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Characterization of Hot Isostatically Pressed Ni-Based Superalloy IN 713C (열간 등압 성형된 니켈기 초내열 합금 IN 713C 분말 소결체의 특성 평가)

  • Kim, Youngmoo;Kim, Eun-Pyo;Chunga, Seong-Taek;Lee, Seong;Noh, Joon-Woong;Lee, Sung Ho;Kwon, Young-Sam
    • Journal of Powder Materials
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    • v.20 no.4
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    • pp.264-268
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    • 2013
  • Nickel-based superalloy IN 713C powders have been consolidated by hot isostatic pressing (HIPing). The microstructure and mechanical properties of the superalloys were investigated at the HIPing temperature ranging from $1030^{\circ}C$ to $1230^{\circ}C$. When the IN 713C powder was heated above ${\gamma}^{\prime}$ solvus temperature (about $1180^{\circ}C$), the microstructure was composed of the austenitic FCC matrix phase ${\gamma}$ plus a variety of secondary phases, such as ${\gamma}^{\prime}$ precipitates in ${\gamma}$ matrix and MC carbides at grain boundaries. The yield and tensile strengths of HIPed specimens at room temperature were decreased while the elongation and reduction of area were increased as the processing temperature increased. At $700^{\circ}C$, the strength was similar regardless of HIPing temperature; however, the ductility was drastically increased with increasing the temperature. It is considered that these properties compared to those of cast products are originated from the homogeneity of microstructure obtained from a PM process.

The Characteristics of Corporate Growth and Innovation in the Materials, Components, and Equipments Sectors of Korean Display Industrial Value Chain (한국 디스플레이산업 가치사슬별 소재부품 및 장비기업의 성장과 혁신 특성)

  • Kim, Karpsoo
    • Journal of Korea Technology Innovation Society
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    • v.20 no.1
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    • pp.205-238
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    • 2017
  • Display industry in Korea has been rapidly developing over 20 years, now taking the top-class leading position in the world. Nevertheless, many previous studies have mainly focused on major panel set makers. To overcome the drawbacks, this study focuses on supplier companies in the upstream of display industry such as materials, components, and equipments sectors. The research method used in this study is an industry value chain perspective combined with architectural innovation approach. Display panel is produced through fabrication process and modular process, each having a different characteristics of process architecture. This research figured out that there are quite a different development characteristics between materials and components suppliers and equipment suppliers. The number and revenue of materials and components suppliers were quite larger than equipments suppliers. However, the former has been growing mainly in the field of modular process, having a very weak position in the field of fabrication process. On the contrary, equipments suppliers have been showing a continuously growing pattern in the field of fabrication process. The R&D expenditures between these two kinds of suppliers showed a similar pattern. The fabrication process of display panel production is characterized as a highly integral architecture characteristics, so as to be a strong barriers to local suppliers, resulting less development of materials and components suppliers in Korea.

Effect of Additives on the Refractive Index of B2O3-SiO2-Al2O3 Glasses for Photolithographic Process in Electronic Micro Devices

  • Won, Ju-Yeon;Hwang, Seong-Jin;Lee, Jung-Ki;Kim, Hyung-Sun
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.370-373
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    • 2010
  • In fabricating plasma display panels, the photolithographic process is used to form patterns of barrier ribs with high accuracy and high aspect ratio. It is important in the photolithographic process to control the refractive index of the photosensitive paste. The composition of this paste for photolithography is based on the $B_2O_3-SiO_2-Al_2O_3$ glass system, including additives of alkali oxides and rare earth oxides. In this work, we investigated the density, structure and refractive index of glasses based on the $B_2O_3-SiO_2-Al_2O_3$ system with the addition of $Li_2O$, $K_2O$, $Na_2O$, CaO, SrO, and MgO. The refractive index of the glasses containing K2O, Na2O and CaO was similar to that of the [BO3] fraction while that of the SrO, MgO and Li2O containing glasses were not correlated with the coordination fraction. The coordination number of the boron atoms was measured by MAS NMR. The refractive index increased with a decrease of molar volume due to the increase in the number of non-bridging oxygen atoms and the polarizability. The lowest refractive index (1.485) in this study was that of the $B_2O_3-SiO_2-Al_2O_3-K_2O$ glass system due to the larger ionic radius of $K^+$. Based on our results, it has been determined that the refractive index of the $B_2O_3-SiO_2-Al_2O_3$ system should be controlled by the addition of alkali oxides and alkali earth oxides for proper formation of the photosensitive paste.

Comparison of the bone healing capacity of autogenous bone, demineralized freeze dried bone allograft, and collagen sponge in repairing rabbit cranial defects

  • Hur, Jung-Woo;Yoon, Suk-Ja;Ryu, Sun-Youl
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.38 no.4
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    • pp.221-230
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    • 2012
  • Objectives: This study sought to evaluate the efficacy of collagen graft materials, as compared to other graft materials, for use in healing calvarial defects in rabbits. Materials and Methods: Ten mm diameter calvarial defects were made in ten rabbits. The rabbits were then divided into 4 groups: control, autogenous bone graft, SureOss graft, and Teruplug graft. Bone regeneration was evaluated using histological and radiographic methods. Results: Based on visual examination, no distinct healing profile was observed. At 4 weeks after treatment, histological analysis showed there was no bone regeneration in the control group; however, at 8 weeks after treatment, new bone formation was observed around the margin of the defective sites. In the autogenous bone graft group, new bone formation was observed at 4 weeks after treatment and mature bone was detected around the grafted bone after 8 weeks. In the SureOss graft group, at 4 weeks after treatment, acute inflammatory and multinuclear cells were noted around the grafted materials; at 8 weeks after treatment, a decrease in graft materials coupled with new bone formation were observed at the defective sites. In the Teruplug graft group, new bone formation was detected surrounding the bone margin and without signs of inflammation. There were statistically significant differences observed between the graft and control group in terms of bone density as evidenced by radiographic analysis using computed tomography (P<0.05), particularly for the autogenous bone graft group (P<0.001). Conclusion: These results suggested that autogenous bone, SureOss and Teruplug have the ability to induce bone regeneration as compared to an untreated control group. The osteogenic potential of Teruplug was observed to be lower than that of autogenous bone, but similar to that of SureOss.

Production of Lightweight Aggregates Using Power Plant Reclaimed Ash (발전소 매립회를 이용한 인공경량골재의 제조)

  • Kim, Kang-Duk;Kim, Jung-Hwan;Kim, Yoo-Taek;Kang, Seung-Gu;Lee, Ki-Gang
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.583-589
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    • 2010
  • In this paper, the properties of reclaimed ash(RA) from various domestic thermal power plants(S, D and H) were analyzed, and the possibility of fabricating the artificial lightweight aggregate(ALA) using RA was studied. The chemical compositions of RA are similar to the clay, but it had higher concentrations of alkali earth metal oxides(CaO, MgO) and unburned-carbon. The TCLP(Toxicity Characteristic Leaching Procedure) results showed that the dissolution concentrations of heavy metal ions of RA were below the limitation defined by the enforcement regulation of wastes management law in Korea. The results of IC analysis showed that leaching concentration of $Cl^-$ ion was 124 ppm for RA of HN and ${SO_4}^{2-}$ ion was leached a few hundreds ppm for all RA in this study. The ALAs with various mass ratio of clay to reclaimed ash(RA:Clay = 7:3, 6:4, 5:5, 4:6, 3:7) were sintered with a electric muffle furnace at the temperature of $1050{\sim}1200^{\circ}C$. The specific gravity and water absorption(%) of the sintered ALAs were 1.1~1.8 and 10~30% respectively. The ALA sintered in the rotary kiln at $1125^{\circ}C$ showed a bulk density of 1.7 and water absorption of 15.2%.

A Research on Legal Alternatives to Fire Performance Certificate and Tests for Interior Finish, Decorative Materials in Premises Used as Assemblies (다중이용업소에서 사용하는 실내장식재에 대한 방화.방염제도 개선에 관한 연구)

  • 박형주;곽동일
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.47-54
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    • 2001
  • Similar patterned fire incidents such as, Inchon Live-Hof Pub Restaurant as, Sea-land Children Resort have proven that serious loss of lives were caused by hazardous gas generated from a combustion of interior finish and decorative materials. Therefore, comparing Korean fire regulation with other countries fire code, e.g. UK, USA, France about limitation of interior finish and decorative materials in premises as assemblies, differences & problems have been int estimated and analyzed on hew serious they may affect on fire spread and smoke development based on analyze facts. It is suggested that Korean fire code would be revised in order to reduce hazardous interior finish materials from special occupancy and adapted new test methods to verify proper fire performance in premises as assembles which require a fire certificate. Finally, detailed code alternatives will be suggested in order to set up effective fire regulation, which could promote preventing serious loss of lives in future.

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Synthesis of Conjugated Linoleic Acid Methylester using Heterogeneous Catalysts (불균일계 촉매에 의한 공액 리놀레산 메틸에스테르의 합성)

  • Yuk, Jeong-Suk;Lee, Sang-Jun;Kim, Nam-Kyun;Kim, Young-Wun;Yoon, Byeong-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.291-298
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    • 2013
  • Conjugated linoleic acid methylester was synthesized through isomerization of linoleic acid methylester by using heterogeneous catalysts. As for heterogeneous catalysts, Ni supported zeolite type catalysts were used. H zoelite Y (HY) were ion exchanged with KCl aqueous solution to synthesize K zeolite Y (KY), and with impregnation method, Ni supported zeolite catalysts were synthesized. Catalysts were used after pre-treatment by using hydrogen. HY catalysts showed a high conversion at low temperatures; but a low selectivity for conjugation reaction. KY catalysts showed a low conversion at low temperatures; but a similar conversion with HY catalysts at high temperatures while a high selectivity at low temperatures. As a result, 4 wt% Ni/KY720 recorded the high conjugation yield of 63.4% at 220.

Measurement of High Temperature Anisotropic Elastic Constants of Zr-2.5Nb Pressure Tube Materials by Resonant Ultrasound Spectroscopy (초음파공명분광법에 의한 Zr-2.5Nb 압력관 재료의 고온 이방성 탄성계수 측정)

  • Cheong, Yong-Moo;Kim, Sung-Soo;Kim, Young-Suk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.2
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    • pp.140-148
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    • 2002
  • Anisotropic elastic constants of Zr-2.5Nb pressure tube materials were determined by a high temperature resonant ultrasound spectroscopy (RUS). The resonant frequencies were measured using alumina wave-guides and wide band ultrasonic transducers in a small furnace. The rectangular parallelepiped specimens were fabricated along with the axial, radial and circumferential direction of the pressure tube. A nine elastic stiffness tensor for orthotropic symmetry was determined in the range of room temperature ${\sim}500^{\circ}C$. As the temperature increases, the elastic constant tensor, cij gradually decreases. Higher elastic constants along the transverse direction compared to those along the axial or radial direction are similar to the case of Young's modulus or shear modulus. A crossing of shear elastic constants along axial direction and radial direction was observed near $150^{\circ}C$. This fact corresponds to the crossing of c44 and c66 of single crystal zirconium.

Analysis of Propagation of Deflagration and Fire Cause in the Busan lndoor Shooting Range (부산 실내사격장 화재의 연소 확대 및 발화원인 분석)

  • Song, Jae-Yong;Sa, Seung-Hun;Nam, Jung-Woo;Kim, Jin-Pyo;Kim, Dong-Hwan
    • Fire Science and Engineering
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    • v.25 no.3
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    • pp.1-7
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    • 2011
  • This paper studied analysis of deflagration rapid propagation of burning through only a few second and fire cause into the Busan indoor shooting range. We carried out combustion experiment of sound-absorbing materials extensively used, to analyze propagation path of burning in indoor shooting range. From the experimental results, general sound-absorbing materials were rapid burned simultaneously with ignition and in case of attached gunpowder residue, they were burning about tripled by comparison with general sound-absorbing materials. The incombustibility sound-absorbing materials had all gone out simultaneously with ignition, but they were burning similar to general type materials in case of attached gunpowder residues. In order to analysis of the cause of fire, we calculated kinetic energy of bounced off bullet, from result, if the bounced off bullet impacted gunpowder residues, the gunpowder residues were possible to ignite by the bullet.

Resistive Memory Switching in Ge5Se5 Thin Films

  • Kim, Jang-Han;Hwang, Yeong-Hyeon;Chung, Hong-Bay
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.326-326
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    • 2014
  • It has been known since the mid 1960s that Ag can be photodissolved in chalcogenide glasses to form materials with interesting technological properties. In the 40 years since, this effect has been used in diverse applications such as the fabrication of relief images in optical elements, micro photolithographic schemes, and for direct imaging by photoinduced Ag surface deposition. ReRAM, also known as conductive bridging RAM (CBRAM), is a resistive switching memory based on non-volatile formation and dissolution of a conductive filament in a solid electrolyte. Especially, Ag-doped chalcogenide glasses and thin films have become attractive materials for fundamental research of their structure, properties, and preparation. Ag-doped chalcogenide glasses have been used in the formation of solid electrolyte which is the active medium in ReRAM devices. In this paper, we investigated the nature of thin films formed by the photo-dissolution of Ag into Ge-Se glasses for use in ReRAM devices. These devices rely on ion transport in the film so produced to create electrically programmable resistance states [1-3]. We have demonstrated functionalities of Ag doped chalcogenide glasses based on their capabilities as solid electrolytes. Formation of such amorphous systems by the introduction of Ag+ ions photo-induced diffusion in thin chalcogenide films is considered. The influence of Ag+ ions is regarded in terms of diffusion kinetics and Ag saturation is related to the composition of the hosting material. Saturated Ag+ ions have been used in the formation of conductive filaments at the solid electrolyte which is the active medium in ReRAM devices. Following fabrication, the cell displays a metal-insulator-metal structure. We measured the I-V characteristics of a cell, similar results were obtained with different via sizes, due to the filamentary nature of resistance switching in ReRAM cell. As the voltage is swept from 0 V to a positive top electrode voltage, the device switches from a high resistive to a low resistive, or set. The low conducting, or reset, state can be restored by means of a negative voltage sweep where the switch-off of the device usually occurs.

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