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Thermal Decomposition of Octanethiolate Self-Assembled Monolayers on Cu(111) in UHV

  • Sung, Myung-M.;Yun, Won-J.;Lee, Sun-S.;Kim, Yun-Soo
    • Bulletin of the Korean Chemical Society
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    • v.24 no.5
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    • pp.610-612
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    • 2003
  • Octanethiol ($CH_3(CH_2)_7SH$) based self-assembled monolayer on Cu(111) in ultra-high vacuum has been examined using x-ray photoelectron spectroscopy (XPS), temperature programmed desorption (TPD), intergrated desorption mass spectrometry (IDMS), and contact angle analysis. The results show that the octanethiolate monolayers similar to those on gold are formed on Cu(111). The monolayers are stable up to temperatures of about 480 K. Above 495 K the monolayers decompose via the γ-hydrogen elimination mechanism to yield 1-octene in the gas phase. The thiolate head groups on the copper surface change to Cu₂S following the decomposition of hydrocarbon fragments in the monolayers at about 605 K.

Performance of rotational mode based indices in identification of added mass in beams

  • Rajendrana, Prakash;Srinivasan, Sivakumar M.
    • Structural Engineering and Mechanics
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    • v.54 no.4
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    • pp.711-723
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    • 2015
  • This study investigates the identification of added mass and its location in the glass fiber reinforced polymer (GFRP) beam structures. The main emphasis of this paper is to ascertain the importance of inclusion of rotational degrees of freedom (dofs) in the introduction of added mass or damage identification. Two identification indices that include the rotational dofs have been introduced in this paper: the modal force index (MFI) and the modal rotational curvature index (MRCI). The MFI amplifies damage signature using undamaged numerical stiffness matrix which is related to changes in the altered mode shapes from the original mode shapes. The MRCI is obtained by using a higher derivative of rotational mode shapes. Experimental and numerical results are compared with the existing methods leading to a conclusion that the contributions of the rotational modes play a key role in the identification of added mass. The authors believe that the similar results are likely in the case of damage identification also.

On geometry dependent R-curve from size effect law for concrete-like quasibrittle materials

  • Zhao, Yan-Hua;Chang, Jian-Mei;Gao, Hong-Bo
    • Computers and Concrete
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    • v.15 no.4
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    • pp.673-686
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    • 2015
  • R-curve based on the size effect law previously developed for geometrically similar specimens (geometry type III) is extended to geometries with variable depth (geometry type I) as well as with variable notch (geometry type II), where the R-curve is defined as the envelope of the family of critical strain energy release rates from specimens of different sizes. The results show that the extended R-curve for type I tends to be the same for different specimen configurations, while it is greatly dependent on specimen geometry in terms of the initial crack length. Furthermore, the predicted load-deflection responses from the suggested R-curve are found to agree well with the testing results on concrete and rock materials. Besides, maximum loads for type II specimen are predicted well from the extended R-curve.

The Solid State Bonding or ZrO2/NiTi: (I) Optimizating of Bonding Condition and its Strength (ZrO$_2$와 NiTi 합금의 고상접합 : (I)접합의 최적조건 및 접합강도)

  • Kim, Young-Jung;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.654-660
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    • 1991
  • Stabilized Zirconia (3 mol % Yttria, 3Y-TZP) was joined with intermetallic compound NiTi which has similar thermal expansion coefficient. The optimum bonding condition was determined by the Taguchi Method. Under the optimum bonding condition, the 4-point bending strength was as high as 400 MPa. bonding interfaces were examined by optical microscope, SEM, and TEM; reaction products were identified by XRD and TEM, The relationship between products and strength was examined.

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A Study on the Drapability of Flare Skirts in the Different Materials -between polyester and rayon fabrics- (소재에 따른 플레어스커트의 입체성능에 관한 연구 -레이온과 폴리에스테르소재 플레이스커트를 중심으로-)

  • 김혜경;이영숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.4
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    • pp.628-636
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    • 1995
  • The purpose of this study was to investigate the general distribution trend of drapery according to the material of flare skirt and the body size. 100% polyester and 100% rayon fabrics were chosen to compare the effect on the material type. The results from this study were as follows. (1) Both materials generally had similar trend of drapery (2) The difference of material influenced the shape and the amount of drapery. The amount of drapery in polyester was more than the one in rayon. (3) Rody size didn't significantly influence the shape of grapery. So it is concluded that material type is more important variable than the body size for the drapery.

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A Study on the Characteristics of the Interior Design of the Apartments in Busan - Focused on the living rooms of apartment units in modelhouse - (부산지역 아파트의 실내디자인 특성에 관한 연구 - 모델하우스의 거실공간을 중심으로 -)

  • 윤지영
    • Korean Institute of Interior Design Journal
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    • no.32
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    • pp.47-54
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    • 2002
  • This study attempts to analyze the characteristics of interior design of the apartments in Busan that people will reside since 2001 and to find out the effects of minimalism in the interior space. The companies which are in construction of the apartments of more than 50 Pyung were selected, and the design of the living rooms of their model houses were analyzed in terms of the floor plans, architectural elements, furniture and lightings. The results reveals that the living rooms of the newly-distributed apartments in Busan show similar design characteristics without distinctive differences among the companies. The new trends provide a flexible wall which makes it possible to manipulate the number of rooms according to the family preference, art-wall design in one-side of the walls and a coffered ceiling design, which can be interpreted to be closely related to the concept of minimalism with expression of simple horizontal and vertical lines, exclusive use of decorative forms, colors and materials, and use of natural materials

High Temperature Dielectric Properties of Silicon Nitride Materials (질화규소 재료의 고온 유전물성 평가)

  • Choi, Doo-Hyun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.10 no.3
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    • pp.114-119
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    • 2007
  • Dielectric properties of quartz glass and $Si_3N_4$ are investigated using the waveguide method from room temperature to $800^{\circ}C$. For the case of dielectric constant, $Si_3N_4$ showed similar increase with quartz glass up to $300^{\circ}C$, but less increase from $300^{\circ}C$ to $800^{\circ}C$. For the case of loss tangent, those showed gradual increase with temperature except of some temperature points. The loss tangent of $Si_3N_4$ and quartz glass increased up to 18.2% and 12.5% respectively. Through these researches, high temperature dielectric properties of silicon nitride materials are characterized.

A Study on the Vibration Characteristics Analysis of Composite Materials by Using Electronic Speckle Pattern Interferometry Method (전자처리 스페클 패턴 간섭법(ESPI)을 이용한 복합재료의 진동 특성 해석에 관한 연구)

  • 김경석;정성균;정현철;양승필;김형택;김동일;이승환
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.9
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    • pp.68-74
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    • 1998
  • The ESPI(Electronic Speckle Pattern Interferometry) is a real time, full-field, non-destructive optical measurement technique that allows static and dynamic deformation analysis and surface shape measurements of engineering structures. e .g. turbine blades. vehicle engine components, body panels, etc. This technique is very similar to holographic interferometry, but uses a solid static camera and an image processing board for recording and digital processing of speckle patterns. In this paper it is presented that FEM results for the free vibration of symmetrically laminated composite as [30/-30/90]s. The natural frequencies of laminated composite rectangular plates having the particular boundary condition are experimentally obtained. In order to demonstrate the validity of the experiment, FEM analysis using ANSYS was performed and natural frequencies experimentally obtained is compared with calculation by FEM analysis. The results obtained from both experiment and FEM analysis show a good agreement.

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A Evaluation Study on Reduction Method of Floor Impact Noise through Field Test and the Effective Method for Heavy Impact Noise (현장실험을 통한 바닥충격음 저감공법의 성능평가 및 중량충격음 저감 방안)

  • Lee, Byung-Kwon;Bae, Sang-Hwan;Hong, Cheon-Hwa
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.11a
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    • pp.451-456
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    • 2004
  • In this study, evaluation was carried out for reduction method of floor impact noise through field test and the effective methods for heavy impact noise were proposed. As a field test, impact noise reduction materials such as EPP, EEPS, EVA, PE and so on, did not satisfied the recommandation value at the condition of 150mm thickness concrete slab. The evaluation results for those materials by 'inverse A curve' showed $53\sim55dB$ at heavy impact noise and $53\sim58dB$ at light impact noise. But, two methods proposed by authors were evaluated $47\sim50dB$ at heavy Impact noise and $54\sim58dB$ at light Impact noise on the similar concrete slab thickness.

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TEXTURE AND RELATED PHENOMENA OF ELECTRODEPOSITS

  • Lee, D.N.
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.317-330
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    • 1999
  • The texture of electrodeposits changes from the orientation that places the lowest energy crystal facets parallel to the substrate under a condition of low ion concentration adjacent to the deposit, to the orientation that places the higher energy crystal facets parallel to the substrate as the ion concentration adjacent to the deposit increases. The electrodeposits have peculiar surface morphologies and microstructures depending on their textures, which in turn may affect their mechanical properties even when they are obtained in a similar electrolysis condition. The electrodeposits undergo recrystallization, when annealed. The recrystallization texture may be different from the deposition texture. These phenomena have been discussed.

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