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Study of Material Characteristics by a Componential Analysis on the Whiteware from the Kiln of Chiljeon-ri, Bangsan-myeon, Yanggu-gun (양구 방산 칠전리 출토 백자의 성분분석을 통한 원료특성 연구)

  • Ahn, Songyee;Hwang, Hyunsung
    • Journal of Conservation Science
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    • v.29 no.3
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    • pp.261-277
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    • 2013
  • This study aims to research the relationship between whitewares and their rare materials from the site of Yanggu and Bunwon through the componential characteristic of the excavated whitewares from the 1st and the 2nd kilns of Chiljeon-ri in Bangsan-myeon, Yanggu-gun. As a result, the sherds were devided according to the chemical compositions of the body and the glaze via their respective production era. However, it considered that the whitewares from Chiljeon-ri had been manufactured with geochemically similar materials and the production process, such as refining and combining materials, had been different. It assumed that the firing temperatures of the whitewares from Chiljeon-ri were around $1,100-1,200^{\circ}C$ and substantially lower than for general whitewares. In the componential analysis, there were disparate properties in the cobalt pigment, which contained trace elements and rare earth elements. A review of the literature revealed a correlation between the whitewares from the late Chosun kiln site in Bunwon-ri and the raw materials from Yanggu-gun, but this was there were various techniques for refining and combining materials in Bunwon-ri.

Effect of The Fused Siliceous Materials on Rice Plant (수도(水稻)에 대(對)한 합성규산물질(合成珪酸物質)의 효과(效果))

  • Lee, Y.H.;Han, K.H.;Lim, S.U.
    • Applied Biological Chemistry
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    • v.14 no.3
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    • pp.183-189
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    • 1971
  • The studies reported herein were conducted to inquire the effect of fused siliceous materials which mixed with sand and quartz added calcium fertilzer on rice grown on low available silica content soil. The applied nitrogen level were examined for the two plots, nitrogen 10kg and 20kg per 10 a., and the siliceous materials(Wollastonite, Fused sand and Fused quartz) were applied as levels to 100kg, 300kg and 500kg per 10a. in the pots. The results are summerized as follows; 1. The available silica content solved in N/2 HCl solution of fused sand was more than of fused quartz but the silica solubility in 2% citric acid of fused quartz were higher than other. 2. The absorbed silica content by plant grown on the fused quartz plot was the highest among other siliceous materials and of fused sand and natural wollastonite were at almost equal. The ratio of absorbed silica of natural wollastonite was highest among them and in fused materials, the quartz was higher than sand. 3. The productivity of rice was increased by percentage of filled grain, weights of 1000 grains, and number of spikelets on account of the large quantity of the silica absorbed by plant Especially fused quartz showed the highest productive effect among siliceous materials and natural wollastonite and fused sand were similar effect. 4. From the above results. the fused quartz was selected as expelled siliceous fertilizer on rice plant among them and the fused sand was equal effect to natural wollastonite.

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Comparison of Magnesium Hydroxide Particles by Precipitation and Hydrothermal Treatment for Flame Retardant Application to Low Density Polyethylene and Ethylene-Co-Vinyl Acetate Resin (침전법과 수열처리로 제조된 수산화마그네슘 비교와 이의 저밀도 폴리에틸렌-에틸렌 비닐 아세테이트 수지 난연제 적용)

  • Hyun, Mi Kyung;Lim, Hyung Mi;Yoon, Joonho;Lee, Dong Jin;Lee, Seung-Ho;Whang, Chin Myung;Jeong, Sang Ok
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.234-240
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    • 2009
  • $Mg(OH)_2$ particles were prepared by precipitation and a hydrothermal treatment to examine the effect of $MgCl_2$ concentration, alkali type and concentration, temperature, hydrothermal treatment on the formation of $Mg(OH)_2$ particles using full factorial design, as one of DOE (Design of experiment) methods. The primary particle size is similar to the secondary particle size for the samples after the hydrothermal treatment, where the average particle size of $Mg(OH)_2$ increased with increasing the concentration of $MgCl_2$ and hydrothermal temperature and decreasing alkali/Mg molar ratio. On the other hand, for the samples prepared from precipitation, the secondary particle size is larger than the primary particles due to aggregation. The difference in alkaline source is that the particles prepared from $NH_4OH$ exhibit the larger size with better dispersion than those from NaOH. Low density polyethylene and ethylene-co-vinyl acetate (LDPE-EVA) resin composed of the smaller secondary particle size of $Mg(OH)_2$ shows a higher limited oxygen index (LOI) at 50 and 55% loading, but the smaller primary particle size may result in a better grade in UL-94 tests. At the high loading of 60%, all samples with any preparation methods exhibit V-0 grade but the LOI value depends on not only primary particle size but also dispersion state.

Physical Characteristics and Germination of Pelleted Tobacco Seeds Depending on Moulding Materials (성형재료에 따른 담배 펠렛 종자의 물리적 틀성과 발아율)

  • 민태기;박민숙;이석순
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.5
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    • pp.535-541
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    • 1996
  • A seed pelleting technique was developed for easy handling of small tobacco seeds (variety, NC82) and for direct seeding in temperary planting bed or in field. The mixture of pelleting material, binder and seeds were moulded in cylindrical holes sized 2 mm diameter and 2 mm height in a plastic plate. Bentonite and cellulose powder were good materials to make pellets with CMC as binder, and bentonite formed the hardest pelleted seeds among the materials. The number of the pelleted seeds made with the same weight of the materials was different with materials used and the number of seeds contained in a pelleted seed could be controlled by mixture ratio of materials and seeds. The seedless pellets ranged 6.9 to 16.0% at the ratio of pelleting material and seed for 2~3 seeds in a pellet. The moisture absorption rate at 100% RH and $25^{\circ}C$ was greater in the order of clay < bentonite < cellulose. Germination rates of pelleted seeds with bentonite and cellulose were similar to that of usual seed, but it was significantly lower with clay pelleted seeds.

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A STUDY ON THE ADHESION OF A SOFT LINER CONTAINING 4-META TO THE BASE METAL ALLOY AND ITS VISCOELASTIC PROPERTY

  • Park Hyun-Joo;Kim Chang-Whe;Kim Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.6
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    • pp.732-746
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    • 2003
  • Statement of problem. Soft lining materials, also referred to as tissue conditioning materials, tissue heating materials, relining materials, soft liners or tissue conditioners, were first introduced to dentistry by a plastic manufacturer in 1959. Since the introduction of the materials to the dental field, their material properties have been continually improved through the effort of many researchers. Soft lining materials have become widely accepted, particularly by prosthodontists, because of their numerous clinical advantages and ease of manipulation. Unfortunately, few reports have been issued upon the topic of increasing the bond strength between the base metal alloy used in cast denture bases and PMMA soft liner modified with 4-META, nor upon the pattern of debonding and material change in wet environment like a intra oral situation. Purpose. The purposes of this study were comparing the bond strength between base metal alloy used for the cast denture bases and PMMA soft liner modified with 4-META, and describing the pattern of debonding and material property change in wet environment like the intraoral situation. Material and Methods. This study consisted of four experiments: 1. The in vitro measurement of shear bond strength of the adhesive soft liner. 2. The in vitro measurement of shear bond strength of the adhesive soft liner after 2 weeks of aging. 3. A comparison of debonding patterns. 4. An evaluation the Relation time of modified soft liner. The soft liner used in this study was commercially available as Coe-soft (GC America.IL.,USA), which is provided in forms of powder and liquid. This is a PMMA soft liner commonly used in dental clinics. The metal primer used in this study was 4-META containing primer packed in Meta fast denture base resin (Sun Medical Co., Osaka, Japan). The specimens were formed in a single lap joint desist which is useful for evaluating the apparent shear bond strength of adhesively bonded metal plate by tensile loading. Using the $20{\times}20mm$ transparent grid, percent area of adhesive soft liner remaining on the shear area was calculated to classify the debonding patterns. To evaluate the change of the initial flow of the modified adhesive soft liner, the gelation time was measured with an oscillating rheometer (Haake RS150W/ TC50, Haake Co., Germany). It was a stress control and parallel plate type with the diameter of 35mm. Conclusion. Within the conditions and limitations of this study, the following conclusions were drawn as follows. 1. There was significant increase of bond strength in the 5% 4-META, 10% 4-META containing groups and in the primer coated groups versus the control group(P<0.05). 2. After 2 weeks of aging, no significant increase in bond strength was found except for the group containing 10% 4-META (P<0.05). 3. The gelation times of the modified soft liner were 9.3 minutes for the 5% 4-META containing liner and 11.5 minutes for the 10% 4-META liner. 4. The debonding patterns of the 4-META containing group after 2 weeks of aging were similar to those of immediaely after preparation, but the debonding pattern of the primer group showed more adhesive failure after 2 weeks of aging.

COMPARISON OF MECHANICAL PROPERTIES OF VARIOUS POST AND CORE MATERIALS

  • Ahn Seung-Geun;Sorensen John A.
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.3
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    • pp.288-299
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    • 2003
  • Statement of problem: Many kinds of post and core systems are in the market, but there are no clear selection criteria for them. Purpose: The purpose of this study was to compare the flexural strength and modulus of elasticity of core materials, and measure the bending strength of post systems made of a variety of materials. Material and Methods: The flexural strength and elastic modulus of thirteen kinds core buildup materials were measured on beams of specimens of $2.0{\times}2.0{\times}24{\pm}0.1mm$. Ten specimens per group were fabricated and loaded on an lnstron testing machine at a crosshead speed of 0.25mm/min. A test span of 20 mm was used. The failure loads were recorded and flexural strength calculated with the measured dimensions. The elastic modulus was calculated from the slopes of the linear portions of the stress-stram graphs. Also nine kinds commercially available prefabricated posts made of various materials with similar nominal diameters, approximately 1.25mm, were loaded in a three-point bend test until plastic deformation or failure occurred. Ten posts per group were tested and the obtained data were anaylzed with analysis of variance and compared with the Tukey multiple comparison tests. Results: Clearfil Photo Core and Luxacore had flexural strengths approaching amalgam, but its modulus of elasticity was only about 15% of that of amalgam. The strengths of the glass ionomer and resin modified glass ionomer were very low. The heat pressed glass ceramic core had a high elastic modulus but a relatively low flexural strength approximating that of the lower strength composite resin core materials. The stainless steel, zirconia and carbon fiber post exhibited high bending strengths. The glass fiber posts displayed strengths that were approximately half of the higher strength posts. Conclusion: When moderate amounts of coronal tooth structure are to be replaced by a post and core on an anterior tooth, a prefabricated post and high strength, high elastic modulus core may be suitable. CLINICAL IMPLICATIONS In this study several newly introduced post and core systems demonstrated satisfactory physical properties. However when the higher stress situation exists with only a minimal ferrule extension remaining a cast post and core or zirconia post and pressed core are desirable.

Changes of S-Adenosyl-L-Methionine (SAM) in Kimchi Using Different Raw Materials (기능성 김치 제조를 위한 김치 원 부재료에 따른 S-adenosyl-L-methionine(SAM) 함량의 변화)

  • Lee, Myung-Ki;Lee, Hyun-Jung;Park, Wan-Soo;Koo, Kyung-Hyung;Kim, Young-Jin;Jang, Dai-Ja;Suh, Joo-Won
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.417-422
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    • 2009
  • The purpose of this study was to measure the changes in S-adenosyl-L-methionine (SAM) content and to find the best condition for SAM Kimchi during fermentation with the different kinds of raw materials of Kimchi and the diverse ways of making Kimchi. As fermentation was processing, pH of all Kimchi groups dramatically decreases at the beginning stage of experimentation. However, pH value was 4.2-4.3 in the last stage. Titratable acidity tends toward the similar results in pH value. At the first, the SAM content went down time substantially and then increases. Kimchi (A), which was made of the most basic raw materials, resulted in the lowest content of SAM. The most abundant SAM content of Kimchi was the Kimchi made with certain materials. Kimchi (I) had the most has SAM content, overall. The best time of fermentation was when pH was between 4.3 and 5.3, and titratable acidity was 0.5-1.0%. As the results of this study, the highest SAM content in Kimchi could be made when Kimchi was fermented for 9-12 days and titratable acidity showed 0.5-1.0% This study proved that the ratio of raw materials such as red pepper, fermented fished sauces, and other materials improved the levels of SAM in the Kimchi.

The characteristics of silicon nitride thin films prepared by atomic layer deposition with batch type reactor (Batch-Type 원자층 증착 방법으로 형성한 실리콘 질화막의 특성)

  • Kim, Hyuk;Lee, Ju-Hyun;Han, Chang-Hee;Kim, Woon-Joong;Lee, Yeon-Seung;Lee, Won-Jun;Na, Sa-Kyun
    • Journal of the Korean Vacuum Society
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    • v.12 no.4
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    • pp.263-268
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    • 2003
  • Precise thickness control and excellent properties of silicon nitride thin films are essential for the next-generation semiconductor and display devices. In this study, silicon nitride thin films were deposited by batch-type atomic layer deposition (ALD) method using $SiC1_4$ and $NH_3$ as the precursors at temperatures ranging from 500 to $600^{\circ}C$. Thin film deposition using a batch-type ALD reactor was a layer-by-layer atomic growth by self-limiting surface reactions, and the thickness of the deposited film can be controlled by the number of deposition cycles. The silicon nitride thin films deposited by ALD method exhibited composition, refractive index and wet etch rate similar with those of the thin films deposited by low-pressure chemical vapor deposition method at $760^{\circ}C$. The addition of pyridine mixed with precursors increased deposition rate by 50%, however, the films deposited with pyridine was readily oxidized owing to its unstable structure, which is unsuitable for the application to semiconductor or display devices.

Texture Properties of a Korean Rice Cake (Karedduk) with Addition of Carbohydrate Materials (당류 물질 첨가 가래떡의 텍스처 특성)

  • Kim, Sang-Sook;Chung, Hae-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.9
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    • pp.1205-1210
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    • 2007
  • Texture properties of a Korean rice cake (Karedduk) added with carbohydrate materials after 0, 2, 6, 24 and 30 hrs of storage at $5^{\circ}C$ were investigated using textural characteristics and sensory descriptive analysis. Carbohydrate materials such as powdered sugar, trehalose, fructooligosaccharide (95%), isomalto, healtholigo, and galactooligosaccharide (50%) were added in 0, 1, 5 and 10% levels to dry rice flour. The texture profile analysis by Texture Analyzer revealed that adhesiveness and cohesiveness of the Korean rice cake (Karedduk) added with carbohydrate materials were similar to those of the control in trends, while hardness was low compared to the control except for fructooligosaccharide (95%) 5% and healtholigo 1% addition. The hardness and sweetness by sensory characteristics were significantly different compared to the control. Instrumental hardness was correlated with sensory hardness. Lastly, the Korean rice cake (Karedduk) added with carbohydrate materials except fructooligosaccharide (95%) 5% and healtholigo 1% addition was effective in delaying retrogradation.

A Changes of Traditional Landscape Architecture Materials in Yangdong Village, Gyeongju - Building Roof Materials in the Village Since the 1970s - (정비 사업을 통해 본 경주 양동마을 전통조경 재료의 변화양상 - 1970년대 이후 마을 내 건축물 지붕 소재를 중심으로 -)

  • Kim, Dong-Hyun;Lee, Jong-Sung;Choi, Jong-Hee
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.36 no.4
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    • pp.50-57
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    • 2018
  • Based on research projects and maintenance plans that have been carried out to observe changes in the appearance of buildings in Yangdong Village, Gyeongju, this study analyzed the process of changes in roof materials since the 1970s and drew the following conclusions. First, as the proportion of houses used in the yanggi and yanggi in the 1970s appears similar to that of Wagawa, it is believed that the village landscape has changed due to the use of modern materials by modernization and urbanization. Second, the initial stage of readjustment was designated as a folk data protection zone in 1977 and important folk data designation in 1984. However, due to the lack of a budget for repair and indiscriminate repair, the effectiveness of the project did not seem to have been high. As a result, the trend of decreasing the initial price of the previous period and increasing the use of materials such as yanggi and slate were continuing. Third, in the 1990s, the Cultural Heritage Administration pushed for restoration to the traditional method through extensive renovation projects, making efforts to restore traditional materials, such as reduction of the yanggi and roof, removal of the Hamseok roof, and an increase in the price of grass. Fourth, in the 2000s and thereafter, various readjustment projects were completed in the previous period, with the ratio of Wagwa and Choga greatly increased and the number of houses on the roof of slate reduced by about half, and the level of maintenance of the village's retirement homes was readjusted after the World Heritage List in 2010.