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Design and Applications of Molecularly Imprinted Polymers for Selective Separations (선택적 분리를 위한 분자 각인 고분자의 설계 및 응용)

  • 정수환;오창엽;서정일;박중곤
    • KSBB Journal
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    • v.16 no.2
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    • pp.115-122
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    • 2001
  • Molecular imprinting has now been established as a technique which allows the creation of tailor-made binding sites for many classes of compounds. MIPs were prepared by covalent and non-covalent chemical bonding systems, by interactions between functional monomer and template. The shape of MIP is divided to particle and membrane. MIP membranes can be prepared by surface imprinting, in-situ polymerization, wet phase inversion and the dry phase inversion method. MIPs have been mainly used for analytical separation and biosensor systems to separate and detect chiral compounds and materials with similar structures. However the application of MIP by the chemical industries is still in its infancy stages. This review summarizes the preparative characteristics and applications of MIP with respect to chiral separations and biosensors.

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Climate and Growth Relationship in Blue Pine (Pinus wallichiana) from the Western Himalaya, India (인도 서히말리아산 블루파인(Pinus wallichiana)의 연륜생장과 기후와의 관계)

  • Yadav, R. R.;Amalava, B.
    • The Korean Journal of Ecology
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    • v.20 no.2
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    • pp.95-102
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    • 1997
  • Ring width chronologies of blue pine (pinus wallichiana) from two mesic sites, Kanasar(2, 400 m) and Gangotri(3, 000 m), in the western Himalayan region. India were developed to understand tree growth-climate relationship and its applicability in proxy climate studies. The resoponse function analyses of the two chronologies show that the site conditions play an important role in modulating the effect of climatic variables on tree growth. Winter temperature, prior to the growth year, has been found to play positive influence on blue pine growth at both sites. Summer temperature also has very similar response except for June and August. June temperature has negative influence at the lower in contrary to at the higher site. Low August temperature favors tree growth to precipitation has been found to vary which could be due to different precipitation regime at the two sites. Winter precipitation is important for tree growth at the higher, whereas summer at the lower sits. The present study suggests that the tree ring materials of blue pine from the temperate Himalayan regions could be used to develop chronologies for the reconstruction of seasonal climatic variables.

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Stress-strain behavior of geopolymer under uniaxial compression

  • Yadollahi, Mehrzad Mohabbi;Benli, Ahmet
    • Computers and Concrete
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    • v.20 no.4
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    • pp.381-389
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    • 2017
  • The various types of structural materials that are available in the construction industry nowadays make it necessary to predict their stress-strain behavior. Geopolymer are alternatives for ordinary Portland cement concrete that are made from pozzolans activation. Due to relatively new material, many mechanical specifications of geopolymer are still not yet discovered. In this study, stress-strain behavior has been provided from experiments for unconfined geopolymers. Modulus of Elasticity and stress-strain behavior are critical requirements at analysis process and knowing complete stress-strain curve facilitates structural behavior assessment at nonlinear analysis for structures that have built with geopolymers. This study intends to investigate stress-strain behavior and modulus of elasticity from experimental data that belongs for geopolymers varying in fineness and mix design and curing method. For the sake of behavior determination, 54 types of geopolymer are used. Similar mix proportions are used for samples productions that have different fineness and curing approach. The results indicated that the compressive strength ranges between 7.7 MPa and 43.9 MPa at the age of 28 days curing.

Development of Neural network based Plasma Monitoring System and simulator for Laser Welding Quality Analysis

  • Kwon, Jang-Woo;Son, Joong-Soo;Lee, Myung-Soo;Lee, Kyung-Don
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1999.11a
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    • pp.494-497
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    • 1999
  • Neural networks are shown to be effective in being able to distinguish incomplete penetration-like weld defects by directly analyzing the plasma which is generated on each impingement of the laser on the materials. The performance is similar to that of existing methods based on extracted feature parameters. In each case around 93% of the defects in a database derived from 100 artificially produced defects of known types can be placed into one of two classes: incomplete penetration and bubbling. Especially we present simulator for weld defects classification and data analysis. The present method based on classification using plasma is faster, and the speed is sufficient to allow on-line classification during data collection.

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A study on the growth and the molecular orientation and the surface Characterization of $\alpha$-Sexithiophene thin films by OMBD technique (유기빔성막법을 이용한 $\alpha$-Sexithiophene 박막의 제조 및 분자 배향과 표면 특성에 관한 연구)

  • 권오관;오세운;박미경;김영관;신동명;최종선;손병청
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.328-330
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    • 1997
  • Organic semiconductors such as conjugated polymers and oligomers have been studied many research groups. The band structures of conjugated polymers and oligomers are similar to those of conventional inorganic semiconductors Thin films based on these materials show a promising potential for Field Effect Transistors(FETs) and Light Emitting Diodes(LED) because fabrication processes are simple and cheaper for large electronic devices and flexible devices are also possible.

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Time-Resolved Photoluminescence Measurement of Frenkel-type Excitonic Lifetimes in InGaN/GaN Multi-quantum Well Structures

  • Shin, Gwi-Su;Hwang, Sung-Won;Kim, Keun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.5
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    • pp.19-23
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    • 2003
  • Time-resolved photoluminescence from InGaN/GaN multi-quantum well structures was investigated for two different shapes of square-and trapezoidal wells grown by metal-organic chemical vapor deposition. To compare to the conventional square well structure with a radiative recombination lifetime of 0.170 nsec, the large value of lifetime of 0.540 nsec from trapezoidal well were found at room temperature. This value is similar to the value for GaN host material indicating no confinement effect of quantum well. Furthermore, the high resolution transmission electron microscopy image provides the In clustering effect in the trapezoidal well structure.

One Step Synthesis of Dense WC-20 vol.% Co Super Hard Material (한공정에 의한 치밀한 WC-20 vol.%Co 초경합금 제조)

  • 박충도;손인진;김환철;이영국
    • Journal of Powder Materials
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    • v.8 no.4
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    • pp.231-238
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    • 2001
  • We combined Field-Activated Combustion Synthesis(FACS) with mechanical pressure to produce dense WC-20 vol.%Co composite in one step. The hardness, the fracture toughness and the relative density of the dense WC-20 vol.%Co were investigated. Under the application of 60 MPa pressure and 3000A current on the reactants, the relative density of WC-20 vol.%Co composite was 99.4%. The fracture toughness and hardness were $9.4 MPa.m^{1/2}$ and $1672kg\textrm{mm}^2$ respectively. The fracture toughness and hardness of WC-20 vol.%Co composite produced by FAPACS were lower than that of nanostructured composite, but similar to commercial ones. Therefore we concluded that the FAPACS method which can produce WC-20 vol.%Co within several minutes in one step is superior to conventional ones.

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The Evaluation of Thermal Properties for W-Cu Composite Sintered from Mechanically Alloyed Powders (기계적 합금화한 W-Cu 복합분말 소결체의 열물성 평가)

  • 오낭렴;김대건;석명진;김영환;김영도;문인형
    • Journal of Powder Materials
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    • v.7 no.3
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    • pp.154-160
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    • 2000
  • In order to enhance sinterability of W-Cu composites used for heat sink materials, mechanical alloying process where both homogeneous mixing of component powders and fine dispersion of minor phase can be easily attained was employed. Nanostructured W-Cu powders prepared by mechanical alloying showed W grain size ranged of 20-50 nm and were able to be efficiently sintered owing to the fine particle size as well as uniform distribution of Cu phase. The thermal properties such as electrical resistivity, coefficient of thermal expansion and thermal conductivity were evaluated as functions of temperature and Cu content. It was found that the coefficient of thermal expansion could be controlled by changing Cu content. The measured electrical resistivities and thermal diffusivities were also varied with Cu content. The thermal conductivities calculated from the values of resistivities and diffusivities showed similar tendency as a function of temperatures. However, this is in contradiction with thermal conductivities of pure W and Cu which decrease with increasing temperature.

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Comparision of Biochar Properties From Biomass produced by Slow Pyrolysis (저속열분해를 통한 바이오매스 부산물의 바이오촤 특성 비교 분석)

  • Park, Jinje;Lee, Yongwoon;Ryu, Changkook;Gang, Ki Seop;Yang, Won;Jung, Jin-Ho;Hyun, Seunghun
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.69-72
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    • 2013
  • This study investigates the characteristics of biochar by slow pyrolysis at $500^{\circ}C$ for various biomass residues. Six biomass materials were tested: Tree bark, Tree stem, bagasse, cocopeat, paddy straw and palm kernel shell. In the biochar yield, the effect of ash in the raw biomass was significant for paddy straw. Excluding the ash content, the timber bark, bagasse and paddy straw had a similar biochar yield of 26-29 wt.%. Tree stem and bagasse had well developed pores in a wide size range and large surface area over $200m^2/g$. Cocopeat and PKS has significantly higher biochar yield due to the increased content of lignin, but the development of intra-particle pores and microscopic surface area was very poor. The elemental composition, pH and other properties of the biochar samples were also compared.

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Dyeing Properties of Easily Dyeable m-Aramid Knit Fabric (염색이 용이한 메타 아라미드 편성물의 염색성에 관한 연구)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.128-134
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    • 2020
  • Heat and flame protecting cloth is usually made of meta aramid fiber because of its own properties. But the high inter molecular hydrogen bonding and high Tg is the reason of the difficulty to dye meta aramid fiber. Recently, it was commercialized that the easily dyeable meta aramid fiber(AMD) for improving dyeability. In this study, the dyeing properties of AMD dyed with cationic dyes were investigated. The K/S values of AMD were 5~10% higher than these of general meta aramid fiber(AM) in the case of 1%owf caused by the lower crystallinity of AMD. The difference between K/S values of AMD and AM was increased as increasing dyeing concentration. The washing and rubbing fastness grade of AM and AMD were similar and good to very good.