZnO powder particle size. Nanorods were fabricated on the FTO deposition with large electronegativity and we found that the electric potential of nanorods rises as the ratio of current rises, there is direct relationship with the catalysts, Therefore, it was considered that Sn can be the alternative material of Au in the formation of ZnO nanostructures.

Removal of Heavy Metal Ions from Aqueous Solution by Leaves (식물 잎을 이용한 중금속 이온의 제거에 관한 연구)

  • Kim, Jong-Geu;Lee, Jang-Hoon;Lee, Su-Yong;Na, Kyung-Won;Ra, Kyu-Hwan;Choi, Han-Young
    • Journal of environmental and Sanitary engineering
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    • v.24 no.2
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    • pp.31-39
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    • 2009
  • In this research, I carried out the adsorption and removal test of Pb, Ni, Co and Cu ions using organic substances spread out any where in the nature which can be obtained easily from our neighbor-such as Paulownia coreana, Pinus densiflora, Juniperus chinesis, Quercus dentata, Magnolia kobus, Platanus occidentalis, Gingko biloba, Diospyros kaki leaves. As the result of the research to find the best optional condition for the adsorption and removal, shows that the adsorption and removal ratio of Pb ion by a Paulownia coreana raw leaves is 99% at $70^{\circ}C$, those of Ni ion and Co ion by Magnolia kobus formalin treatment leaves are 79% at $70^{\circ}C$, 97% at $40^{\circ}C$ respectively. And that of Cu ion by Platanus occidentalis treatment leaves is 97% at $50^{\circ}C$ in mixed solution. As the result of comparing the removal ratio by raw leaves and formalin treatment leaves, the removal ratio of treatment is 30~90% more effective than raw leaves in most cases. And I concluded Pb > Cu > Co > Ni ion in multiple solution and Co > Ni > Cu >Pb ion in single solution after testing adsorption and removal ratio of mixed solution separately as time goes by. In general, the reactions were completed within first 5 minutes. The test result of measuring the hydrolysable tannin content of each leaf shows that an overcup Quercus dentata is 11.36%, a Diospyros kaki is 10.81% and the rest of them are 2.49~4.12% in raw leaves cases. In treatment leaves cases, an overcup Quercus dentata is 3.23% and the others are less than 1%.

Molecular Behavior of $SF_6+H_2$ Structure II Hydrates (sII $SF_6+H_2$ 하이드레이트의 분자 거동)

  • Park, Da-Hye;Lee, Bo Ram;Sa, Jeong-Hoon;Sum, Amadeu K.;Lee, Kun-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.122.2-122.2
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    • 2011
  • Sulfur hexafluoride ($SF_6$), one of the most potent greenhouse gases, is known as a hydrate former and has been studied at the high pressure up to 1.3 GPa with gas mixtures and with aqueous surfactant. Since we regard $SF_6$ as a potential promoter molecule that can stabilize hydrate structure more effectively compare to the other promoters, further investigation is required to verify the stabilizing ability of $SF_6$ in the hydrate structure. However, the insoluble nature of $SF_6$ in water or gases hinders fine scale analyses. This work discusses the data obtained by using molecular dynamics simulations of structure II (sII) clathrate hydrates containing $SF_6$ and $H_2$. The simulations were performed using the TIP4P/Ice model for water molecule and a previously reported $SF_6$ molecular model (optimized at the pure $SF_6$ single phase system (Olivet and Vega, 2007)), and a $H_2$ molecular model (adapted from the THF+$H_2$ hydrate system (Alavi et al., 2006)). The simulations are performed to observe the stability of $SF_6$ and $H_2$ in the sII clathrate hydrate system with varying temperature and pressure conditions and occupancies of $SF_6$ and $H_2$, which cannot be easily tuned experimentally. We observe that stability of H2 enclathrated in the hydrate structure more affected by the occupancy of $SF_6$ molecules and temperature than pressure, which ranges from 1 to 100 bar.

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Preparation and Characterization of Suvarna Bhasma Parada Marit - Characterization of Suvarna Bhasma Parada Marit -

  • Thakur, Kapil;Gudi, Ramacharya;Vahalia, Mahesh;Shitut, Shekhar;Nadkarni, Shailesh
    • Journal of Pharmacopuncture
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    • v.20 no.1
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    • pp.36-44
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    • 2017
  • Objectives: The goal of this study was to characterize Suvarna Bhasma Parada Marit by using the Ayurvedic test parameters, physico-chemical tests, and various instrumentation techniques. Methods: Suvarna Bhasma, an Ayurvedic formulation manufactured as per Bharat Bhaishajya Ratnakar 5/8357 (BBR), has been studied using various instrumentation techniques: X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), laser particle size distribution (PSD) analysis, fourier transform infrared spectroscopy (FT-IR), and atomic absorption spectroscopy (AAS), and physico-chemical parameters, such as the loss on drying (LOD), loss on ignition (LOI), and acid insoluble Ash (AIA) were determined. In addition, Ayurvedic tests, such as Rekhapurnatva (enterable in the furrows of the fingers), Varitaratwa (floatable over water), Nirdhoomta (smokeless), Dantagre Kach-Kach (gritty particle feeling between the teeth), were performed. Results: The XRD study showed Suvarna Bhasma to be crystalline in nature and to contain more than 98% gold. The mean size of the gold crystallites was less than 10 microns, and the morphology was globular and irregular. Suvarna Bhasma contains gold as its single and major element, with EDAX and FT-IR spectra showing that it is more than 98% pure gold. The moisture content (LOD) is less than 0.5%, the LOI is less than 2%, and the AIA is not less than 95%. The Ayurvedic tests, as specified above, helped to confirm the quality of Suvarna bhasma prepared as per the text reference (BBR). Conclusion: This chemical characterization of Suvarna Bhasma performed in this study by using modern instrumentation techniques will be helpful in understanding its pharmacological actions and will help in establishing quality protocols and specifications to substantiate the safety, efficacy & quality of Suvarna Bhasma.

Characteristic Analysis of Multicell Convective System that Occurred on 6 August 2013 over the Korean Peninsula (2013년 8월 6일 한반도에서 발달한 다세포(Multicell) 대류계의 특성 분석)

  • Yoon, Ji-Hyun;Min, Ki-Hong
    • Atmosphere
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    • v.26 no.2
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    • pp.321-336
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    • 2016
  • Damages caused by torrential rain occur every year in Korea and summer time convection can cause strong thunderstorms to develop which bring dangerous weather such as torrential rain, gusts, and flash flooding. On 6 August 2013 a sudden torrential rain concentrated over the inland of Southern Korean Peninsula occurred. This was an event characterized as a mesoscale multicellular convection. The purpose of this study is to analyze the conditions of the multicellular convection and the synoptic and mesoscale nature of the system development. To this end, dynamical and thermodynamic analyses of surface and upper-level weather charts, satellite images, soundings, reanalysis data and WRF model simulations are performed. At the beginning stage there was a cool, dry air intrusion in the upper-level of the Korean Peninsula, and a warm humid air flow from the southwest in the lower-level creating atmospheric instability. This produced a single cell cumulonimbus cloud in the vicinity of Baengnyeongdo, and due to baroclinic instability, shear and cyclonic vorticity the cloud further developed into a multicellular convection. The cloud system moved southeast towards Seoul metropolitan area accompanied by lightning, heavy precipitation and strong wind gusts. In addition, atmospheric instability due to daytime insolation caused new convective cells to develop in the upstream part of the Sobaek Mountain which merged with existing multicellular convection creating a larger system. This case was unusual because the system was affected little by the upper-level jet stream which is typical in Korea. The development and propagation of the multicellular convection showed strong mesoscale characteristics and was not governed by large synoptic-scale dynamics. In particular, the system moved southeast crossing the Peninsula diagonally from northwest to southeast and did not follow the upper-level westerly pattern. The analysis result shows that the movement of the system can be determined by the vertical wind shear.

A Study on Textile Fashion Design Using the Formativeness of the Works of Gustav Klimt (구스타브 클림트[Gustav Klimt] 작품의 조형성을 활용한 텍스타일 의상 디자인 연구)

  • Lee, In-Young;Kim, Soo-Kyong
    • Journal of the Korean Society of Costume
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    • v.56 no.9 s.109
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    • pp.83-97
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    • 2006
  • This Study is a thesis presenting handicrafty and decorative textile design as well as sensual fashion design through the works of Gustav Klimt. The result is as below; The formative qualities in the works of Klimt could be featured as decorativeness, sensuality and symbolism. First, the decorative inclination is prominent in the portrait and the effect is maximized with the golden mosaic shape expressed on the dress and the background influenced by the Byzantine. Second, the sensuality could be recognized directly from the women's pose or facial expression in the works of Klimt, otherwise appeared on the refined expression showed on the portraits of noble lady Third, to surpass the reality, Klimt preferred the symbolic expression, which can be shown on the patterns in the works addressing the themes such as the legends and myths, or figures of men and women expressed with the image of an abstract features of membrum. The development of the textile design is as fellowed. First, it analyzes and reconstitutes the formativeness and the element of design in the works of Klimt by the flow of the form factor. Second. it makes a pattern of a single nature through perception, analysis, description and drawing and expresses with realization of the characteristics of Klimt. Focusing on the handicrafts and decorativeness out of the latest trends and making the most use of the sensuality, the designed textiles were completed by the handicrafty techniques, used in the fashion design and completed as the design of sensual images. The textile development aims at minimizing the limit of design that can be caused by the absence of silhouette and detail, expanding the range of its creativity of fashion designs and creating fashion design high value-added.

A Study on the Problem for discussion about Photogeography (사진지리학의 역할과 범위)

  • Kim, Joo-Hwan
    • Journal of the Speleological Society of Korea
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    • no.74
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    • pp.33-43
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    • 2006
  • The purpose of this study is to scientifically establish the concepts of photogeography, and to present desirable directions for the pursuit of photogeography in Korea. Photogeography is to effectively utilize the documentary and artistic nature of the photo, as an image medium, in the geographic study. The concept of photogeography, along with the term photogeology, is already known widely in foreign countries, and extensive research has been carried out in the field. However, here in Korea, nobody knows the concept of photogeography. Since photogeography has not been systemized as a science, and interest in photography is being minimal, photography, in reality, has in no way been utilized effectively. The photographs used in Photogeography can be classified, according to character, into two major categories, geographic photographs and general photographs, and, according to subject and camera, into still photographs and dynamic photographs. Photographs, such single photographs, slides, air photographs and satellite photographs are in the category of still photographs, while pictures like video and movie pictures are dynamic photographs.

Electrochemical Studies on Some Substituted Thiadiazoles (몇 가지 치환 Thiadiazole에 대한 전기화학적 연구)

  • El Maghraby, A. A.;Abou-Elenien, G. M.;Abdel-Reheem, N. A.;Abdel-Tawab, H. R.
    • Journal of the Korean Chemical Society
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    • v.50 no.4
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    • pp.307-314
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    • 2006
  • The redox characteristics of 2-ketohydrazono-3-phenyl-5-substituted-2,3-dihydro-1,3,4-thiadiazoles and its derivatives (1a-h) has been investigated in nonaqueous solvents such as 1,2-dichloroethane (DCE), dichloromethane (DCM), acetonitrile (AN), tetrahydrofuran (THF), and dimethylsulfoxide (DMSO) containing 0.1 mol.dm-3 tetra n-butylammonium perchlorate (TBAP) as supporting electrolyte at platinum ectrode. Through controlled potential electrolysis, the oxidation and reduction products of the investigated compounds can be separated and indentified. The redox mechanism is suggested and proved. It was found that all the investigated compounds are oxidized in two irreversible one-electron processes following the well known pattern of EC-mechanism. On the other hand, these compounds are reduced in a single two electron or in a successive two one electron processes following the well known pattern of EEC-mechanism according to the nature of the substituent

Single Level Adaptive hp-Refinement using Integrals of Legendre Shape Function (적분형 르장드르 형상함수를 이용한 단일 수준 적응적 hp-체눈 세분화)

  • Jo, Jun-Hyung;Yoo, Hyo-Jin;Woo, Kwang-Sung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.23 no.3
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    • pp.331-340
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    • 2010
  • The basic theory and application of new adaptive finite element algorithm have been proposed in this study including the adaptive hp-refinement strategy, and the effective method for constructing hp-approximation. The hp-adaptive finite element concept needs the integrals of Legendre shape function, nonuniform p-distribution, and suitable constraint of continuity in conjunction with irregular node connection. The continuity of hp-adaptive mesh is an important problem at the common boundary of element interface. To solve this problem, the constraint of continuity has been enforced at the common boundary using the connectivity mapping matrix. The effective method for constructing of the proposed algorithm has been developed by using hierarchical nature of the integrals of Legendre shape function. To verify the proposed algorithm, the problem of simple cantilever beam has been solved by the conventional h-refinement and p-refinement as well as the proposed hp-refinement. The result obtained by hp-refinement approach shows more rapid convergence rate than those by h-refinement and p-refinement schemes. It it noted that the proposed algorithm may be implemented efficiently in practice.

Nonlinear Analysis of Underwater Towed Cable Using Robust Nodal Position Finite Element Method (강건 절점위치 유한요소법을 이용한 수중 예인 케이블의 비선형 거동해석)

  • Lee, Euntaek;Go, Gwangsoo;Ahn, Hyung Taek;Kim, Seongil;Chun, Seung Yong;Kim, Jung Suk;Lee, Byeong Hee
    • Journal of the Society of Naval Architects of Korea
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    • v.53 no.5
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    • pp.388-399
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    • 2016
  • A motion analysis of an underwater towed cable is a complex task due to its nonlinear nature of the problem. The major source of the nonlinearity of the underwater cable analysis is that the motion of the cable involves large rigid-body motion. This large rigid-body motion makes difficult to use standard displacement-based finite element method. In this paper, the authors apply recently developed nodal position-based finite element method which can deal with the geometric nonlinearity due to the large rigid-body motion. In order to enhance the stability of the large-scale nonlinear cable motion simulation, an efficient time-integration scheme is proposed, namely predictor/multi-corrector Newmark scheme. Three different predictors are introduced, and the best predictor in terms of stability and robustness for impulsive cable motion analysis is proposed. As a result, the nonlinear motion of underwater cable is predicted in a very efficient manner compared to the classical finite element of finite difference methods. The efficacy of the method is demonstrated with several test cases, involving static and dynamic motion of a single cable element, and also under water towed cable composed of multiple cable elements.