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Degradation of Phenol with Fenton-like Treatment by Using Heterogeneous Catalyst (Modified Iron Oxide) and Hydrogen Peroxide

  • Lee, Si-hoon;Oh, Joo-yub;Park, Yoon-chang
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.489-494
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    • 2006
  • Goethite, hematite, magnetite and synthesized iron oxide are used as catalysts for Fenton-type oxidation of phenol. The synthesized iron oxides were characterized by X-ray diffraction (XRD), BET, X-ray photoelectron spectroscopy (XPS), and electron paramagnetic resonance (EPR). The catalytic activity of these materials is classified according to the observed rate of phenol oxidation. The effectiveness of the catalysts followed the sequence: ferrous ion > synthesized iron oxide >> magnetite hematite > goethite. According to these results, the most effective iron oxide catalyst had the structure similar to natural hematite. The surface oxidation state of the catalyst was between magnetite and hematite (+2.5 ~ +3.0). Phenol degraded completely in 40 min at neutral pH (pH = 7). Soluble ferric and ferrous ions were not detected in the filtrate from Fenton reaction solution by AAS. The formation of hydroxyl radicals was confirmed by EPR.

An Experimental Study on the Performance of Wire Mesh Reinforced Porous Concrete (Wire Mesh보강 포러스콘크리트의 성능평가에 관한 실험적 연구)

  • 권혁준;이택우;김선용;박승범
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1227-1232
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    • 2000
  • In this study the mechanical properties of various wire mesh reinforcing porous concrete mixtures are investigated. A properly designed porous concrete pavements provides a durable riding surface. It also eliminates puddles and standing water, resulting in improved skid resistance. The most popular application is that of light-traffic volume roadways such as parking lots, resident roads, driveways, and sidewalks. Flexural strength and toughness index are examined for wire mesh reinforcing porous concrete. Type of Wire mesh is divided into three cases, A type, B type and C type. It shows A type is most excellent shape of destruction of slab specimen is similar to that of flexural specimen. The aim of this paper is to present the results of a pilot study undertaken to examine the extent to which wire mesh reinforced porous concrete can be used as a continuous paving materials.

An Experimental Study on Mechanical Properties of Ductile Concrete with the Kinds of Aggregate (골재종류에 따른 고인성 콘크리트의 역학적 특성에 관한 실험적 연구)

  • Han Byung-chan;Yang Il-seung;Park Wan-shin;Lim Seung-chan;Morii Naoharu;Youn Hyun-do
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.61-64
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    • 2005
  • Concrete is one of the principal materials for the structure and it is widely used all over the world, but it shows extremely brittle failure under bending and tensile load. Recently to improve such a poor property, Ductile Fiber Reinforced Cementitious Composites (DFRCC) have been developed, and it are defined by an ultimate strength higher than their first cracking strength and the formation of multiple cracking during the inelastic deformation process. This paper is to estimate experimentally the mechanical properties of ductile concrete with the kinds of used fine and coarse aggregate for purpose of development of high ductile concrete mixing coarse aggregate. As the results, ductile concrete mixed coarse aggregate showed the displacement-hardening behavior under bending load similar to DFRCC, and its compressive and bending performance varied according to the kinds of used coarse aggregate.

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Fire and Rangeland's Management in India

  • Paulsamy, S.;Manian, S.;Kil, Bong-Seop
    • The Korean Journal of Ecology
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    • v.28 no.1
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    • pp.55-61
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    • 2005
  • Fire, usually a detrimental factor makes changes in commonly structure and functions when it is practiced properly. In countries like Australia, South Africa, Japan and Texas in USA etc., fire is used as a tool to manage the natural ecosystems in productive condition on the basis of ecological approach. However, in developing countries like India there is effective measure to use and control fire in rangelands. This review provides knowledge on changes in sociological characters of plants, biomass profile, cycling of materials and strategy to use fire for the shaping of communities in different rangelands located in India and other countries. Further, the informations furnished in this article will be more useful for the forest managers, planners of rangelands and administrators in countries like India and tropical countries with similar bioclimatic conditions to prepare appropriate management plans where the fire is an integral factor.

A study on the Armour of Great Britain (영국 군복에 관한 연구)

  • 이은숙
    • Journal of the Korean Home Economics Association
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    • v.34 no.4
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    • pp.133-144
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    • 1996
  • The purpose of this study was to investigate not only the change and characterisitics of armours design, item, and material but also the social change which was represented them from the ancient to the middle age. The result of the study as follows : 1. In the ancient, a painting tattoing, and scar had used to express a threating attitude or fear instead of armour. Also the natural material including leather and fur had used for armour's material and it caused by their life style. 2. The change of war method and appearance of new arms introduced the various kinds of armours, helmets, materials, etc. 3. In various parts of Europe, armour's design and material were indicated similar character. 4. Armour's color and a flag were used by a means that distinguish between region and nation.

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Analysis of fatigue Crack Growth Behavior in the Integrally Stiffened Panels Subjected to Single Overload (과하중을 받는 일체형 보강판의 피로균열 성장거동 해석)

  • 이환우;서정호
    • Journal of Ocean Engineering and Technology
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    • v.18 no.1
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    • pp.28-34
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    • 2004
  • It is well known that tensile peak overloads may significantly delay suubsequent constant amplitude fatigue crack growth in many materials. Since real structures are usually subjected to complex load histories, the ability to predict accurate crack growth under realistic service conditions is of major engineering interest. This paper describes experiments on fatigue track growth in the integrally stiffened panel of 7075-T6 aluminum alloy. The effect of shape parameters and overload position on the fatigue crack growth behavior of integrally stiffened panels are discussed. Based on the experimental results, the following conclusions have been drawn: the overall fatigue crack growth retardation resulting from single overload in the stiffened panels was generally larger in the larger thickness ratio, although the retardation trends, according to the change in overload positions, were similar to those exhibited in the non-stiffened panels.

Fining of Flint Glass Melts Containing Blast Furnace Slag

  • Kim, Ki-Dong
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.618-621
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    • 2007
  • In this study, flint glass batches with blast furnace slag (BFS) were prepared and the contribution of the BFS to the fining of melts was studied through investigations of the melting and fining characteristics. Additionally, a sulfur redox reaction for BFS-doped melts was examined by square wave voltammetry (SWV). The results of the melting & fining test showed that BFS improved the fining of the melts. In a voltammogram of BFS-doped melts, two reduction peaks were shown at high frequencies while only one peak appeared at low frequencies. The peaks were located at a potential that was similar to those of melts fined by sulfate. From those results it was concluded that sulfide ($S^{2-}$) in BFS has effects in glass melts that are identical to those of sulfate ($SO_4^{2-}$).

Absence of Distinctively High Grain-Boundary Impedance in Polycrystalline Cubic Bismuth Oxide

  • Jung, Hyun Joon;Chung, Sung-Yoon
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.413-421
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    • 2017
  • In this work, we studied a fluorite structure oxides: Yttria stabilized zirconia, (YSZ); Gd doped $CeO_2$ (GDC); erbia stabilized $Bi_2O_3$ (ESB); Zr doped erbia stabilized $Bi_2O_3$ (ZESB); Ca doped erbia stabilized $Bi_2O_3$ (CESB) in the temperature range of 250 to $600^{\circ}C$ using electrochemical impedance spectroscopy (EIS). As is well known, grain boundary blocking effect was observed in YSZ and GDC. However, there is no grain boundary effect on ESB, ZESB, and CESB. The Nyquist plots of these materials exhibit a single arc at low temperature. This means that there is no space charge effect on ${\delta}-Bi_2O_3$. In addition, impedance data were analyzed by using the brick layer model. We indirectly demonstrate that grain boundary ionic conductivity is similar to or even higher than bulk ionic conductivity on cubic bismuth oxide.

Comparison of Shear Strengths of Crushed Rock Determined by Large Triaxial Test and Direct Shear Test (대형삼축압축시험 및 대형직접전단시험에 의한 사석재료의 전단강도 평가)

  • 신동훈;안태봉;이경필;이한출
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.10a
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    • pp.259-264
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    • 2002
  • In this study the shear strengths of a poorly grad ed rock material(d/sub max/≤50.8mm, C/sub u/=1.86) were determined by large direct shear test and large triaxial test. The obtained stress-strain curves by the above large shear tests for the rock materials are similar to the loose sand's or normally consolidated clay's curve, in which the peak strength does not appear obviously. And for the uniformly graded rock material the shear strength by large direct shear test may be overestimated around 1.54∼1.70 times that of large triaxial test.

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A Bibliographical Analysis on the Characteristics of the Articles Dealing with Architecture in the Chapter of Seomyongji of Imwongyeongjeji (서지학적 분석을 통한 임원경제지 섬용지 영조기사의 구성과 특징 연구)

  • Lee, Kang-Min
    • Journal of the Korean housing association
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    • v.21 no.4
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    • pp.59-69
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    • 2010
  • Imwongyeongjeji, Administration of Our Daily Life in Woods and Fields, is a sort of encyclopedia compiled by Seo, Yoo Goo in Joseon Dynasty in the 19th century. This voluminous work is made up of 16 chapters with various references including many articles dealing with architecture. The chapter Seomyongji covering the daily necessities contains a number of methods and materials of building construction. The distinctive feature of these articles is that they are mostly from Joseon's books. It is not similar to other chapters which are made of quotations from Chinese books. Especially, he quoted many of articles about architecture from his own work Geumhwagyeongdokgi, Record of Plowing and Reading in Geumhwa. In addition, He selected only empirical knowledge, put it in the book, and commented on it in his judgment. These articles provide valuable information on architectural knowledge in late Joseon period.