• Journal of Hydrogen and New Energy
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• v.32 no.3
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• pp.149-155
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• 2021

Most of the reformer experiments have been conducted only in high-temperature operation conditions above 700℃. However, to design high efficiency solid oxide fuel cell, it is necessary to test actual reaction performance in mid-temperature (550℃) operation areas. In order to study the operation characteristics and performance of commercial reforming catalysts, a reforming performance experiment was conducted on mid-temperature. The catalysts used in this study are Ni-based FCR-4 and Ru-based RuA, RuAL. Experiments were conducted with a Steam-to-carbon ratio of 2.0 to 3.0 under gas hourly space velocity (GHSV) 2,000 to 5,000 hr-1. As a result, RuA and RuAL catalysts showed similar gas composition to the equilibrium regardless of the reforming temperature. However, the FCR-4 catalyst showed a lower hydrogen yield compared to the equilibrium under high GHSV conditions.

• Membrane and Water Treatment
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• v.13 no.6
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• pp.291-301
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• 2022

In this study, cement/PVDF hollow-fiber hybrid membranes were prepared via a mixed process of diffusion-induced phase separation and hydration. The presence of X-ray diffraction peaks of Ca(OH)₂, an AFt phase, an AFm phase, and C-S-H phase confirmed the hydration reaction. Good hydrophilicity was obtained. The cross-sectional and surface morphologies of the hybrid membranes showed that an asymmetric pore structure was formed. Hydration products comprising parallel plates of Ca(OH)₂, fibrous ettringite AFt, and granulated particles AFm were obtained gradually. For the hybrid membranes cured for different time, the pore-size distribution was similar but the porosity decreased because of blocking of the hydration products. In addition, the water flux decreased with hydration time, and carbon retention was 90% after 5 h of rejection treatment. Almost all the Zn²⁺ ions were adsorbed by the hybrid membrane. The above results proved that the obtained membrane could be alternative as basement membrane for separation application.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.4_2
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• pp.571-576
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• 2023

In this study, the harmless crack size(a_hml) according to the residual stress depth was evaluated using the fatigue limit of SCM440 steel by quenching-tempering(QT) and induction hardening(IH), and threshold stress intensity factor of QT steel. Because the residual stress increased rapidly as the crack depth increased, a_hml was determined at the depth of all the crack aspect ratio(As) regardless of Type I-III, and a_hml also increased according to the residual stress depth. a_hml was minimal at As=1.0 and maximal at As=0.1, but was almost similar on each Type. a_hml was small the dependence on As.

• Nuclear Engineering and Technology
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• v.55 no.4
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• pp.1287-1299
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• 2023

A new Monte-Carlo-based computer program (RDS-BASIC) is developed to simulate the transport of energetic ions in pure matter. This computer program is utilizing an algorithm that uses detailed numerical solutions for the classical scattering integral for evaluating the outcomes of the binary collision processes. This approach is adopted by several prominent similar simulation programs and is known to provide results with higher accuracy compared to other approaches that use approximations to shorten the simulation time. Furthermore, RDS-BASIC simulation program contains special methods to reduce the displacement energy threshold of surface atoms. This implementation is found essential for accurate simulation results for sputtering yield in the case of very low energy ions irradiation (near sputtering energy threshold) and also successfully solve the problem of simultaneously obtaining an acceptable number of atomic displacements per incident ions. Results of our simulation for several irradiation systems are presented and compared with their respective TRIM (SRIM-2013) and the state-of-the-art SDTrimSP simulation results. Our sputtering simulation results were also compared with available experimental data. The simulation execution time for these different simulation programs has also been compared.

• Corrosion Science and Technology
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• v.23 no.2
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• pp.166-178
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• 2024

The localized corrosion resistance of UNS N07718 alloy was investigated after solution heat treatment. When the alloy was heat-treated at 1050 ℃ for 2.5 hours, it experienced an increase in average grain diameter, a reduction in grain boundary area, and the dissolution of delta phases along grain boundaries. Additionally, primary metallic nitrides (MN) and metallic carbides (MC), enriched with either Ti or Nb, were identified and exhibited a random distribution within the microstructures. Despite the solution heat treatment, the composition, diameter, and abundance of MNs and MCs remained relatively consistent. The critical pitting temperature (CPT), as determined by the ASTM G48-C immersion test, revealed similar values of 45 ℃ for both treated and untreated alloys. However, a decrease in maximum pit depth and corrosion rate was observed after the solution heat treatment. The microstructural changes that occurred during the heat treatment and their potential implications were discussed to understand the influence of the solution heat treatment.

• Journal of Surface Science and Engineering
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• v.57 no.1
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• pp.1-7
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• 2024

The study investigated the impact of substrate pretreatment on depositing high-quality B-doped diamond (BDD) thin films using the HFCVD method. Films were deposited on Si and Nb substrates after sanding and seeding. Despite identical sanding conditions, BDD films formed faster on Nb due to even diamond seed distribution. Post-deposition, film average roughness (R_a) remained similar to substrate R_a, but higher substrate R_a led to decreased crystallinity. Nb substrate with 0.83 ㎛ R_a exhibited faster crystal growth due to dense, evenly distributed diamond seeds. BDD film on Nb with 0.83 ㎛ R_a showed a wide, stable potential window (2.8 eV) in CV results and a prominent 1332 cm^-1 diamond peak in R_aman spectroscopy, indicating high quality. The findings underscore the critical role of substrate pretreatment in achieving high-quality BDD film fabrication, crucial for applications demanding robust p-type semiconductors with superior electrical properties.

• Transactions of Materials Processing
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• v.33 no.3
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• pp.193-199
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• 2024

The friction welding characteristics of stainless steels, mainly used in energy and chemical plant industries due to its excellent corrosion resistance and high strength, was evaluated in this study. Friction welding was introduced and conducted at a rotation speed of 2,000 RPM, friction pressure of 30 MPa, burn-off length of 5 mm and upset pressure of 110 ~ 200 MPa on rod typed specimens. The grain boundary characteristics distributions such a grain size, shape, misorientation angle and kernel average misorientation of the welds were clarified by electron backscattering diffraction method. The application of friction welding on SUS304 alloy resulted in a significant refinement of the grain size in the weld zone (5.11 mm) compared to that of the base material (48.09 mm). The mechanical properties of the welds, on the other hand, appeared to be relatively low or similar to those of the base material, which were mainly caused by dislocation density in the initial material and grain refinement in the welds.

• Transactions of Materials Processing
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• v.33 no.5
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• pp.363-370
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• 2024

This study investigated the evolution behavior of microtexture developed in Ta-10W alloy during cold rolling. The changes in microtexture during the cold rolling process were experimentally analyzed using EBSD techniques. At relatively low rolling reductions (20%, 40%), θ-fiber and α-fiber textures were developed. However, as the reduction increased to 60% and 80%, strong α-fiber and γ-fiber textures were observed. The microtexture behavior was theoretically predicted using the VPSC polycrystal model under plane strain compression(PSC) and conditions considering deformation in the transverse direction. The VPSC model results under PSC predicted the strong development of θ-fiber texture at low reductions (20%, 40%) and the development of α-fiber and γ-fiber textures as the reduction increased to 60% and 80%. The VPSC model considering transverse deformation predicted results similar to the plane strain PSC at low reductions (20%, 40%), but as the reduction increased to 60% and 80%, it predicted that the development of α-fiber texture would be relatively weak, and the θ-fiber texture would still remain even at an 80% reduction. It was confirmed that the VPSC model considering transverse deformation more accurately predicts the evolution behavior of microtexture observed experimentally.

• Transactions of Materials Processing
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• v.33 no.4
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• pp.285-290
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• 2024

Electropulsing treatment (EPT) has been developed as an alternative to furnace heat treatment (FHT) to exploit its engineering advantages in rapidly annealing metallic materials. Conventionally, the separation of thermal and athermal effects of EPT has been attempted by comparing EPT and FHT specimens processed under identical temperature and duration. However, this method inherently introduces experimental and measurement errors. This study proposes a novel approach to distinguish the thermal and athermal effects of EPT-processed metals using T-shaped specimen with two observation points, namely 'C' and 'D'. For verification, the thermal gradient of T-shaped Mg alloys was examined under various EPT conditions. The points C exhibited higher temperatures compared to those at points D at a given electric current density, because only the former received both thermal and athermal effects. It was confirmed from twelve specimens that the point C at an electric current density of 65 A·mm^-2 and point D at 70 A·mm^-2 exhibited similar temperatures. This developed method is expected to reduce measurement errors in distinguishing thermal and athermal effects, thus providing a deeper understanding of their quantitative contributions in future studies.

• Journal of Photoscience
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• v.9 no.2
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• pp.122-125
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• 2002

Coherent oscillations in is fluorescence dynamics of W.-t. PYP and its site-directed mutants have been observed. Two oscillatory modes coupled with the ultrafast fluorescence due to the twisting of the excited chromophore were identified, a high ftequency mode (∼135 cm$\^$-1/) with ∼550 is damping time and a low frequency overdamped mode (-45 cm$\^$-1/) with ∼250 is damping time, respectively. Both modes disappear in the fluorescence dynamics of denatured PYP emphasizing the important role of the protein nanospace as the environment for photoreaction. The qualitative picture of fluorescence dynamics in site-directed mutants was rather similar to that in W.-t. PYP, i.e., similar oscillatory modes (∼130-140 cm$\^$-1/ and ∼40-70 cm$\^$-1/) have been observed. This indicates that the vibrational modes and electron-vibration couplings do not change dramatically due to the mutation though the damping time of low frequency mode a little decreases as the protein nanospace structure becomes looser and more disordered by mutation. On the other hand, in the case of some PYP analogues, the qualitative picture of fluorescence dynamics changes, showing the familiar picture of solvation effect whereas the oscillations are almost damped. Comparative analyses of these observations are presented.