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Experimental Study on the Properties of Solid Material Made by Autoclave Curing according to CaO/SiO2 Ratio and W/B (CaO/SiO2비 및 W/B 변화에 따른 오토클레이브 양생 경화체의 특성에 관한 실험적 연구)

  • Kang, Cheol;Kang, Ki-Woong;Kim, Jin-Man
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.557-563
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    • 2009
  • This study is on the properties of inorganic porous calcium silicate material made from silica powder through the autoclaving curing, the results of this study should be utilized fundamental data for the development of noise reduction porous solid material using siliceous byproduct generated by various manufacture process. For the manufacture of autoclave curing specimen, various calcareous materials used and siliceous materials used silica powder. In this study, properties in density and compressive strength according to the change of W/B and C/S ratio, microscopy for the shape of pore, SEM and XRD for the examination of hydrate after autoclave curing are carried out respectively. The test results shown that the more slurry density decrease, the more W/B increase at the fresh state, this tendency shown similar to in hardened state. Among the specimens of C/S ratio, the compressive strength of C/S ratio of 0.85 gave the highest the compressive strength. In the results of XRD, tobermorite generated by autoclaving curing was created all of specimens regardless of C/S ratio. To ascertain pore structure, we compared with existing porous calcium silicate product(ALC, organic sound absorbing porous material). The results of microscope observation, pore structure of specimen of this study was similar to that of existing inorganic sound absorbing foam concrete. therefore, we could conformed a possibility of sound absorbing porous solid material on the basis of the results.

A study on the Effectivness of Hand-made Paraffin Thyroid Phantom (Paraffin을 이용한 Thyroid Phantom제작에 따른 유용성에 관한 연구)

  • Park, Soung-Ock;Lee, In-Ja
    • Journal of radiological science and technology
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    • v.30 no.3
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    • pp.237-243
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    • 2007
  • Phantoms are very necessary for quality assurance of radio nuclides imaging systems to maintain standards and to ensure reproducibility of test. General quality assurance and instrument quality control are essential in every hospital. The human tissue equivalent materials are aluminum, areryl, water and epoxy..etc. It is very important to select optimum equivalant materials for a phantoms in QC. Especially, paraffin is very similar with human soft tissue in X or Gamma-ray physical characteristics and easy to buy with economically. We made a paraffin thyroid phantom and compare with thyroid areryl phantom, also used commercially in practice. Two small size cold spots(3 and 6 mm diameter) and a hot spot(3 mm diameter) embeded in paraffin phantom. And imaged with $^{99m}TcO_4$ by camera for analysis about spatial resolution and noise at the hot and cold spots. We got some results as below : 1. No difference in counting rate and noise between both arcryl and paraffin thyroid phantoms. 2. The best spatial resolution can be seen 6 cm distance between pinhole collimator and thyroid phantoms(arcryl and paraffin). 3. More optimal spatial resolution could acquired in paraffin thyroid phantom. Paraffin is very similar with human soft tissue in atomic number, density and relative absorbtion function, and can be shaped easily what we wanted. So we can recommendation paraffin as quality assurance phantom because its usefulness, economical benefit and purchasability.

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Study of Characteristics for Red Adhesive in Traditional Gold Thread (전통 편금사에 사용된 붉은 접착제 특성 연구)

  • Kim, Ji Eun;Yu, Ji A;Han, Ye Bin;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.32 no.1
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    • pp.43-49
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    • 2016
  • Gold threads mean thread made by metal, it is composed various material to gold leaf, adhesive and media. The making technique and using materials of Gold threads are different from region, it can be used to distinguish country of origin. So this study finds characteristics and making techniques for flat gold threads of relics. Standard samples are made of animal glue, lacquer, red lacquer and etc. This materials are based on the scientific investigation of cultural gold threads properties. Then traditional techniques were estimated by comparison and analysis of actual cultural properties and standard samples. As a result of investigating cultural properties, it is similar to the standard sample which are mixed with red soil additives. After analysis of SEM-EDS, it is detected to Al, Si, Fe. So it is to the conclusion that traditional gold thread is made of adhesive mixed with red soil to improve gold color better. And this ways are similar with china that uses animal glue and red soil to adhesive and different from japan that uses lacquer to adhesive. Through this study, it will be used to data and reference for reappearance and making techniques of traditional gold threads.

The Effect on the Marine Water and Sediment Quality by the Use of Nano-S 2. Result of Field Experiment (Nano-S가 해양수질 및 저질에 미치는 영향에 관한 연구 2. 현장실험 결과)

  • Cho, Chon-Rae;Jang, Young-Nam;Cho, Hyeon-Seo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.1 s.28
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    • pp.21-28
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    • 2007
  • The purpose of this study was to observe the effect on the water quality and sediment environment by the use of Nano-S for anti-Red tide material. The experiment was performed at subtidal and intertidal zone during six months(from Aug 2005 to Feb. 2006). The experiment sites were divided with concentration of materials. One is lower concentration(0.1%) and the other is higher concentration(1%). The results of experiments didn't show the remarkable influence of the materials effect before and after applying the Nano-S and the red mud. pH, salinity and DO were slowly increased during experiment period but nutrients were conversely decreased in the seawater. In the subtidal zone, qualities of sediments, IL, AVS and COD, were gradually lowered and the similar results were appeared in the intertidal zone. These results showed similar trends over all the experiment sites including control site. The results of heavy metals also did not show the interest different effect before and after applying the Nano-S and red mud compared with control site.

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Synthesis of Novel Prepolymers Containing No Bisphenol A and Preparation of Organic Matrices for Dental Applications (비스페놀 A를 함유하지 않은 치과용 신규 프리폴리머의 합성 및 유기 매트릭스의 제조)

  • Son, Jun-Sik;Lee, Ki-Baek;Park, Kwi-Deok;Kim, Jae-Jin;Ahn, Kwang-Duk;Kim, Jung-Hyun;Han, Dong-Keun
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.538-544
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    • 2006
  • Two kinds of novel bifunctional methacrylated prepolymers (170-2MA and 631-2MA) which have similar structure with 2,2-bis[4- (2'-hynroxy-3'-methacryloyloxypropoxy)phenyl] propane (Bis-GMA) was synthesized for dental applications as an alternative to Bis-GMA containing bisphenol A that is doubtful as an endocrine disrupter. The organic matrices were prepared by mixing a diluent and/or a monomer with the synthesized methacrylated prepolymers. The yield, viscosity, and chemical structures of the prepolymers and the physical and methanical properties of the organic matrices were evaluated. The yields of the prepolymers synthesized through a ring-opening reaction of epoxy compound and methacrylic acid were above 90% and the viscosities of the prepolymers were much lower than that of the Bis-GMA control. From the results of $^1H-NMR$ and FTIR analyses, the chemical structures of the prepolymers were similar to that of Bis-GMA. In addition, the curing time, poly-merization shrinkage, photoconversion, polymerization depth, and compressive strength of the organic matrices formulated with 170-2MA and 631-2MA prepolymers exhibited comparable to or better than those of the existing Bis-GMA-based one. These results suggest that the novel methacrylated prepolymers which have no endocrine disrupter can be an alternative to Bis-GMA and be applicable to dental polymer materials.

Archaeological Scientific Characteristics of Patternless Pottery with Talc Temper: Baekseokdong Gojaemigol Site in Cheonan, Korea (활석비짐 무문토기의 고고과학적 특성: 천안 백석동 고재미골 유적)

  • Kim, Su Kyoung;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.31 no.2
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    • pp.159-173
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    • 2015
  • The patternless potteries excavated from the Baekseokdong Gojaemigol site in Cheonan, was subdivided into talc and non-talc (including amphibole) type pottery. The potteries showed black, reddish brown and yellowish brown colors, but represent to difference with occurrences and internal texture of raw materials and temper minerals. The all potteries and paleosoils are commonly high content of temper minerals with poorly sorting and roundness of particles, and the paleosoils composed mainly of quartz, plagioclase, mica, chlorite and kaolinite. Between the talc and non-talc type potteries are very similar with magnetic susceptibility, absorption ratio and specific gravity. Geochemical behaviors of major, minor, compatible and incompatible elements in talc pottery are very similar with amphibole, non-talc pottery and paleosoils, and well correspondence with enrichment and deficiency patterns of each element, and the talc and amphibole potteries are highly enriched patterns of MgO concentration. In paleosoils of Gojaemigol site, talc and amphibole are not detected, therefore, making the pottery of the site estimate the possible to artificial additions of the temper minerals of talc and amphibole used interbedded talc layer within gneiss complex near the Baekseokdong area. Based on the phase relations, differential thermal and thermal gravimetric analyses, the potteries could be classified into two groups by firing temperature. The one group of talc temper pottery fired from 800 to $870^{\circ}C$ and the other group of amphibole and non-talc temper pottery revealed of 900 to $950^{\circ}C$.

A Study on Chemical Composition and Firing Temperature of White Wares from the Guyre-2ri Kiln Sites, Wonju (원주 귀래2리 가마터 출토 백자의 화학조성과 소성온도 연구)

  • Lee, Byeong Hoon;So, Myoung-Gi
    • Journal of Conservation Science
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    • v.30 no.3
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    • pp.249-261
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    • 2014
  • This study aims to examine production technique of white wares from the Guyre-2ri 1st and 2nd kiln sites, Wonju, Gangwon Province and characteristics of the used materials, and to find a correlation among materials of the excavated white wares. X-ray fluorescence sequential spectroscopy(XRF), X-ray diffraction(XRD), Dilatometer and Inductively coupled plasma mass spectrometry(ICP-MS), Inductively coupled plasma automic emission spectrometer(ICP-AES) were applied to determine the chemical composition, crystalline phase of samples, firing temperatures, trace elements and rare earth elements. White wares from the Guyre-2ri kiln sites contained high contents of coloring oxides and fluxes. Though firing temperature of each sample was different, they were mostly fired at a temperature below $1200^{\circ}C$ and some of them experienced a low temperature of $1000^{\circ}C{\pm}20^{\circ}C$ and a high temperature above $1200^{\circ}C$. When analyzing body crystalline phases of the white wares using the XRD method, quartz and mullite were extracted from all the samples, and the proportions were similar to each other. When analyzing the excavated white wares using the Seger formula, also, all the samples showed similar clay sources and production techniques. Moreover, the white wares were made of host rocks of the same geological origin, according to the result of rare earth elements analysis.

$BBPY^{(R)}$ graft for periodontal intrabony defects and molar furcation lesions: Case Report (다양한 치주 골내낭과 이개부 병변의 처치를 위한 $BBP^{(R)}$ 이식재의 임상적 효과)

  • Kim, Myung-Jin;Lee, Ju-Youn;Kim, Sung-Jo;Choi, Jeom-Il
    • Journal of Periodontal and Implant Science
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    • v.38 no.1
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    • pp.97-102
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    • 2008
  • Purpose: Periodontal intrabony defects have great deal of importance since they contribute to the development of periodontal disease. Current treatment regimens for intrabony defects involve grafting of numerous bony materials, GTR using biocompatible barriers, and biomodification of root surface that will encourage the attachment of connective tissue. Xenograft using deproteinized bovine bone particles seems to be very convenient to adjust because it doesn't require any donor sites or imply the danger of cross infections. These particles are similar to human cancellous bone in structure and turned out to be effective in bone regeneration in vivo. We here represent the effectiveness of grafting deproteinized bovine bone particles in intrabony defect and furcation involvements that have various numbers of bony walls. Materials and methods: Open flap debridement was done to remove all root accretions and granulation tissue from the defects within persisting intrabony lesions demonstrating attachment loss of over 6mm even 3 months after nonsurgical periodontal therapy have been completed. Deproteinized bovine bone particles($BBP^{(R)}$, Oscotec, Seoul) was grafted in intrabony defects to encourage bone regeneration. Patients were instructed of mouthrinses with chlorohexidine-digluconate twice a day and to take antibiotics 2-3 times a day for 2 weeks. They were check-up regularly for oral hygiene performance and further development of disease. Probing depth, level of attachment and mobility were measured at baseline and 6 months after the surgery. The radiographic evidence of bone regenerations were also monitored at least for 6 months. Conclusion: In most cases, radio-opacities increased after 6 months. 2- and 3-wall defects showed greater improvements in pocket depth reduction when compared to 1-wall defects. Class I & II furcation involvements in mandibular molars demonstrated the similar results with acceptable pocket depth both horizontally and vertically comparable to other intrabony defects. Exact amount of bone gain could not be measured as the re-entry procedure has not been available. With in the limited data based on our clinical parameter to measure pocket depth reduction following $BBP^{(R)}$ grafts, it was comparable to the results observed following other regeneration techniques such as GTR.

The development of deformation microstructures and textures in high Mn steels (고Mn강의 소성에 따른 미세조직및 Texture 변화에 관한연구)

  • Kim, Taek-Nam;Kim, Jong-Ok
    • The Journal of Natural Sciences
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    • v.7
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    • pp.83-90
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    • 1995
  • The microstructural and textural development during rolling is compared in two Hadifield's steels (high Mn steel), one having low carbon content (0.65 wt.%) and the other high carbon (1.35 wt.%).In low carbon Hadfield's steel (LCHS) mixed microstructures are formed which contain intrinsic stacking faults, deformation twins, and brass type shear bands. The deformation twins are thought to be formed by the stacking of intrinsic stacking faults. The similar development to 70-30 brass texture is observed in early deformation. However the abnormal texture is developed after 40 % deformation, which is thought to be due to the martensite phase transformation. In high carbon Hadfield's steel (HCHS) mixed substructures of dislocation tangles, deformation twins, and shear bands (both copper and brass type) are found to develop. The texture development is similar to that of 70-30 brass. This is consistant with no carbon segregation and no martensitic phase transformation in HCHS. In spite of the difference of substructure and texture development during rolling in two steels, the difference in stacking fault energy is measured to be small ($2 mJm^-2$). The carbon segregation is only occurred in LCHS. Thus it is thought that the carbon segregation influence the microstructure and texture development during rolling. This is related with martensite phase transformation in LCHS.

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Electrical Output and Reliability of Photovoltaic Module Using Ethylene Tetrafluoroethylene Film (ETFE 필름을 적용한 태양광 모듈의 전기적 출력 및 신뢰성에 관한 연구)

  • Shin, Woogyun;Lim, Jongrok;Ko, Sukwhan;Kang, Gihwan;Ju, Youngchul;Hwang, Heymi
    • Journal of the Korean Solar Energy Society
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    • v.40 no.4
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    • pp.13-22
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    • 2020
  • As the supply of photovoltaic (PV) increases worldwide, the cumulative installations in 2018 were 7.9 and 560 GW in Korea and the world, respectively. Typically, when the ground on commercial PV modules is installed, the area is limited; hence, new designs of PV modules are required to install additional PVs. Among the new design of PV modules, lightweight PV modules can be utilized in PV systems, such as buildings, farmlands, and floating PV. Concerning the investigation of lightweight PV modules, several studies on materials for replacing low-iron tempered glass, which comprises approximately 65% of the PV module weight, have been conducted. However, materials that are used as substitutes for glass should possess similar lightweight properties and reliability as glass. In this study, experimental tests were performed to evaluate the applicability of ethylene tetrafluoroethylene (ETFE) film with excellent resistance to water and aging as a front material of PV modules. The transmittance and ultraviolet properties of the ETFE film were determined and compared with those of glass. A 1-cell module and laboratory-scale 24-cell module were manufactured using the ETFE film and glass, and the electrical output was measured and analyzed. Furthermore, damp heat and thermal cycle tests were conducted to evaluate the reliability of the ETFE film module. Based on the experimental results, the electrical output and reliability of the ETFE film module were similar to those of the glass module, and the ETFE film could be used as the front material of PV modules.